Meteoric 10Be as a Tracer for Subglacial Chemical Weathering in East Antarctica

• Main Author: Arnardóttir, Eiríka Ösp
• Other Authors: Licht, Kathy, Graly, Joseph, Bird, Broxton, Gilhooly, William
• Format: Thesis
• Language: English
• Published: 2021
• Subjects: Subglacial Chemical Weathering; Meteoric 10Be; Cosmogenic Nuclides; Sequential Chemical Extractions; Antarctica; Antarc*; Antarctic; East Antarctica; Ice Sheet
• Online Access: https://hdl.handle.net/1805/27242; https://doi.org/10.7912/C2/83

Indiana University-Purdue University Indianapolis (IUPUI) Subglacial chemical processes in Antarctica are potentially significant contributors to global geochemical cycles, but current understanding of their scale and nature is limited. A sequential chemical extraction procedure was developed and tested to investigate the utility of meteoric 10Be as a tracer for chemical weathering processes beneath the East Antarctic Ice Sheet. Subglacial meltwater is widely available under the Antarctic Ice Sheet and chemical constituents within it have the potential to drive geochemical weathering processes in the subglacial environment. Meteoric 10Be is a cosmogenic nuclide with a half-life of 1.39×106 years that is incorporated into glacier ice, therefore its abundance in the subglacial environment in Antarctica is meltwater dependent. It is known to adsorb to fine-grained particles in aqueous solution, precipitate with amorphous oxides, and/or be incorporated into authigenic clay structures during chemical weathering. The presence of 10Be in weathering products derived from beneath the ice therefore indicates chemical weathering processes in the subglacial environment. Freshly emerging subglacial sediments from the Mt. Achernar blue ice moraine were subject to chemical extractions where these weathering phases were isolated and 10Be concentrations therein quantified. Optimization of the phase isolation was developed by examining the effects of each extraction on the sample mineralogy and chemical composition. Experiments on 10Be desorption revealed that pH 3.2-3.5 was optimal for the extraction of adsorbed 10Be. Vigorous disaggregation of the samples before grain size separations and acid extractions is crucial due to the preferential fractionation of the nuclide with clay-sized particles. 10Be concentrations of 2-22×107 atoms g-1 measured in oxides and clay minerals in freshly emerging sediments strongly indicate subglacial chemical weathering in the catchment of the Mt. Achernar moraine. Sediment-meltwater contact in ...