Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum
The subtidal red alga Plocamium cartilagineum was collected from the Western Antarctic Peninsula during the 2011 and 2017 austral summers. Bulk collections from specific sites corresponded to chemogroups identified by Young et al. in 2013. One of the chemogroups yielded several known acyclic halogen...
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ftmdpi:oai:mdpi.com:/1660-3397/17/4/230/ 2023-08-20T04:01:02+02:00 Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum Andrew J. Shilling Jacqueline L. von Salm Anthony R. Sanchez Younghoon Kee Charles D. Amsler James B. McClintock Bill J. Baker agris 2019-04-17 application/pdf https://doi.org/10.3390/md17040230 EN eng Multidisciplinary Digital Publishing Institute https://dx.doi.org/10.3390/md17040230 https://creativecommons.org/licenses/by/4.0/ Marine Drugs; Volume 17; Issue 4; Pages: 230 halogenated monoterpenes anverenes Plocamium cartilagineum Text 2019 ftmdpi https://doi.org/10.3390/md17040230 2023-07-31T22:12:16Z The subtidal red alga Plocamium cartilagineum was collected from the Western Antarctic Peninsula during the 2011 and 2017 austral summers. Bulk collections from specific sites corresponded to chemogroups identified by Young et al. in 2013. One of the chemogroups yielded several known acyclic halogenated monoterpenes (2–5) as well as undescribed compounds of the same class, anverenes B–D (6–8). Examination of another chemogroup yielded an undescribed cyclic halogenated monoterpene anverene E (9) as its major secondary metabolite. Elucidation of structures was achieved through one-dimensional (1D) and 2D nuclear magnetic resonance (NMR) spectroscopy and negative chemical ionization mass spectrometry. Compounds 1–9 show moderate cytotoxicity against cervical cancer (HeLa) cells. Text Antarc* Antarctic Antarctic Peninsula MDPI Open Access Publishing Antarctic Antarctic Peninsula Austral The Antarctic Marine Drugs 17 4 230 |
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MDPI Open Access Publishing |
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ftmdpi |
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English |
topic |
halogenated monoterpenes anverenes Plocamium cartilagineum |
spellingShingle |
halogenated monoterpenes anverenes Plocamium cartilagineum Andrew J. Shilling Jacqueline L. von Salm Anthony R. Sanchez Younghoon Kee Charles D. Amsler James B. McClintock Bill J. Baker Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
topic_facet |
halogenated monoterpenes anverenes Plocamium cartilagineum |
description |
The subtidal red alga Plocamium cartilagineum was collected from the Western Antarctic Peninsula during the 2011 and 2017 austral summers. Bulk collections from specific sites corresponded to chemogroups identified by Young et al. in 2013. One of the chemogroups yielded several known acyclic halogenated monoterpenes (2–5) as well as undescribed compounds of the same class, anverenes B–D (6–8). Examination of another chemogroup yielded an undescribed cyclic halogenated monoterpene anverene E (9) as its major secondary metabolite. Elucidation of structures was achieved through one-dimensional (1D) and 2D nuclear magnetic resonance (NMR) spectroscopy and negative chemical ionization mass spectrometry. Compounds 1–9 show moderate cytotoxicity against cervical cancer (HeLa) cells. |
format |
Text |
author |
Andrew J. Shilling Jacqueline L. von Salm Anthony R. Sanchez Younghoon Kee Charles D. Amsler James B. McClintock Bill J. Baker |
author_facet |
Andrew J. Shilling Jacqueline L. von Salm Anthony R. Sanchez Younghoon Kee Charles D. Amsler James B. McClintock Bill J. Baker |
author_sort |
Andrew J. Shilling |
title |
Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
title_short |
Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
title_full |
Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
title_fullStr |
Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
title_full_unstemmed |
Anverenes B–E, New Polyhalogenated Monoterpenes from the Antarctic Red Alga Plocamium cartilagineum |
title_sort |
anverenes b–e, new polyhalogenated monoterpenes from the antarctic red alga plocamium cartilagineum |
publisher |
Multidisciplinary Digital Publishing Institute |
publishDate |
2019 |
url |
https://doi.org/10.3390/md17040230 |
op_coverage |
agris |
geographic |
Antarctic Antarctic Peninsula Austral The Antarctic |
geographic_facet |
Antarctic Antarctic Peninsula Austral The Antarctic |
genre |
Antarc* Antarctic Antarctic Peninsula |
genre_facet |
Antarc* Antarctic Antarctic Peninsula |
op_source |
Marine Drugs; Volume 17; Issue 4; Pages: 230 |
op_relation |
https://dx.doi.org/10.3390/md17040230 |
op_rights |
https://creativecommons.org/licenses/by/4.0/ |
op_doi |
https://doi.org/10.3390/md17040230 |
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Marine Drugs |
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17 |
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4 |
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230 |
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1774722171022606336 |