Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control
After the 1980s, atmospheric sulfate reduction is slower than the dramatic reductions in sulfur dioxide (SO2) emissions. However, a lack of observational evidence has hindered the identification of causal feedback mechanisms. Here, we report an increase in the oxygen isotopic composition of sulfate...
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ftleedsuniv:oai:eprints.whiterose.ac.uk:173794 2023-05-15T16:28:34+02:00 Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control Hattori, Shohei Iizuka, Yoshinori Alexander, Becky Ishino, Sakiko Fujita, Koji Zhai, Shuting Sherwen, Tomás Oshima, Naga Uemura, Ryu Yamada, Akinori Suzuki, Nozomi Matoba, Sumito Tsuruta, Asuka Savarino, Joel Yoshida, Naohiro 2021-05-05 text https://eprints.whiterose.ac.uk/173794/ https://eprints.whiterose.ac.uk/173794/1/Hattori_2021.pdf https://doi.org/10.1126/sciadv.abd4610 en eng https://eprints.whiterose.ac.uk/173794/1/Hattori_2021.pdf Hattori, Shohei, Iizuka, Yoshinori, Alexander, Becky et al. (12 more authors) (2021) Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control. Science Advances. eabd4610. ISSN 2375-2548 cc_by CC-BY Article PeerReviewed 2021 ftleedsuniv https://doi.org/10.1126/sciadv.abd4610 2023-01-30T22:38:21Z After the 1980s, atmospheric sulfate reduction is slower than the dramatic reductions in sulfur dioxide (SO2) emissions. However, a lack of observational evidence has hindered the identification of causal feedback mechanisms. Here, we report an increase in the oxygen isotopic composition of sulfate (Δ17OSO42-) in a Greenland ice core, implying an enhanced role of acidity-dependent in-cloud oxidation by ozone (up to 17 to 27 in sulfate production since the 1960s. A global chemical transport model reproduces the magnitude of the increase in observed Δ17OSO42- with a 10 to 15 to sulfate in Eastern North America and Western Europe. With an expected continued decrease in atmospheric acidity, this feedback will continue in the future and partially hinder air quality improvements. Article in Journal/Newspaper Greenland Greenland ice core ice core White Rose Research Online (Universities of Leeds, Sheffield & York) Greenland Science Advances 7 19 eabd4610 |
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White Rose Research Online (Universities of Leeds, Sheffield & York) |
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ftleedsuniv |
language |
English |
description |
After the 1980s, atmospheric sulfate reduction is slower than the dramatic reductions in sulfur dioxide (SO2) emissions. However, a lack of observational evidence has hindered the identification of causal feedback mechanisms. Here, we report an increase in the oxygen isotopic composition of sulfate (Δ17OSO42-) in a Greenland ice core, implying an enhanced role of acidity-dependent in-cloud oxidation by ozone (up to 17 to 27 in sulfate production since the 1960s. A global chemical transport model reproduces the magnitude of the increase in observed Δ17OSO42- with a 10 to 15 to sulfate in Eastern North America and Western Europe. With an expected continued decrease in atmospheric acidity, this feedback will continue in the future and partially hinder air quality improvements. |
format |
Article in Journal/Newspaper |
author |
Hattori, Shohei Iizuka, Yoshinori Alexander, Becky Ishino, Sakiko Fujita, Koji Zhai, Shuting Sherwen, Tomás Oshima, Naga Uemura, Ryu Yamada, Akinori Suzuki, Nozomi Matoba, Sumito Tsuruta, Asuka Savarino, Joel Yoshida, Naohiro |
spellingShingle |
Hattori, Shohei Iizuka, Yoshinori Alexander, Becky Ishino, Sakiko Fujita, Koji Zhai, Shuting Sherwen, Tomás Oshima, Naga Uemura, Ryu Yamada, Akinori Suzuki, Nozomi Matoba, Sumito Tsuruta, Asuka Savarino, Joel Yoshida, Naohiro Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
author_facet |
Hattori, Shohei Iizuka, Yoshinori Alexander, Becky Ishino, Sakiko Fujita, Koji Zhai, Shuting Sherwen, Tomás Oshima, Naga Uemura, Ryu Yamada, Akinori Suzuki, Nozomi Matoba, Sumito Tsuruta, Asuka Savarino, Joel Yoshida, Naohiro |
author_sort |
Hattori, Shohei |
title |
Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
title_short |
Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
title_full |
Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
title_fullStr |
Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
title_full_unstemmed |
Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control |
title_sort |
isotopic evidence for acidity-driven enhancement of sulfate formation after so2 emission control |
publishDate |
2021 |
url |
https://eprints.whiterose.ac.uk/173794/ https://eprints.whiterose.ac.uk/173794/1/Hattori_2021.pdf https://doi.org/10.1126/sciadv.abd4610 |
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Greenland |
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Greenland |
genre |
Greenland Greenland ice core ice core |
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Greenland Greenland ice core ice core |
op_relation |
https://eprints.whiterose.ac.uk/173794/1/Hattori_2021.pdf Hattori, Shohei, Iizuka, Yoshinori, Alexander, Becky et al. (12 more authors) (2021) Isotopic evidence for acidity-driven enhancement of sulfate formation after SO2 emission control. Science Advances. eabd4610. ISSN 2375-2548 |
op_rights |
cc_by |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.1126/sciadv.abd4610 |
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Science Advances |
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7 |
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19 |
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eabd4610 |
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1766018225369251840 |