Organic geochemical studies on kerogen precursors in recently deposited algal mats and oozes

• Main Authors: Philp, R. P., Calvin, M., Brown, S., Yang, E.
• Format: Other/Unknown Material
• Language: unknown
• Published: 1978
• Subjects: 51; Baffin Bay; Baja
• Online Access: http://ntrs.nasa.gov/search.jsp?R=19790026406

The same kerogen-like residue from the algal mats and oozes at Laguna Mormona, Baja California, is examined following degradation by saponification, alkaline KMnO4 oxidation, and HBr treatment. For comparison, pyrolytic degradation is performed for the residue and five others, two of which are obtained from algal mats at Baffin Bay, Texas. Major conclusions are that (1) Saponification of a residue specimen from the algal-ooze residue results in minor amounts of components bonded to it as esters; (2) Alkaline KMnO4 oxidation reveals that the same residue consists of a cross-linked aliphatic nucleus with additional components attached to it as esters; (3) the major products from pyrolysis of the residue include phytenes, pristenes, sterenes, and triterpenes; and (4) the HBr treatment yielded only one product, indicating the absence of a large number of ether-linkages readily cleaved by HBr.