Selective hydrolysis of wheat straw hemicellulose using high-pressure CO2 as catalyst

• Published in: RSC Advances
• Main Authors: Relvas, F., Morais, Ana Rita C., Lukasik, Rafal M.
• Format: Article in Journal/Newspaper
• Language: English
• Published: The Royal Society of Chemistry 2016
• Subjects: Hydrolysis; Lignocellulosic residues; Hemicellulose; Wheat Straw; Carbonic acid
• Online Access: http://hdl.handle.net/10400.9/2882; https://doi.org/10.1039/c5ra14632a

The processing of wheat straw using high-pressure CO2–H2O technology was studied with the objective to evaluate the effect of CO2 as catalyst on the hydrothermal production of hemicellulose-derived sugars either as oligomers or as monomers. Also, the reduction of the crystallinity of the cellulose-rich fraction was assessed. Over a range of reaction conditions (0 to 50 bar of initial CO2 pressure and 0 to 45 minutes of holding time, at T ¼ 180 C), the addition of CO2 to water-based processes led to the in situ formation of carbonic acid, which allowed us to obtain a higher dissolution of wheat straw hemicellulose. Furthermore, this approach led to a xylo-oligosaccharide (XOS) rich fraction, yielding 79.6 g of XOS per 100 g of the initial xylan content (at 50 bar of initial CO2 pressure and 12 min of residence time) while the water-only process gave only 70.8 g of XOS per 100 g of initial xylan content. Furthermore, for higher pressures of CO2, a decrease in oligosaccharide content was found and was counterbalanced by production of monomer sugars, achieving a maximum of 5.7 g L1 at the severest condition.