Ba distribution in surface Southern Ocean sediments and export production estimates

• Published in: Paleoceanography
• Main Authors: Fagel, Nathalie, Dehairs, Frank, André, Luc, Bareille, Gilles, Monnin, Christophe
• Other Authors: Argiles, Géochimie et Environnement sédimentaires, Université de Liège, Analytical and Environmental Chemistry and Earth System Sciences, Vrije Universiteit Brussel Bruxelles (VUB), Geology and mineralogy, section of Mineralogy and Petrography, Royal Museum for Central Africa Tervuren (RMCA), Geology and Oceanography Department, Université de Bordeaux (UB), Laboratoire de Chimie Analytique Bio-Inorganique et Environnement (LCABIE), Université de Pau et des Pays de l'Adour (UPPA)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Mécanismes et Transfert en Géologie (LMTG), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Centre National de la Recherche Scientifique (CNRS)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2002
• Subjects: Geochemistry: Marine geochemistry (4835; 4850); Oceanography: Biological and Chemical: Inorganic marine chemistry; [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; [SDE.MCG]Environmental Sciences/Global Changes; Antarc*; Antarctic; Southern Ocean
• Online Access: https://hal.science/hal-00663036; https://hal.science/hal-00663036/document; https://hal.science/hal-00663036/file/Paleoceanography%20-%202002%20-%20Fagel.pdf; https://doi.org/10.1029/2000PA000552

International audience We present excess Ba (Baxs) data (i.e., total Ba corrected for lithogenic Ba) for surface sediments from a north-south transect between the Polar Front Zone and the northern Weddell Gyre in the Atlantic sector and between the Polar Front Zone and the Antarctic continent in the Indian sector. Focus is on two different processes that affect excess Ba accumulation in the sediments: sediment redistribution and excess Ba dissolution. The effect of these processes needs to be corrected for in order to convert accumulation rate into vertical rain rate, the flux component that can be linked to export production. In the Southern Ocean a major process affecting Ba accumulation rate is sediment focusing, which is corrected for using excess 230Th. This correction, however, may not always be straightforward because of boundary scavenging effects. A further major process affecting excess Ba accumulation is barite dissolution during exposure at the sediment-water column interface. Export production estimates derived from excess 230Th and barite dissolution corrected Baxs accumulation rates (i.e., excess Ba vertical rain rates) are of the same magnitude but generally larger than export production estimates based on water column proxies (234Th-deficit in the upper water column; particulate excess Ba enrichment in the mesopelagic water column). We believe export production values based on excess Ba vertical rain rate might be overestimated due to inaccurate assessment of the Baxs preservation rate. Barite dissolution has, in general, been taken into account by relating it to exposure time before burial depending on the rate of sediment accumulation. However, the observed decrease of excess Ba content with increasing water column depth (or increasing hydrostatic pressure) illustrates the dependence of barite preservation on degree of saturation in the deep water column in accordance with available thermodynamic data. Therefore correction for barite dissolution would not be appropriate by considering only ...