Sea Spray Aerosol (SSA) as a Source of Perfluoroalkyl Acids (PFAAs) to the Atmosphere : Field Evidence from Long-Term Air Monitoring

• Published in: Environmental Science & Technology
• Main Authors: Sha, Bo, Johansson, Jana, Tunved, Peter, Bohlin-Nizzetto, Pernilla, Cousins, Ian T., Salter, Matthew E.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Stockholms universitet, Institutionen för miljövetenskap 2022
• Subjects: per- and polyfluoroalkyl substances (PFAS); perfluoroalkyl acids (PFAAs); sea spray aerosols (SSA); coastal areas; long-range atmospheric transport; air monitoring; Arctic; Norway; Earth and Related Environmental Sciences; Geovetenskap och miljövetenskap
• Online Access: http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-191957; https://doi.org/10.1021/acs.est.1c04277

The effective enrichment of perfluoroalkyl acids (PFAAs) in sea spray aerosols (SSA) demonstrated in previous laboratory studies suggests that SSA is a potential source of PFAAs to the atmosphere. In order to investigate the influence of SSA on atmospheric PFAAs in the field, 48 h aerosol samples were collected regularly between 2018 and 2020 at two Norwegian coastal locations, Andoya and Birkenes. Significant correlations (p < 0.05) between the SSA tracer ion, Na+, and PFAA concentrations were observed in the samples from both locations, with Pearson's correlation coefficients (r) between 0.4-0.8. Such significant correlations indicate SSA to be an important source of atmospheric PFAAs to coastal areas. The correlations in the samples from Andoya were observed for more PFAA species and were generally stronger than in the samples from Birkenes, which is located further away from the coast and closer to urban areas than Andøya. Factors such as the origin of the SSA, the distance of the sampling site to open water, and the presence of other PFAA sources (e.g., volatile precursor compounds) can have influence on the contribution of SSA to PFAA in air at the sampling sites and therefore affect the observed correlations between PFAAs and Na+.