| Summary: | Thesis (Ph. D.)--Joint Program in Chemical Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2007. Includes bibliographical references. A 225-year old coral from the south shore of Bermuda (64°W, 320N) provides a record of decadal-to-centennial scale climate variability. The coral was collected live, and sub-annual density bands seen in x-radiographs delineate cold and warm seasons allowing for precise dating. Coral skeletons incorporate strontium (Sr) and calcium (Ca) in relative proportions inversely to the sea surface temperature (SST) in which the skeleton is secreted. [Delta]180 of the coral skeleton changes based on both temperature and the [delta]180 of sea water ([delta]Ow), and 6Ow is proportional to sea surface salinity (SSS). Understanding long-term climate variability requires the reconstruction of key climate parameters, such as sea surface temperature (SST) and salinity, in records extending beyond the relatively short instrumental period. The high accretion rates, longevity, and skeletal growth bands found in coral skeletons make them an ideal resource for well-dated, seasonal climate reconstructions. Growing between 2 and 6 mm/year and reaching more than im in length, slow-growing corals provide multi-century records from one colony. Additionally, unlike the fast growing (10-20 mm/year) species Porites, slow-growing species are generally found in both tropical and sub-tropical locations greatly expanding the geographical location of these records. A high resolution record (HRR, ~11 samples per year) was drilled for the entire length of the coral record (218 years). Samples were split and Sr/Ca, [delta]180, and [delta]13C were measured for each sample. Sr/Ca was used to reconstruct winter time and mean-annual SST. Oxygen isotopic measurements were used to determine directional salinity changes, in conjunction with Sr/Ca based SST reconstructions. (cont.) Winter-time and mean annual SSTs ...
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