Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions
The reactions, BrO + ClO yields Br + ClOO (1a) yields Br + OClO (1b) yields BrCl + O2 (1c) and ClO + ClO yields Cl + CiOO (2a) yields Cl + OClO (2b) yields Cl2 + O2 (2c) yields (ClO)2 (2d) have assumed new importance in explaining the unusual springtime depletion of ozone observed in the Antarctic s...
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ftnasantrs:oai:casi.ntrs.nasa.gov:19890005228 2023-05-15T13:35:10+02:00 Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions Sander, Stanley P. Friedl, Randall R. Unclassified, Unlimited, Publicly available May 1, 1988 application/pdf http://hdl.handle.net/2060/19890005228 unknown Document ID: 19890005228 Accession ID: 89N14599 http://hdl.handle.net/2060/19890005228 No Copyright CASI ENVIRONMENT POLLUTION NASA, Goddard Space Flight Center, Polar Ozone Workshop. Abstracts; p 253-255 1988 ftnasantrs 2015-03-15T05:59:46Z The reactions, BrO + ClO yields Br + ClOO (1a) yields Br + OClO (1b) yields BrCl + O2 (1c) and ClO + ClO yields Cl + CiOO (2a) yields Cl + OClO (2b) yields Cl2 + O2 (2c) yields (ClO)2 (2d) have assumed new importance in explaining the unusual springtime depletion of ozone observed in the Antarctic stratosphere. The mechanisms of these reactions involve the formation of metastable intermediates which subsequently decompose through several energetically allowed products providing the motivation to study these reactions using both the discharge flow-mass spectrometric and flash photolysis - ultraviolet absorption techniques. These methods have also been used to explore aspects of the kinetics and spectroscopy of the ClO dimer. Other/Unknown Material Antarc* Antarctic NASA Technical Reports Server (NTRS) Antarctic The Antarctic |
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Open Polar |
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NASA Technical Reports Server (NTRS) |
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ftnasantrs |
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unknown |
topic |
ENVIRONMENT POLLUTION |
spellingShingle |
ENVIRONMENT POLLUTION Sander, Stanley P. Friedl, Randall R. Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
topic_facet |
ENVIRONMENT POLLUTION |
description |
The reactions, BrO + ClO yields Br + ClOO (1a) yields Br + OClO (1b) yields BrCl + O2 (1c) and ClO + ClO yields Cl + CiOO (2a) yields Cl + OClO (2b) yields Cl2 + O2 (2c) yields (ClO)2 (2d) have assumed new importance in explaining the unusual springtime depletion of ozone observed in the Antarctic stratosphere. The mechanisms of these reactions involve the formation of metastable intermediates which subsequently decompose through several energetically allowed products providing the motivation to study these reactions using both the discharge flow-mass spectrometric and flash photolysis - ultraviolet absorption techniques. These methods have also been used to explore aspects of the kinetics and spectroscopy of the ClO dimer. |
format |
Other/Unknown Material |
author |
Sander, Stanley P. Friedl, Randall R. |
author_facet |
Sander, Stanley P. Friedl, Randall R. |
author_sort |
Sander, Stanley P. |
title |
Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
title_short |
Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
title_full |
Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
title_fullStr |
Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
title_full_unstemmed |
Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions |
title_sort |
studies of clo and bro reactions important in the polar stratosphere: kinetics and mechanism of the clo+bro and clo+clo reactions |
publishDate |
1988 |
url |
http://hdl.handle.net/2060/19890005228 |
op_coverage |
Unclassified, Unlimited, Publicly available |
geographic |
Antarctic The Antarctic |
geographic_facet |
Antarctic The Antarctic |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
CASI |
op_relation |
Document ID: 19890005228 Accession ID: 89N14599 http://hdl.handle.net/2060/19890005228 |
op_rights |
No Copyright |
_version_ |
1766061919711526912 |