Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. A new adsorbent is synthesized on the basis of silica consecutively modified by polyhexamethylene guanidine and 4,5-dihydroxy-1,3-benzenedisulfonic acid (Tiron) for the group preconcentration of Fe(III), Al(III), Cu(I...
Published in: | Journal of Analytical Chemistry |
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Online Access: | https://doi.org/10.1134/S1061934816090082 https://openrepository.ru/article?id=454010 |
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ftneicon:oai:rour.neicon.ru:rour/454010 2023-05-15T17:05:30+02:00 Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry Didukh (Дидух Светлана Леонидовна), S. L. Losev (Лосев Владимир Николаевич), V. N. Mukhina (Мухина Александра Николаевна), A. N. Trofimchuk (Трофимчук Анатолий Константинович), A. K. Институт цветных металлов и материаловедения Кафедра композиционных материалов и физико-химии металлургических процессов Кафедра физической и неорганической химии 2016-11 https://doi.org/10.1134/S1061934816090082 https://openrepository.ru/article?id=454010 unknown Journal of Analytical Chemistry Q3 Q4 Didukh (Дидух Светлана Леонидовна), S. L. Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry [Текст] / S. L. Didukh (Дидух Светлана Леонидовна), V. N. Losev (Лосев Владимир Николаевич), A. N. Mukhina (Мухина Александра Николаевна), A. K. Trofimchuk (Трофимчук Анатолий Константинович) // Journal of Analytical Chemistry. — 2016. — Т. 71 (№ 11). — С. 1137-1144 10619348 doi:10.1134/S1061934816090082 https://openrepository.ru/article?id=454010 modified silica polyhexamethylene guanidine Tiron metal ions adsorption preconcentration determination by atomic emission spectrometry 31.19.15 Journal Article Journal Article Preprint 2016 ftneicon https://doi.org/10.1134/S1061934816090082 2020-07-21T13:05:29Z Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. A new adsorbent is synthesized on the basis of silica consecutively modified by polyhexamethylene guanidine and 4,5-dihydroxy-1,3-benzenedisulfonic acid (Tiron) for the group preconcentration of Fe(III), Al(III), Cu(II), Pb(II), Zn(II), and Mn(II) followed by determination by inductively coupled plasma atomic emission spectrometry. The adsorbent in the batch mode quantitatively (recovery 98−99%) extracts Fe(III), Al(III) and Cu(II) ions at pH 4.0 and Fe(III), Al(III), Cu(II), Pb(II), Zn(II), and Mn(II) ions at pH 7.0; the time of attainment of an adsorption equilibrium does not exceed 10 min. Consecutive preconcentration at pH 4.0 and 7.0 in the batch and dynamic modes ensures the quantitative separation of Fe(III), Al(III), and Cu(II) from Pb(II), Zn(II), and Mn(II) and their separate determination. The quantitative desorption of metals was attained with 0.5−1.0 M HNO3 (5 or 10 mL). In preconcentration from 200 mL of solution with 5 mL of a desorbing solution, the preconcentration coefficient was equal to 40. The developed procedure was used for the determination of metal ions in river waters of Krasnoyarsk Krai. The results obtained were verified by the added−found method. modified silica, polyhexamethylene guanidine, Tiron, metal ions, adsorption preconcentration, determination by atomic emission spectrometry Article in Journal/Newspaper Krasnoyarsk Krai NORA (National aggregator of open repositories of Russian universities) Journal of Analytical Chemistry 71 11 1081 1088 |
institution |
Open Polar |
collection |
NORA (National aggregator of open repositories of Russian universities) |
op_collection_id |
ftneicon |
language |
unknown |
topic |
modified silica polyhexamethylene guanidine Tiron metal ions adsorption preconcentration determination by atomic emission spectrometry 31.19.15 |
spellingShingle |
modified silica polyhexamethylene guanidine Tiron metal ions adsorption preconcentration determination by atomic emission spectrometry 31.19.15 Didukh (Дидух Светлана Леонидовна), S. L. Losev (Лосев Владимир Николаевич), V. N. Mukhina (Мухина Александра Николаевна), A. N. Trofimchuk (Трофимчук Анатолий Константинович), A. K. Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
topic_facet |
modified silica polyhexamethylene guanidine Tiron metal ions adsorption preconcentration determination by atomic emission spectrometry 31.19.15 |
description |
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. A new adsorbent is synthesized on the basis of silica consecutively modified by polyhexamethylene guanidine and 4,5-dihydroxy-1,3-benzenedisulfonic acid (Tiron) for the group preconcentration of Fe(III), Al(III), Cu(II), Pb(II), Zn(II), and Mn(II) followed by determination by inductively coupled plasma atomic emission spectrometry. The adsorbent in the batch mode quantitatively (recovery 98−99%) extracts Fe(III), Al(III) and Cu(II) ions at pH 4.0 and Fe(III), Al(III), Cu(II), Pb(II), Zn(II), and Mn(II) ions at pH 7.0; the time of attainment of an adsorption equilibrium does not exceed 10 min. Consecutive preconcentration at pH 4.0 and 7.0 in the batch and dynamic modes ensures the quantitative separation of Fe(III), Al(III), and Cu(II) from Pb(II), Zn(II), and Mn(II) and their separate determination. The quantitative desorption of metals was attained with 0.5−1.0 M HNO3 (5 or 10 mL). In preconcentration from 200 mL of solution with 5 mL of a desorbing solution, the preconcentration coefficient was equal to 40. The developed procedure was used for the determination of metal ions in river waters of Krasnoyarsk Krai. The results obtained were verified by the added−found method. modified silica, polyhexamethylene guanidine, Tiron, metal ions, adsorption preconcentration, determination by atomic emission spectrometry |
author2 |
Институт цветных металлов и материаловедения Кафедра композиционных материалов и физико-химии металлургических процессов Кафедра физической и неорганической химии |
format |
Article in Journal/Newspaper |
author |
Didukh (Дидух Светлана Леонидовна), S. L. Losev (Лосев Владимир Николаевич), V. N. Mukhina (Мухина Александра Николаевна), A. N. Trofimchuk (Трофимчук Анатолий Константинович), A. K. |
author_facet |
Didukh (Дидух Светлана Леонидовна), S. L. Losev (Лосев Владимир Николаевич), V. N. Mukhina (Мухина Александра Николаевна), A. N. Trofimchuk (Трофимчук Анатолий Константинович), A. K. |
author_sort |
Didukh (Дидух Светлана Леонидовна), S. L. |
title |
Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
title_short |
Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
title_full |
Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
title_fullStr |
Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
title_full_unstemmed |
Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry |
title_sort |
using silica modified by tiron for metal preconcentration and determination in natural waters by inductively coupled plasma atomic emission spectrometry |
publishDate |
2016 |
url |
https://doi.org/10.1134/S1061934816090082 https://openrepository.ru/article?id=454010 |
genre |
Krasnoyarsk Krai |
genre_facet |
Krasnoyarsk Krai |
op_relation |
Journal of Analytical Chemistry Q3 Q4 Didukh (Дидух Светлана Леонидовна), S. L. Using Silica Modified by Tiron for Metal Preconcentration and Determination in Natural Waters by Inductively Coupled Plasma Atomic Emission Spectrometry [Текст] / S. L. Didukh (Дидух Светлана Леонидовна), V. N. Losev (Лосев Владимир Николаевич), A. N. Mukhina (Мухина Александра Николаевна), A. K. Trofimchuk (Трофимчук Анатолий Константинович) // Journal of Analytical Chemistry. — 2016. — Т. 71 (№ 11). — С. 1137-1144 10619348 doi:10.1134/S1061934816090082 https://openrepository.ru/article?id=454010 |
op_doi |
https://doi.org/10.1134/S1061934816090082 |
container_title |
Journal of Analytical Chemistry |
container_volume |
71 |
container_issue |
11 |
container_start_page |
1081 |
op_container_end_page |
1088 |
_version_ |
1766060039583301632 |