Hydroxyl radical and NOx production rates, black carbon concentrations and light-absorbing impurities in snow from field measurements of light penetration and nadir reflectivity of onshore and offshore coastal Alaskan snow

• Published in: Journal of Geophysical Research: Atmospheres
• Other Authors: France, J. (author), Reay, H. (author), King, M. (author), Voisin, D. (author), Jacobi, H. (author), Domine, F. (author), Beine, H. (author), Anastasio, C. (author), MacArthur, A. (author), Lee-Taylor, Julia (author)
• Format: Article in Journal/Newspaper
• Language: English
• Published: American Geophysical Union 2012
• Subjects: Barrow; e-folding depth; Photochemistry; Arctic; black carbon; Sea ice; Alaska
• Online Access: http://nldr.library.ucar.edu/repository/collections/OSGC-000-000-009-055; https://doi.org/10.1029/2011JD016639

Photolytic production rates of NO, NO₂ and OH radicals in snow and the total absorption spectrum due to impurities in snowpack have been calculated for the Ocean-Atmosphere-Sea-Ice-Snowpack (OASIS) campaign during Spring 2009 at Barrow, Alaska. The photolytic production rate and snowpack absorption cross-sections were calculated from measurements of snowpack stratigraphy, light penetration depths (e-folding depths), nadir reflectivity (350-700 nm) and UV broadband atmospheric radiation. Maximum NOx fluxes calculated during the campaign owing to combined nitrate and nitrite photolysis were calculated as 72 nmol m⁻² h⁻¹ for the inland snowpack and 44 nmol m⁻² h⁻¹ for the snow on sea-ice and snowpack around the Barrow Arctic Research Center (BARC). Depth-integrated photochemical production rates of OH radicals were calculated giving maximum OH depth-integrated production rates of -160 nmol m⁻² h⁻¹ for the inland snowpack and -110 - 120 nmol m⁻² h⁻¹ for the snow around BARC and snow on sea-ice. Light penetration (e-folding) depths at a wavelength of 400 nm measured for snowpack in the vicinity of Barrow and snow on sea-ice are -9 cm and 14 cm for snow 15 km inland. Fitting scaled HULIS (HUmic-LIke Substances) and black carbon absorption cross-sections to the determined snow impurity absorption cross-sections show a "humic-like" component to snowpack absorption, with typical concentrations of 1.2-1.5 μgC g⁻¹. Estimates of black carbon concentrations for the four snowpacks are -40 to 70 ng g⁻¹ for the terrestrial Arctic snowpacks and -90 ng g⁻¹ for snow on sea-ice.