Nuclear Magnetic Resonance Study Of CO2 Capture By Fluoroalkylamines: Ammonium Ion PKa Depression Via Fluorine Modification And Thermochemistry Of Carbamylation

• Published in: The Journal of Organic Chemistry
• Main Authors: Jameson, Brian, Knobbe, Kari, Glaser, Rainer
• Format: Text
• Language: unknown
• Published: Scholars' Mine 2023
• Subjects: Chemistry; K5; Carbonic acid
• Online Access: https://scholarsmine.mst.edu/chem_facwork/3644; https://doi.org/10.1021/acs.joc.3c00701; https://scholarsmine.mst.edu/context/chem_facwork/article/4647/viewcontent/Nuclear_Magnetic_Resonance_Study_of_CO2_Capture_by_______.pdf

We are developing energy-efficient and reversible carbon capture and release (CCR) systems that mimic the Lys201 carbamylation reaction in the active site of ribulose-1,5-bisphosphate carboxylase-oxygenase (RuBisCO). The multiequilibria scenario ammonium ion Xa ⇌ amine Xb ⇌ carbamic acid Xc ⇌ carbam...