A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments

Laboratory acoustic measurements of hydrate-bearing sediments serve as an important reference for the geological interpretation of seismic exploration data. Tetrahydrofuran (THF) hydrates are relatively easy to form with precise control of hydrate saturation, and they overcome the long time it takes...

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Published in:Journal of Marine Science and Engineering
Main Authors: Wengao Zhao, Qingtao Bu, Zihao Wang, Tong Liu, Qingguo Meng, Yapeng Zhao, Gaowei Hu
Format: Text
Language:English
Published: Multidisciplinary Digital Publishing Institute 2024
Subjects:
Online Access:https://doi.org/10.3390/jmse12122239
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author Wengao Zhao
Qingtao Bu
Zihao Wang
Tong Liu
Qingguo Meng
Yapeng Zhao
Gaowei Hu
author_facet Wengao Zhao
Qingtao Bu
Zihao Wang
Tong Liu
Qingguo Meng
Yapeng Zhao
Gaowei Hu
author_sort Wengao Zhao
collection MDPI Open Access Publishing
container_issue 12
container_start_page 2239
container_title Journal of Marine Science and Engineering
container_volume 12
description Laboratory acoustic measurements of hydrate-bearing sediments serve as an important reference for the geological interpretation of seismic exploration data. Tetrahydrofuran (THF) hydrates are relatively easy to form with precise control of hydrate saturation, and they overcome the long time it takes for methane in sediments to form hydrate. However, when THF hydrates are used as a substitute for methane hydrate, their acoustic properties yield different results. This study reports the results of a series of laboratory experiments on the formation of methane and THF hydrate in quartz sand and the evaluation of their acoustic properties. It compares the experimental results with the results of calculations from micro-distribution models of the four hydrates using effective medium theory (EMT). Methane hydrate formed by the excess gas method has higher acoustic velocities than THF hydrate at 0–80% saturation, but at 80–100% saturation, the situation reverses, with THF hydrate having a higher wave velocity. The methane hydrate synthesis process follows a mixed micro-distribution, with grain coating predominating at low saturations, the pore-filling mixing mode dominating at medium saturations, and grain coating dominating at high saturations. In addition, THF hydrate has a slow-velocity growth at low saturation and is dominated by a pore-filling model and a load-bearing model at high saturation. We compared our experimental data with a compilation of similar published results to confirm their reliability and support our conclusions. Both hydrate types exhibit distinct micro-distributions across different saturations. Therefore, when testing the elastic characteristics of hydrate sediments, the distinct hydrate synthesis methods and micro-distribution should be considered, especially when using THF hydrate as an alternative to methane hydrate.
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spelling ftmdpi:oai:mdpi.com:/2077-1312/12/12/2239/ 2025-01-16T23:04:30+00:00 A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments Wengao Zhao Qingtao Bu Zihao Wang Tong Liu Qingguo Meng Yapeng Zhao Gaowei Hu agris 2024-12-05 application/pdf https://doi.org/10.3390/jmse12122239 eng eng Multidisciplinary Digital Publishing Institute Geological Oceanography https://dx.doi.org/10.3390/jmse12122239 https://creativecommons.org/licenses/by/4.0/ Journal of Marine Science and Engineering Volume 12 Issue 12 Pages: 2239 methane hydrate THF hydrate acoustic characteristics hydrate saturation Text 2024 ftmdpi https://doi.org/10.3390/jmse12122239 2024-12-13T01:06:16Z Laboratory acoustic measurements of hydrate-bearing sediments serve as an important reference for the geological interpretation of seismic exploration data. Tetrahydrofuran (THF) hydrates are relatively easy to form with precise control of hydrate saturation, and they overcome the long time it takes for methane in sediments to form hydrate. However, when THF hydrates are used as a substitute for methane hydrate, their acoustic properties yield different results. This study reports the results of a series of laboratory experiments on the formation of methane and THF hydrate in quartz sand and the evaluation of their acoustic properties. It compares the experimental results with the results of calculations from micro-distribution models of the four hydrates using effective medium theory (EMT). Methane hydrate formed by the excess gas method has higher acoustic velocities than THF hydrate at 0–80% saturation, but at 80–100% saturation, the situation reverses, with THF hydrate having a higher wave velocity. The methane hydrate synthesis process follows a mixed micro-distribution, with grain coating predominating at low saturations, the pore-filling mixing mode dominating at medium saturations, and grain coating dominating at high saturations. In addition, THF hydrate has a slow-velocity growth at low saturation and is dominated by a pore-filling model and a load-bearing model at high saturation. We compared our experimental data with a compilation of similar published results to confirm their reliability and support our conclusions. Both hydrate types exhibit distinct micro-distributions across different saturations. Therefore, when testing the elastic characteristics of hydrate sediments, the distinct hydrate synthesis methods and micro-distribution should be considered, especially when using THF hydrate as an alternative to methane hydrate. Text Methane hydrate MDPI Open Access Publishing Journal of Marine Science and Engineering 12 12 2239
spellingShingle methane hydrate
THF hydrate
acoustic characteristics
hydrate saturation
Wengao Zhao
Qingtao Bu
Zihao Wang
Tong Liu
Qingguo Meng
Yapeng Zhao
Gaowei Hu
A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title_full A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title_fullStr A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title_full_unstemmed A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title_short A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments
title_sort comparative study on acoustic characteristics of methane and tetrahydrofuran hydrate-bearing sediments
topic methane hydrate
THF hydrate
acoustic characteristics
hydrate saturation
topic_facet methane hydrate
THF hydrate
acoustic characteristics
hydrate saturation
url https://doi.org/10.3390/jmse12122239