Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. tSupramolecular ensembles of arabinogalactan (AG) and its complexes with betulin diacetate (BDA) werestudied in water and dimethyl sulfoxide (DMSO) using ablation, induced by submillimeter radiation fromthe free elect...
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ftneicon:oai:rour.neicon.ru:rour/458984 2023-05-15T18:19:40+02:00 Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica Михайленко, М. А. Шахтшнейдер, Т. П. Ельцов, И. В. Козлов, А. С. Кузнецова, С. А. Карачаров, А. А. Болдырев, В. В. Институт цветных металлов и материаловедения Кафедра аналитической и органической химии 2016-03 https://doi.org/10.1016/j.carbpol.2015.11.047 https://openrepository.ru/article?id=458984 unknown http://www.sciencedirect.com/science/journal/01448617/138 Carbohydrate Polymers Q1 Михайленко, М. А. Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica [Текст] / М. А. Михайленко, Т. П. Шахтшнейдер, И. В. Ельцов, А. С. Козлов, С. А. Кузнецова, А. А. Карачаров, В. В. Болдырев // Carbohydrate Polymers. — 2016. — Т. 138 (15 марта 2016). — С. 1-7 01448617 doi:10.1016/j.carbpol.2015.11.047 https://openrepository.ru/article?id=458984 Arabinogalactan Arabinogalactan-betulin diacetate complex Betulin diacetate NMR Polymer associates THz laser ablation 31.21 Journal Article Published Journal Article 2016 ftneicon https://doi.org/10.1016/j.carbpol.2015.11.047 2020-07-21T13:06:50Z Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. tSupramolecular ensembles of arabinogalactan (AG) and its complexes with betulin diacetate (BDA) werestudied in water and dimethyl sulfoxide (DMSO) using ablation, induced by submillimeter radiation fromthe free electron laser. Solutions of 1 wt% AG resulted in formation of aerosol particles with a maximumsize of 60–70 nm. In contrast, with DMSO as the solvent, the majority of particles were significantlysmaller. Nevertheless, the addition of water shifted the particle size distribution to a larger size, suggestingthe cross-linking of AG chains due to hydrogen bonding through water molecules. The ensembles ofmolecules were larger in solutions of the AG–BDA complex as compared to pure AG aqueous solution,and the distribution was narrow. The role of side chain interactions in the formation of AG–BDA complexesin aqueous solutions was confirmed by NMR. Article in Journal/Newspaper Sibirica NORA (National aggregator of open repositories of Russian universities) Carbohydrate Polymers 138 1 7 |
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Open Polar |
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NORA (National aggregator of open repositories of Russian universities) |
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unknown |
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Arabinogalactan Arabinogalactan-betulin diacetate complex Betulin diacetate NMR Polymer associates THz laser ablation 31.21 |
spellingShingle |
Arabinogalactan Arabinogalactan-betulin diacetate complex Betulin diacetate NMR Polymer associates THz laser ablation 31.21 Михайленко, М. А. Шахтшнейдер, Т. П. Ельцов, И. В. Козлов, А. С. Кузнецова, С. А. Карачаров, А. А. Болдырев, В. В. Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
topic_facet |
Arabinogalactan Arabinogalactan-betulin diacetate complex Betulin diacetate NMR Polymer associates THz laser ablation 31.21 |
description |
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. tSupramolecular ensembles of arabinogalactan (AG) and its complexes with betulin diacetate (BDA) werestudied in water and dimethyl sulfoxide (DMSO) using ablation, induced by submillimeter radiation fromthe free electron laser. Solutions of 1 wt% AG resulted in formation of aerosol particles with a maximumsize of 60–70 nm. In contrast, with DMSO as the solvent, the majority of particles were significantlysmaller. Nevertheless, the addition of water shifted the particle size distribution to a larger size, suggestingthe cross-linking of AG chains due to hydrogen bonding through water molecules. The ensembles ofmolecules were larger in solutions of the AG–BDA complex as compared to pure AG aqueous solution,and the distribution was narrow. The role of side chain interactions in the formation of AG–BDA complexesin aqueous solutions was confirmed by NMR. |
author2 |
Институт цветных металлов и материаловедения Кафедра аналитической и органической химии |
format |
Article in Journal/Newspaper |
author |
Михайленко, М. А. Шахтшнейдер, Т. П. Ельцов, И. В. Козлов, А. С. Кузнецова, С. А. Карачаров, А. А. Болдырев, В. В. |
author_facet |
Михайленко, М. А. Шахтшнейдер, Т. П. Ельцов, И. В. Козлов, А. С. Кузнецова, С. А. Карачаров, А. А. Болдырев, В. В. |
author_sort |
Михайленко, М. А. |
title |
Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
title_short |
Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
title_full |
Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
title_fullStr |
Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
title_full_unstemmed |
Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica |
title_sort |
supramolecular architecture of betulin diacetate complexes witharabinogalactan from larix sibirica |
publishDate |
2016 |
url |
https://doi.org/10.1016/j.carbpol.2015.11.047 https://openrepository.ru/article?id=458984 |
genre |
Sibirica |
genre_facet |
Sibirica |
op_relation |
http://www.sciencedirect.com/science/journal/01448617/138 Carbohydrate Polymers Q1 Михайленко, М. А. Supramolecular architecture of betulin diacetate complexes witharabinogalactan from Larix sibirica [Текст] / М. А. Михайленко, Т. П. Шахтшнейдер, И. В. Ельцов, А. С. Козлов, С. А. Кузнецова, А. А. Карачаров, В. В. Болдырев // Carbohydrate Polymers. — 2016. — Т. 138 (15 марта 2016). — С. 1-7 01448617 doi:10.1016/j.carbpol.2015.11.047 https://openrepository.ru/article?id=458984 |
op_doi |
https://doi.org/10.1016/j.carbpol.2015.11.047 |
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Carbohydrate Polymers |
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138 |
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1 |
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7 |
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1766196868249812992 |