Uptake of Ethyl Xanthate to Metal Organic Frameworks
As the mining industry spreads to new areas in the arctic regions, the need for re-useable efficient methods for mine chemicals’ recycling increases. Especially in the case of xanthates, which are used as collectors for many metals from ore. Xanthates are very toxic to aquatic life either directly o...
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American Chemical Society
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ftjyvaeskylaenun:oai:jyx.jyu.fi:123456789/89316 2024-05-19T07:36:07+00:00 Uptake of Ethyl Xanthate to Metal Organic Frameworks Kuosmanen, Riikka Sievänen, Elina Lahtinen, Manu 2023 application/pdf 35044-35053 fulltext http://urn.fi/URN:NBN:fi:jyu-202309295332 eng eng American Chemical Society ACS Omega 2470-1343 38 8 10.1021/acsomega.3c04539 Kuosmanen, R., Sievänen, E., & Lahtinen, M. (2023). Uptake of Ethyl Xanthate to Metal Organic Frameworks. ACS Omega , 8 (38), 35044-35053. https://doi.org/10.1021/acsomega.3c04539 CONVID_188949630 URN:NBN:fi:jyu-202309295332 http://urn.fi/URN:NBN:fi:jyu-202309295332 CC BY 4.0 © 2022 The Authors. Published by American Chemical Society. openAccess https://creativecommons.org/licenses/by/4.0/ talteenotto rikkiyhdisteet kaivosvesi polymeerit jäteveden käsittely kompleksiyhdisteet ympäristömyrkyt organometalliyhdisteet article http://purl.org/eprint/type/JournalArticle http://purl.org/coar/resource_type/c_2df8fbb1 publishedVersion A1 2023 ftjyvaeskylaenun 2024-04-23T23:38:28Z As the mining industry spreads to new areas in the arctic regions, the need for re-useable efficient methods for mine chemicals’ recycling increases. Especially in the case of xanthates, which are used as collectors for many metals from ore. Xanthates are very toxic to aquatic life either directly or indirectly and cause potentially severe health problems to humans after long-term exposure. In the present work, potassium ethyl xanthate (KEX) was observed to coordinate into metal organic frameworks (MOFs). HKUST-1 and its post-synthetically modified forms were observed to behave most effectively of the studied MOFs at low concentrations of KEX. Differences in the uptake of KEX were detected regarding the synthesis method in the case of MIL-100(Fe) synthetized by solvothermal and mechanochemical methods. Other studied MOFs, UiO-66 and MIL-100(Al)/MIL-96(Al), were not observed to be effective in KEX uptake. peerReviewed Article in Journal/Newspaper Arctic JYX - Jyväskylä University Digital Archive |
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Open Polar |
collection |
JYX - Jyväskylä University Digital Archive |
op_collection_id |
ftjyvaeskylaenun |
language |
English |
topic |
talteenotto rikkiyhdisteet kaivosvesi polymeerit jäteveden käsittely kompleksiyhdisteet ympäristömyrkyt organometalliyhdisteet |
spellingShingle |
talteenotto rikkiyhdisteet kaivosvesi polymeerit jäteveden käsittely kompleksiyhdisteet ympäristömyrkyt organometalliyhdisteet Kuosmanen, Riikka Sievänen, Elina Lahtinen, Manu Uptake of Ethyl Xanthate to Metal Organic Frameworks |
topic_facet |
talteenotto rikkiyhdisteet kaivosvesi polymeerit jäteveden käsittely kompleksiyhdisteet ympäristömyrkyt organometalliyhdisteet |
description |
As the mining industry spreads to new areas in the arctic regions, the need for re-useable efficient methods for mine chemicals’ recycling increases. Especially in the case of xanthates, which are used as collectors for many metals from ore. Xanthates are very toxic to aquatic life either directly or indirectly and cause potentially severe health problems to humans after long-term exposure. In the present work, potassium ethyl xanthate (KEX) was observed to coordinate into metal organic frameworks (MOFs). HKUST-1 and its post-synthetically modified forms were observed to behave most effectively of the studied MOFs at low concentrations of KEX. Differences in the uptake of KEX were detected regarding the synthesis method in the case of MIL-100(Fe) synthetized by solvothermal and mechanochemical methods. Other studied MOFs, UiO-66 and MIL-100(Al)/MIL-96(Al), were not observed to be effective in KEX uptake. peerReviewed |
format |
Article in Journal/Newspaper |
author |
Kuosmanen, Riikka Sievänen, Elina Lahtinen, Manu |
author_facet |
Kuosmanen, Riikka Sievänen, Elina Lahtinen, Manu |
author_sort |
Kuosmanen, Riikka |
title |
Uptake of Ethyl Xanthate to Metal Organic Frameworks |
title_short |
Uptake of Ethyl Xanthate to Metal Organic Frameworks |
title_full |
Uptake of Ethyl Xanthate to Metal Organic Frameworks |
title_fullStr |
Uptake of Ethyl Xanthate to Metal Organic Frameworks |
title_full_unstemmed |
Uptake of Ethyl Xanthate to Metal Organic Frameworks |
title_sort |
uptake of ethyl xanthate to metal organic frameworks |
publisher |
American Chemical Society |
publishDate |
2023 |
url |
http://urn.fi/URN:NBN:fi:jyu-202309295332 |
genre |
Arctic |
genre_facet |
Arctic |
op_relation |
ACS Omega 2470-1343 38 8 10.1021/acsomega.3c04539 Kuosmanen, R., Sievänen, E., & Lahtinen, M. (2023). Uptake of Ethyl Xanthate to Metal Organic Frameworks. ACS Omega , 8 (38), 35044-35053. https://doi.org/10.1021/acsomega.3c04539 CONVID_188949630 URN:NBN:fi:jyu-202309295332 http://urn.fi/URN:NBN:fi:jyu-202309295332 |
op_rights |
CC BY 4.0 © 2022 The Authors. Published by American Chemical Society. openAccess https://creativecommons.org/licenses/by/4.0/ |
_version_ |
1799475157307228160 |