Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon
International audience Volatile organic molecules and a complex organic refractory material were detected on the Moon and on lunar samples. The Moon’s surface is exposed to a continuous flux of solar UV photons and fast ions, e.g. galactic cosmic rays (GCRs), solar wind (SW), and solar energetic par...
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2024
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ftinsu:oai:HAL:insu-04539893v1 2024-09-30T14:43:49+00:00 Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon Dalla Pria, G, L Sohier, Orianne Scirè, C Urso, R, G Baratta, G, A Palumbo, M, E INAF - Osservatorio Astrofisico di Catania (OACT) Istituto Nazionale di Astrofisica (INAF) Luleå University of Technology = Luleå Tekniska Universitet (LUT) PLANETO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) 2024-04 https://insu.hal.science/insu-04539893 https://insu.hal.science/insu-04539893/document https://insu.hal.science/insu-04539893/file/1-s2.0-S0019103524001374-main.pdf https://doi.org/10.1016/j.icarus.2024.116077 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.icarus.2024.116077 insu-04539893 https://insu.hal.science/insu-04539893 https://insu.hal.science/insu-04539893/document https://insu.hal.science/insu-04539893/file/1-s2.0-S0019103524001374-main.pdf doi:10.1016/j.icarus.2024.116077 ISSN: 0019-1035 EISSN: 1090-2643 Icarus https://insu.hal.science/insu-04539893 Icarus, 2024, 415 (June), pp.116077. ⟨10.1016/j.icarus.2024.116077⟩ Astrobiology Astrochemistry Ice spectroscopy [SDU]Sciences of the Universe [physics] info:eu-repo/semantics/article Journal articles 2024 ftinsu https://doi.org/10.1016/j.icarus.2024.116077 2024-09-12T00:14:33Z International audience Volatile organic molecules and a complex organic refractory material were detected on the Moon and on lunar samples. The Moon’s surface is exposed to a continuous flux of solar UV photons and fast ions, e.g. galactic cosmic rays (GCRs), solar wind (SW), and solar energetic particles (SEPs), that modify the physical and chemical properties of surface materials, thus challenging the survival of organic compounds. With this in mind, the aim of this work is to estimate the lifetime of organic compounds on the Moon’s surface under processing by energetic particles. We performed laboratory experiments to measure the destruction cross section of selected organic compounds, namely methane (CH 4 ), formamide (NH 2 CHO), and an organic refractory residue, under simulated Moon conditions. Volatile species were deposited at low temperature (17 - 18 K) and irradiated with energetic ions (200 keV) in an ultra-high vacuum chamber. The organic refractory residue was produced after warming up of a CO:CH 4 ice mixture irradiated with 200 keV H + at 18 K. All the samples were analyzed in situ by infrared transmission spectroscopy. We found that destruction cross sections are strongly affected (up to one order of magnitude) by the dilution of a given organic in an inert matrix. Among the selected samples, organic refractory residues are the most resistant to radiation. We estimated the lifetime of organic compounds on the surface of the Moon by calculating the dose rate due to GCRs and SEPs at the Moon’s orbit and by using the experimental cross section values. Taking into account impact gardening, we also estimated the fraction of surviving organic material as a function of depth. Our results are compatible with the detection of CH 4 in the LCROSS eject plume originating from layers deeper than about 0.7 m at the Moon’s South Pole and with the identification of complex organic material in lunar samples collected by Apollo 17 mission. Article in Journal/Newspaper South pole Institut national des sciences de l'Univers: HAL-INSU South Pole Icarus 415 116077 |
institution |
Open Polar |
collection |
Institut national des sciences de l'Univers: HAL-INSU |
op_collection_id |
ftinsu |
language |
English |
topic |
Astrobiology Astrochemistry Ice spectroscopy [SDU]Sciences of the Universe [physics] |
spellingShingle |
Astrobiology Astrochemistry Ice spectroscopy [SDU]Sciences of the Universe [physics] Dalla Pria, G, L Sohier, Orianne Scirè, C Urso, R, G Baratta, G, A Palumbo, M, E Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
topic_facet |
Astrobiology Astrochemistry Ice spectroscopy [SDU]Sciences of the Universe [physics] |
description |
International audience Volatile organic molecules and a complex organic refractory material were detected on the Moon and on lunar samples. The Moon’s surface is exposed to a continuous flux of solar UV photons and fast ions, e.g. galactic cosmic rays (GCRs), solar wind (SW), and solar energetic particles (SEPs), that modify the physical and chemical properties of surface materials, thus challenging the survival of organic compounds. With this in mind, the aim of this work is to estimate the lifetime of organic compounds on the Moon’s surface under processing by energetic particles. We performed laboratory experiments to measure the destruction cross section of selected organic compounds, namely methane (CH 4 ), formamide (NH 2 CHO), and an organic refractory residue, under simulated Moon conditions. Volatile species were deposited at low temperature (17 - 18 K) and irradiated with energetic ions (200 keV) in an ultra-high vacuum chamber. The organic refractory residue was produced after warming up of a CO:CH 4 ice mixture irradiated with 200 keV H + at 18 K. All the samples were analyzed in situ by infrared transmission spectroscopy. We found that destruction cross sections are strongly affected (up to one order of magnitude) by the dilution of a given organic in an inert matrix. Among the selected samples, organic refractory residues are the most resistant to radiation. We estimated the lifetime of organic compounds on the surface of the Moon by calculating the dose rate due to GCRs and SEPs at the Moon’s orbit and by using the experimental cross section values. Taking into account impact gardening, we also estimated the fraction of surviving organic material as a function of depth. Our results are compatible with the detection of CH 4 in the LCROSS eject plume originating from layers deeper than about 0.7 m at the Moon’s South Pole and with the identification of complex organic material in lunar samples collected by Apollo 17 mission. |
author2 |
INAF - Osservatorio Astrofisico di Catania (OACT) Istituto Nazionale di Astrofisica (INAF) Luleå University of Technology = Luleå Tekniska Universitet (LUT) PLANETO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Dalla Pria, G, L Sohier, Orianne Scirè, C Urso, R, G Baratta, G, A Palumbo, M, E |
author_facet |
Dalla Pria, G, L Sohier, Orianne Scirè, C Urso, R, G Baratta, G, A Palumbo, M, E |
author_sort |
Dalla Pria, G, L |
title |
Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
title_short |
Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
title_full |
Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
title_fullStr |
Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
title_full_unstemmed |
Experimental study on the radiation-induced destruction of organic compounds on the surface of the Moon |
title_sort |
experimental study on the radiation-induced destruction of organic compounds on the surface of the moon |
publisher |
HAL CCSD |
publishDate |
2024 |
url |
https://insu.hal.science/insu-04539893 https://insu.hal.science/insu-04539893/document https://insu.hal.science/insu-04539893/file/1-s2.0-S0019103524001374-main.pdf https://doi.org/10.1016/j.icarus.2024.116077 |
geographic |
South Pole |
geographic_facet |
South Pole |
genre |
South pole |
genre_facet |
South pole |
op_source |
ISSN: 0019-1035 EISSN: 1090-2643 Icarus https://insu.hal.science/insu-04539893 Icarus, 2024, 415 (June), pp.116077. ⟨10.1016/j.icarus.2024.116077⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.icarus.2024.116077 insu-04539893 https://insu.hal.science/insu-04539893 https://insu.hal.science/insu-04539893/document https://insu.hal.science/insu-04539893/file/1-s2.0-S0019103524001374-main.pdf doi:10.1016/j.icarus.2024.116077 |
op_doi |
https://doi.org/10.1016/j.icarus.2024.116077 |
container_title |
Icarus |
container_volume |
415 |
container_start_page |
116077 |
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