Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid
The processing of refractory gold-containing concentrates by hydrometallurgical methods is becoming increasingly important due to the depletion of rich and easily extracted mineral resources, as well as due to the need to reduce harmful emissions from metallurgy, especially given the high content of...
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ftmdpi:oai:mdpi.com:/2075-4701/9/4/465/ 2023-08-20T04:10:20+02:00 Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid Denis A. Rogozhnikov Andrei A. Shoppert Oleg A. Dizer Kirill A. Karimov Rostislav E. Rusalev 2019-04-22 application/pdf https://doi.org/10.3390/met9040465 EN eng Multidisciplinary Digital Publishing Institute Extractive Metallurgy https://dx.doi.org/10.3390/met9040465 https://creativecommons.org/licenses/by/4.0/ Metals; Volume 9; Issue 4; Pages: 465 refractory gold concentrate resources depletion reducing harmful emissions arsenic nitric acid kinetics shrinking core model pyrite arsenopyrite Text 2019 ftmdpi https://doi.org/10.3390/met9040465 2023-07-31T22:12:56Z The processing of refractory gold-containing concentrates by hydrometallurgical methods is becoming increasingly important due to the depletion of rich and easily extracted mineral resources, as well as due to the need to reduce harmful emissions from metallurgy, especially given the high content of arsenic in the ores. This paper describes the investigation of the kinetics of HNO3 leaching of sulfide gold-containing concentrates of the Yenisei ridge (Yakutia, Russia). The effect of temperature (70–85 °C), the initial concentration of HNO3 (10–40%) and the content of sulfur in the concentrate (8.22–22.44%) on the iron recovery into the solution was studied. It has been shown that increasing the content of S in the concentrate from 8.22 to 22.44% leads to an average of 45% increase in the iron recovery across the entire range temperatures and concentrations of HNO3 per one hour of leaching. The leaching kinetics of the studied types of concentrates correlates well with the new shrinking core model, which indicates that the reaction is regulated by interfacial diffusion and diffusion through the product layer. Elemental S is found on the surface of the solid leach residue, as confirmed by XRD and SEM/EDS analysis. The apparent activation energy is 60.276 kJ/mol. The semi-empirical expression describing the reaction rate under the studied conditions can be written as follows: 1/3ln(1 − X) + [(1 − X)−1/3 − 1] = 87.811(HNO3)0.837(S)2.948e−60276/RT·t. Text Yakutia MDPI Open Access Publishing Metals 9 4 465 |
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MDPI Open Access Publishing |
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English |
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refractory gold concentrate resources depletion reducing harmful emissions arsenic nitric acid kinetics shrinking core model pyrite arsenopyrite |
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refractory gold concentrate resources depletion reducing harmful emissions arsenic nitric acid kinetics shrinking core model pyrite arsenopyrite Denis A. Rogozhnikov Andrei A. Shoppert Oleg A. Dizer Kirill A. Karimov Rostislav E. Rusalev Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
topic_facet |
refractory gold concentrate resources depletion reducing harmful emissions arsenic nitric acid kinetics shrinking core model pyrite arsenopyrite |
description |
The processing of refractory gold-containing concentrates by hydrometallurgical methods is becoming increasingly important due to the depletion of rich and easily extracted mineral resources, as well as due to the need to reduce harmful emissions from metallurgy, especially given the high content of arsenic in the ores. This paper describes the investigation of the kinetics of HNO3 leaching of sulfide gold-containing concentrates of the Yenisei ridge (Yakutia, Russia). The effect of temperature (70–85 °C), the initial concentration of HNO3 (10–40%) and the content of sulfur in the concentrate (8.22–22.44%) on the iron recovery into the solution was studied. It has been shown that increasing the content of S in the concentrate from 8.22 to 22.44% leads to an average of 45% increase in the iron recovery across the entire range temperatures and concentrations of HNO3 per one hour of leaching. The leaching kinetics of the studied types of concentrates correlates well with the new shrinking core model, which indicates that the reaction is regulated by interfacial diffusion and diffusion through the product layer. Elemental S is found on the surface of the solid leach residue, as confirmed by XRD and SEM/EDS analysis. The apparent activation energy is 60.276 kJ/mol. The semi-empirical expression describing the reaction rate under the studied conditions can be written as follows: 1/3ln(1 − X) + [(1 − X)−1/3 − 1] = 87.811(HNO3)0.837(S)2.948e−60276/RT·t. |
format |
Text |
author |
Denis A. Rogozhnikov Andrei A. Shoppert Oleg A. Dizer Kirill A. Karimov Rostislav E. Rusalev |
author_facet |
Denis A. Rogozhnikov Andrei A. Shoppert Oleg A. Dizer Kirill A. Karimov Rostislav E. Rusalev |
author_sort |
Denis A. Rogozhnikov |
title |
Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
title_short |
Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
title_full |
Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
title_fullStr |
Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
title_full_unstemmed |
Leaching Kinetics of Sulfides from Refractory Gold Concentrates by Nitric Acid |
title_sort |
leaching kinetics of sulfides from refractory gold concentrates by nitric acid |
publisher |
Multidisciplinary Digital Publishing Institute |
publishDate |
2019 |
url |
https://doi.org/10.3390/met9040465 |
genre |
Yakutia |
genre_facet |
Yakutia |
op_source |
Metals; Volume 9; Issue 4; Pages: 465 |
op_relation |
Extractive Metallurgy https://dx.doi.org/10.3390/met9040465 |
op_rights |
https://creativecommons.org/licenses/by/4.0/ |
op_doi |
https://doi.org/10.3390/met9040465 |
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Metals |
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465 |
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