Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study

International audience While carbon dioxide is the main cause for global warming, modeling short-lived climate forcers (SLCFs) such as methane, ozone, and particles in the Arctic allows us to simulate near-term climate and health impacts for a sensitive, pristine region that is warming at 3 times th...

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Published in:Atmospheric Chemistry and Physics
Main Authors: Whaley, Cynthia, H., Mahmood, Rashed, von Salzen, Knut, Winter, Barbara, Eckhardt, Sabine, Arnold, Stephen, Beagley, Stephen, Becagli, Silvia, Chien, Rong-You, Christensen, Jesper, Damani, Sujay, M., Dong, Xinyi, Eleftheriadis, Kostas, Evangeliou, Nikolaos, Faluvegi, Gregory, S., Flanner, Mark, Fu, Joshua, S., Gauss, Michael, Giardi, Fabio, Gong, Wanmin, Hjorth, Jens, Liengaard, Huang, Lin, Im, Ulas, Kanaya, Yugo, Krishnan, Srinath, Klimont, Zbigniew, Kühn, Thomas, Langner, Joakim, Law, Kathy S., Marelle, Louis, Massling, Andreas, Olivié, Dirk, Onishi, Tatsuo, Oshima, Naga, Peng, Yiran, Plummer, David, A., Popovicheva, Olga, Pozzoli, Luca, Raut, Jean-Christophe, Sand, Maria, Saunders, Laura, N., Schmale, Julia, Sharma, Sangeeta, Skeie, Ragnhild Bieltvedt, Skov, Henrik, Taketani, Fumikazu, Thomas, Manu, A., Traversi, Rita, Tsigaridis, Kostas, Tsyro, Svetlana, Turnock, Steven, Vitale, Vito, Walker, Kaley, A., Wang, Minqi, Watson-Parris, Duncan, Weiss-Gibbons, Tahya
Other Authors: Canadian Centre for Climate Modelling and Analysis (CCCma), Environment and Climate Change Canada, Barcelona Supercomputing Center - Centro Nacional de Supercomputacion (BSC - CNS), Department of Geography Montréal, McGill University = Université McGill Montréal, Canada, Norwegian Institute for Air Research (NILU), Institute for Climate and Atmospheric Science Leeds (ICAS), School of Earth and Environment Leeds (SEE), University of Leeds-University of Leeds, Climate Chemistry Measurements and Research, Norwegian Meteorological Institute Oslo (MET), The University of Tennessee Knoxville, Department of Environmental Science Roskilde (ENVS), Aarhus University Aarhus, Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety (INRASTES), National Center for Scientific Research "Demokritos" (NCSR), NASA Goddard Institute for Space Studies (GISS), NASA Goddard Space Flight Center (GSFC), Center for Climate Systems Research New York (CCSR), Columbia University New York, University of Michigan Ann Arbor, University of Michigan System, Dipartimento di Chimica "Ugo schifo", Università degli Studi di Firenze = University of Florence (UniFI), Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Center for International Climate and Environmental Research Oslo (CICERO), University of Oslo (UiO), International Institute for Applied Systems Analysis Laxenburg (IIASA), Department of Applied Physics Kuopio, University of Kuopio, Atmospheric Research Centre of Eastern Finland, Finnish Meteorological Institute (FMI), Swedish Meteorological and Hydrological Institute (SMHI), TROPO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Meteorological Research Institute Tsukuba (MRI), Japan Meteorological Agency (JMA), Center for Earth System Science Beijing (CESS), Tsinghua University Beijing (THU), Lomonosov Moscow State University (MSU), European Commission - Joint Research Centre Ispra (JRC), University of Toronto, Extreme Environments Research Laboratory (EERL), Ecole Polytechnique Fédérale de Lausanne (EPFL), Met Office Hadley Centre (MOHC), United Kingdom Met Office Exeter, Department of Atmospheric, Oceanic and Planetary Physics Oxford (AOPP), University of Oxford
Format: Article in Journal/Newspaper
Language:English
Published: HAL CCSD 2022
Subjects:
Online Access:https://insu.hal.science/insu-03454867
https://insu.hal.science/insu-03454867v2/document
https://insu.hal.science/insu-03454867v2/file/acp-22-5775-2022.pdf
https://doi.org/10.5194/acp-22-5775-2022
id ftinsu:oai:HAL:insu-03454867v2
record_format openpolar
institution Open Polar
collection Institut national des sciences de l'Univers: HAL-INSU
op_collection_id ftinsu
language English
topic [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]
[SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology
spellingShingle [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]
[SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology
Whaley, Cynthia, H.
Mahmood, Rashed
von Salzen, Knut
Winter, Barbara
Eckhardt, Sabine
Arnold, Stephen
Beagley, Stephen
Becagli, Silvia
Chien, Rong-You
Christensen, Jesper
Damani, Sujay, M.
Dong, Xinyi
Eleftheriadis, Kostas
Evangeliou, Nikolaos
Faluvegi, Gregory, S.
Flanner, Mark
Fu, Joshua, S.
Gauss, Michael
Giardi, Fabio
Gong, Wanmin
Hjorth, Jens, Liengaard
Huang, Lin
Im, Ulas
Kanaya, Yugo
Krishnan, Srinath
Klimont, Zbigniew
Kühn, Thomas
Langner, Joakim
Law, Kathy S.
Marelle, Louis
Massling, Andreas
Olivié, Dirk
Onishi, Tatsuo
Oshima, Naga
Peng, Yiran
Plummer, David, A.
Popovicheva, Olga
Pozzoli, Luca
Raut, Jean-Christophe
Sand, Maria
Saunders, Laura, N.
Schmale, Julia
Sharma, Sangeeta
Skeie, Ragnhild Bieltvedt
Skov, Henrik
Taketani, Fumikazu
Thomas, Manu, A.
Traversi, Rita
Tsigaridis, Kostas
Tsyro, Svetlana
Turnock, Steven
Vitale, Vito
Walker, Kaley, A.
Wang, Minqi
Watson-Parris, Duncan
Weiss-Gibbons, Tahya
Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
topic_facet [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]
[SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology
description International audience While carbon dioxide is the main cause for global warming, modeling short-lived climate forcers (SLCFs) such as methane, ozone, and particles in the Arctic allows us to simulate near-term climate and health impacts for a sensitive, pristine region that is warming at 3 times the global rate. Atmospheric modeling is critical for understanding the long-range transport of pollutants to the Arctic, as well as the abundance and distribution of SLCFs throughout the Arctic atmosphere. Modeling is also used as a tool to determine SLCF impacts on climate and health in the present and in future emissions scenarios.In this study, we evaluate 18 state-of-the-art atmospheric and Earth system models by assessing their represen-tation of Arctic and Northern Hemisphere atmospheric SLCF distributions, considering a wide range of differentchemical species (methane, tropospheric ozone and its precursors, black carbon, sulfate, organic aerosol, andparticulate matter) and multiple observational datasets. Model simulations over 4 years (2008–2009 and 2014–2015) conducted for the 2022 Arctic Monitoring and Assessment Programme (AMAP) SLCF assessment reportare thoroughly evaluated against satellite, ground, ship, and aircraft-based observations. The annual means, sea-sonal cycles, and 3-D distributions of SLCFs were evaluated using several metrics, such as absolute and percentmodel biases and correlation coefficients. The results show a large range in model performance, with no oneparticular model or model type performing well for all regions and all SLCF species. The multi-model mean(mmm) was able to represent the general features of SLCFs in the Arctic and had the best overall performance.For the SLCFs with the greatest radiative impact (CH4, O3, BC, and SO2−), the mmm was within ±25 % of the 4measurements across the Northern Hemisphere. Therefore, we recommend a multi-model ensemble be used for simulating climate and health impacts of SLCFs.Of the SLCFs in our study, model biases were smallest for CH4 and ...
author2 Canadian Centre for Climate Modelling and Analysis (CCCma)
Environment and Climate Change Canada
Barcelona Supercomputing Center - Centro Nacional de Supercomputacion (BSC - CNS)
Department of Geography Montréal
McGill University = Université McGill Montréal, Canada
Norwegian Institute for Air Research (NILU)
Institute for Climate and Atmospheric Science Leeds (ICAS)
School of Earth and Environment Leeds (SEE)
University of Leeds-University of Leeds
Climate Chemistry Measurements and Research
Norwegian Meteorological Institute Oslo (MET)
The University of Tennessee Knoxville
Department of Environmental Science Roskilde (ENVS)
Aarhus University Aarhus
Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety (INRASTES)
National Center for Scientific Research "Demokritos" (NCSR)
NASA Goddard Institute for Space Studies (GISS)
NASA Goddard Space Flight Center (GSFC)
Center for Climate Systems Research New York (CCSR)
Columbia University New York
University of Michigan Ann Arbor
University of Michigan System
Dipartimento di Chimica "Ugo schifo"
Università degli Studi di Firenze = University of Florence (UniFI)
Japan Agency for Marine-Earth Science and Technology (JAMSTEC)
Center for International Climate and Environmental Research Oslo (CICERO)
University of Oslo (UiO)
International Institute for Applied Systems Analysis Laxenburg (IIASA)
Department of Applied Physics Kuopio
University of Kuopio
Atmospheric Research Centre of Eastern Finland
Finnish Meteorological Institute (FMI)
Swedish Meteorological and Hydrological Institute (SMHI)
TROPO - LATMOS
Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS)
Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)
Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)
Meteorological Research Institute Tsukuba (MRI)
Japan Meteorological Agency (JMA)
Center for Earth System Science Beijing (CESS)
Tsinghua University Beijing (THU)
Lomonosov Moscow State University (MSU)
European Commission - Joint Research Centre Ispra (JRC)
University of Toronto
Extreme Environments Research Laboratory (EERL)
Ecole Polytechnique Fédérale de Lausanne (EPFL)
Met Office Hadley Centre (MOHC)
United Kingdom Met Office Exeter
Department of Atmospheric, Oceanic and Planetary Physics Oxford (AOPP)
University of Oxford
format Article in Journal/Newspaper
author Whaley, Cynthia, H.
Mahmood, Rashed
von Salzen, Knut
Winter, Barbara
Eckhardt, Sabine
Arnold, Stephen
Beagley, Stephen
Becagli, Silvia
Chien, Rong-You
Christensen, Jesper
Damani, Sujay, M.
Dong, Xinyi
Eleftheriadis, Kostas
Evangeliou, Nikolaos
Faluvegi, Gregory, S.
Flanner, Mark
Fu, Joshua, S.
Gauss, Michael
Giardi, Fabio
Gong, Wanmin
Hjorth, Jens, Liengaard
Huang, Lin
Im, Ulas
Kanaya, Yugo
Krishnan, Srinath
Klimont, Zbigniew
Kühn, Thomas
Langner, Joakim
Law, Kathy S.
Marelle, Louis
Massling, Andreas
Olivié, Dirk
Onishi, Tatsuo
Oshima, Naga
Peng, Yiran
Plummer, David, A.
Popovicheva, Olga
Pozzoli, Luca
Raut, Jean-Christophe
Sand, Maria
Saunders, Laura, N.
Schmale, Julia
Sharma, Sangeeta
Skeie, Ragnhild Bieltvedt
Skov, Henrik
Taketani, Fumikazu
Thomas, Manu, A.
Traversi, Rita
Tsigaridis, Kostas
Tsyro, Svetlana
Turnock, Steven
Vitale, Vito
Walker, Kaley, A.
Wang, Minqi
Watson-Parris, Duncan
Weiss-Gibbons, Tahya
author_facet Whaley, Cynthia, H.
Mahmood, Rashed
von Salzen, Knut
Winter, Barbara
Eckhardt, Sabine
Arnold, Stephen
Beagley, Stephen
Becagli, Silvia
Chien, Rong-You
Christensen, Jesper
Damani, Sujay, M.
Dong, Xinyi
Eleftheriadis, Kostas
Evangeliou, Nikolaos
Faluvegi, Gregory, S.
Flanner, Mark
Fu, Joshua, S.
Gauss, Michael
Giardi, Fabio
Gong, Wanmin
Hjorth, Jens, Liengaard
Huang, Lin
Im, Ulas
Kanaya, Yugo
Krishnan, Srinath
Klimont, Zbigniew
Kühn, Thomas
Langner, Joakim
Law, Kathy S.
Marelle, Louis
Massling, Andreas
Olivié, Dirk
Onishi, Tatsuo
Oshima, Naga
Peng, Yiran
Plummer, David, A.
Popovicheva, Olga
Pozzoli, Luca
Raut, Jean-Christophe
Sand, Maria
Saunders, Laura, N.
Schmale, Julia
Sharma, Sangeeta
Skeie, Ragnhild Bieltvedt
Skov, Henrik
Taketani, Fumikazu
Thomas, Manu, A.
Traversi, Rita
Tsigaridis, Kostas
Tsyro, Svetlana
Turnock, Steven
Vitale, Vito
Walker, Kaley, A.
Wang, Minqi
Watson-Parris, Duncan
Weiss-Gibbons, Tahya
author_sort Whaley, Cynthia, H.
title Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
title_short Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
title_full Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
title_fullStr Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
title_full_unstemmed Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study
title_sort model evaluation of short-lived climate forcers for the arctic monitoring and assessment programme:a multi-species, multi-model study
publisher HAL CCSD
publishDate 2022
url https://insu.hal.science/insu-03454867
https://insu.hal.science/insu-03454867v2/document
https://insu.hal.science/insu-03454867v2/file/acp-22-5775-2022.pdf
https://doi.org/10.5194/acp-22-5775-2022
geographic Arctic
geographic_facet Arctic
genre AMAP
Arctic
black carbon
Global warming
genre_facet AMAP
Arctic
black carbon
Global warming
op_source ISSN: 1680-7316
EISSN: 1680-7324
Atmospheric Chemistry and Physics
https://insu.hal.science/insu-03454867
Atmospheric Chemistry and Physics, 2022, 22 (9), pp.5775-5828. ⟨10.5194/acp-22-5775-2022⟩
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spelling ftinsu:oai:HAL:insu-03454867v2 2024-02-04T09:52:40+01:00 Model evaluation of short-lived climate forcers for the Arctic Monitoring and Assessment Programme:a multi-species, multi-model study Whaley, Cynthia, H. Mahmood, Rashed von Salzen, Knut Winter, Barbara Eckhardt, Sabine Arnold, Stephen Beagley, Stephen Becagli, Silvia Chien, Rong-You Christensen, Jesper Damani, Sujay, M. Dong, Xinyi Eleftheriadis, Kostas Evangeliou, Nikolaos Faluvegi, Gregory, S. Flanner, Mark Fu, Joshua, S. Gauss, Michael Giardi, Fabio Gong, Wanmin Hjorth, Jens, Liengaard Huang, Lin Im, Ulas Kanaya, Yugo Krishnan, Srinath Klimont, Zbigniew Kühn, Thomas Langner, Joakim Law, Kathy S. Marelle, Louis Massling, Andreas Olivié, Dirk Onishi, Tatsuo Oshima, Naga Peng, Yiran Plummer, David, A. Popovicheva, Olga Pozzoli, Luca Raut, Jean-Christophe Sand, Maria Saunders, Laura, N. Schmale, Julia Sharma, Sangeeta Skeie, Ragnhild Bieltvedt Skov, Henrik Taketani, Fumikazu Thomas, Manu, A. Traversi, Rita Tsigaridis, Kostas Tsyro, Svetlana Turnock, Steven Vitale, Vito Walker, Kaley, A. Wang, Minqi Watson-Parris, Duncan Weiss-Gibbons, Tahya Canadian Centre for Climate Modelling and Analysis (CCCma) Environment and Climate Change Canada Barcelona Supercomputing Center - Centro Nacional de Supercomputacion (BSC - CNS) Department of Geography Montréal McGill University = Université McGill Montréal, Canada Norwegian Institute for Air Research (NILU) Institute for Climate and Atmospheric Science Leeds (ICAS) School of Earth and Environment Leeds (SEE) University of Leeds-University of Leeds Climate Chemistry Measurements and Research Norwegian Meteorological Institute Oslo (MET) The University of Tennessee Knoxville Department of Environmental Science Roskilde (ENVS) Aarhus University Aarhus Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety (INRASTES) National Center for Scientific Research "Demokritos" (NCSR) NASA Goddard Institute for Space Studies (GISS) NASA Goddard Space Flight Center (GSFC) Center for Climate Systems Research New York (CCSR) Columbia University New York University of Michigan Ann Arbor University of Michigan System Dipartimento di Chimica "Ugo schifo" Università degli Studi di Firenze = University of Florence (UniFI) Japan Agency for Marine-Earth Science and Technology (JAMSTEC) Center for International Climate and Environmental Research Oslo (CICERO) University of Oslo (UiO) International Institute for Applied Systems Analysis Laxenburg (IIASA) Department of Applied Physics Kuopio University of Kuopio Atmospheric Research Centre of Eastern Finland Finnish Meteorological Institute (FMI) Swedish Meteorological and Hydrological Institute (SMHI) TROPO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) Meteorological Research Institute Tsukuba (MRI) Japan Meteorological Agency (JMA) Center for Earth System Science Beijing (CESS) Tsinghua University Beijing (THU) Lomonosov Moscow State University (MSU) European Commission - Joint Research Centre Ispra (JRC) University of Toronto Extreme Environments Research Laboratory (EERL) Ecole Polytechnique Fédérale de Lausanne (EPFL) Met Office Hadley Centre (MOHC) United Kingdom Met Office Exeter Department of Atmospheric, Oceanic and Planetary Physics Oxford (AOPP) University of Oxford 2022 https://insu.hal.science/insu-03454867 https://insu.hal.science/insu-03454867v2/document https://insu.hal.science/insu-03454867v2/file/acp-22-5775-2022.pdf https://doi.org/10.5194/acp-22-5775-2022 en eng HAL CCSD European Geosciences Union info:eu-repo/semantics/altIdentifier/doi/10.5194/acp-22-5775-2022 info:eu-repo/grantAgreement//689443/EU/The European network for observing our changing planet/ERA-PLANET info:eu-repo/grantAgreement/EC/FP7/315195/EU/Electro-agglomeration and separation of Engineered NanoParticles from process and waste water in the coating industry to minimise health and environmental risks/NANOFLOC insu-03454867 https://insu.hal.science/insu-03454867 https://insu.hal.science/insu-03454867v2/document https://insu.hal.science/insu-03454867v2/file/acp-22-5775-2022.pdf doi:10.5194/acp-22-5775-2022 http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://insu.hal.science/insu-03454867 Atmospheric Chemistry and Physics, 2022, 22 (9), pp.5775-5828. ⟨10.5194/acp-22-5775-2022⟩ [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology info:eu-repo/semantics/article Journal articles 2022 ftinsu https://doi.org/10.5194/acp-22-5775-2022 2024-01-10T17:24:57Z International audience While carbon dioxide is the main cause for global warming, modeling short-lived climate forcers (SLCFs) such as methane, ozone, and particles in the Arctic allows us to simulate near-term climate and health impacts for a sensitive, pristine region that is warming at 3 times the global rate. Atmospheric modeling is critical for understanding the long-range transport of pollutants to the Arctic, as well as the abundance and distribution of SLCFs throughout the Arctic atmosphere. Modeling is also used as a tool to determine SLCF impacts on climate and health in the present and in future emissions scenarios.In this study, we evaluate 18 state-of-the-art atmospheric and Earth system models by assessing their represen-tation of Arctic and Northern Hemisphere atmospheric SLCF distributions, considering a wide range of differentchemical species (methane, tropospheric ozone and its precursors, black carbon, sulfate, organic aerosol, andparticulate matter) and multiple observational datasets. Model simulations over 4 years (2008–2009 and 2014–2015) conducted for the 2022 Arctic Monitoring and Assessment Programme (AMAP) SLCF assessment reportare thoroughly evaluated against satellite, ground, ship, and aircraft-based observations. The annual means, sea-sonal cycles, and 3-D distributions of SLCFs were evaluated using several metrics, such as absolute and percentmodel biases and correlation coefficients. The results show a large range in model performance, with no oneparticular model or model type performing well for all regions and all SLCF species. The multi-model mean(mmm) was able to represent the general features of SLCFs in the Arctic and had the best overall performance.For the SLCFs with the greatest radiative impact (CH4, O3, BC, and SO2−), the mmm was within ±25 % of the 4measurements across the Northern Hemisphere. Therefore, we recommend a multi-model ensemble be used for simulating climate and health impacts of SLCFs.Of the SLCFs in our study, model biases were smallest for CH4 and ... Article in Journal/Newspaper AMAP Arctic black carbon Global warming Institut national des sciences de l'Univers: HAL-INSU Arctic Atmospheric Chemistry and Physics 22 9 5775 5828