Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin
Solute yields, laboratory dissolution data and both chemical and isotopic markers of rock weathering reactions are used to characterise the biogeochemistry of glacial meltwaters draining a maritime Antarctic glacier. We find that delayed flowpaths through ice-marginal talus and moraine sediments are...
Published in: | Biogeochemistry |
---|---|
Main Authors: | , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Springer
2010
|
Subjects: | |
Online Access: | http://nora.nerc.ac.uk/id/eprint/9800/ https://nora.nerc.ac.uk/id/eprint/9800/1/Biogeochem_in_revision.pdf http://www.springerlink.com/content/100244/ |
id |
ftnerc:oai:nora.nerc.ac.uk:9800 |
---|---|
record_format |
openpolar |
spelling |
ftnerc:oai:nora.nerc.ac.uk:9800 2023-05-15T14:05:16+02:00 Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin Hodson, Andy Heaton, Tim Langford, Harry Newsham, Kevin 2010 text http://nora.nerc.ac.uk/id/eprint/9800/ https://nora.nerc.ac.uk/id/eprint/9800/1/Biogeochem_in_revision.pdf http://www.springerlink.com/content/100244/ en eng Springer https://nora.nerc.ac.uk/id/eprint/9800/1/Biogeochem_in_revision.pdf Hodson, Andy; Heaton, Tim; Langford, Harry; Newsham, Kevin orcid:0000-0002-9108-0936 . 2010 Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin. Biogeochemistry, 98 (1-3). 9-27. https://doi.org/10.1007/s10533-009-9372-2 <https://doi.org/10.1007/s10533-009-9372-2> Publication - Article PeerReviewed 2010 ftnerc https://doi.org/10.1007/s10533-009-9372-2 2023-02-04T19:26:18Z Solute yields, laboratory dissolution data and both chemical and isotopic markers of rock weathering reactions are used to characterise the biogeochemistry of glacial meltwaters draining a maritime Antarctic glacier. We find that delayed flowpaths through ice-marginal talus and moraine sediments are critical for the acquisition of solute from rock minerals because delayed flowpaths through subglacial sediments are absent beneath this small, cold-based glacier. Here the mechanisms of weathering are similar to those reported in subglacial environments, and include sub-oxic conditions in the early summer and increasingly oxic conditions thereafter. Up to 85% of the NO3 − and 65% of the SO4 2− are most likely produced by bacterially mediated reactions in these ice marginal sediments. However, reactive pyrite phases are sparse in the host rocks, limiting the export of Fe, SO4 2− and cations that may be removed by weathering once pyrite oxidation has taken place. This means that dissolution of Ca2+ and Na+ from carbonate and silicate minerals dominate, producing moderate cationic denudation yields from Tuva Glacier (163 Σ*meq+ m−2 a−1) compared to a global range of values (94–4,200 Σ*meq+ km−2 a−1). Overall, crustally derived cations represent 42% of the total cationic flux, the rest being accounted for by snowpack sources. Article in Journal/Newspaper Antarc* Antarctic Cold-based glacier Natural Environment Research Council: NERC Open Research Archive Antarctic Tuva ENVELOPE(12.506,12.506,65.215,65.215) Biogeochemistry 98 1-3 9 27 |
institution |
Open Polar |
collection |
Natural Environment Research Council: NERC Open Research Archive |
op_collection_id |
ftnerc |
language |
English |
description |
Solute yields, laboratory dissolution data and both chemical and isotopic markers of rock weathering reactions are used to characterise the biogeochemistry of glacial meltwaters draining a maritime Antarctic glacier. We find that delayed flowpaths through ice-marginal talus and moraine sediments are critical for the acquisition of solute from rock minerals because delayed flowpaths through subglacial sediments are absent beneath this small, cold-based glacier. Here the mechanisms of weathering are similar to those reported in subglacial environments, and include sub-oxic conditions in the early summer and increasingly oxic conditions thereafter. Up to 85% of the NO3 − and 65% of the SO4 2− are most likely produced by bacterially mediated reactions in these ice marginal sediments. However, reactive pyrite phases are sparse in the host rocks, limiting the export of Fe, SO4 2− and cations that may be removed by weathering once pyrite oxidation has taken place. This means that dissolution of Ca2+ and Na+ from carbonate and silicate minerals dominate, producing moderate cationic denudation yields from Tuva Glacier (163 Σ*meq+ m−2 a−1) compared to a global range of values (94–4,200 Σ*meq+ km−2 a−1). Overall, crustally derived cations represent 42% of the total cationic flux, the rest being accounted for by snowpack sources. |
format |
Article in Journal/Newspaper |
author |
Hodson, Andy Heaton, Tim Langford, Harry Newsham, Kevin |
spellingShingle |
Hodson, Andy Heaton, Tim Langford, Harry Newsham, Kevin Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
author_facet |
Hodson, Andy Heaton, Tim Langford, Harry Newsham, Kevin |
author_sort |
Hodson, Andy |
title |
Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
title_short |
Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
title_full |
Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
title_fullStr |
Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
title_full_unstemmed |
Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin |
title_sort |
chemical weathering and solute export by meltwater in a maritime antarctic glacier basin |
publisher |
Springer |
publishDate |
2010 |
url |
http://nora.nerc.ac.uk/id/eprint/9800/ https://nora.nerc.ac.uk/id/eprint/9800/1/Biogeochem_in_revision.pdf http://www.springerlink.com/content/100244/ |
long_lat |
ENVELOPE(12.506,12.506,65.215,65.215) |
geographic |
Antarctic Tuva |
geographic_facet |
Antarctic Tuva |
genre |
Antarc* Antarctic Cold-based glacier |
genre_facet |
Antarc* Antarctic Cold-based glacier |
op_relation |
https://nora.nerc.ac.uk/id/eprint/9800/1/Biogeochem_in_revision.pdf Hodson, Andy; Heaton, Tim; Langford, Harry; Newsham, Kevin orcid:0000-0002-9108-0936 . 2010 Chemical weathering and solute export by meltwater in a maritime Antarctic glacier basin. Biogeochemistry, 98 (1-3). 9-27. https://doi.org/10.1007/s10533-009-9372-2 <https://doi.org/10.1007/s10533-009-9372-2> |
op_doi |
https://doi.org/10.1007/s10533-009-9372-2 |
container_title |
Biogeochemistry |
container_volume |
98 |
container_issue |
1-3 |
container_start_page |
9 |
op_container_end_page |
27 |
_version_ |
1766277089353269248 |