Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial
Abstract Tropospheric reactive gaseous chlorine (Cl y ) impacts the atmosphere's oxidation capacity with implications for chemically reduced gases such as methane. Here we use Greenland ice‐core records of chlorine, sodium, and acidity, and global model simulations to show how tropospheric Cl y...
Published in: | Geophysical Research Letters |
---|---|
Main Authors: | , , , , , , , , , , , , , , , , , , , |
Other Authors: | , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2021
|
Subjects: | |
Online Access: | https://hal.science/hal-04278530 https://hal.science/hal-04278530/document https://hal.science/hal-04278530/file/Zhai_et_al_2021GL093808.pdf https://doi.org/10.1029/2021GL093808 |
id |
ftinsu:oai:HAL:hal-04278530v1 |
---|---|
record_format |
openpolar |
spelling |
ftinsu:oai:HAL:hal-04278530v1 2023-12-17T10:30:59+01:00 Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial Zhai, Shuting Wang, Xuan Mcconnell, Joseph, R Geng, Lei Cole‐dai, Jihong Sigl, Michael Chellman, Nathan Sherwen, Tomás Pound, Ryan Fujita, Koji Hattori, Shohei Moch, Jonathan, M Zhu, Lei Evans, Mat Legrand, Michel Liu, Pengfei Pasteris, Daniel Chan, Yuk‐chun Murray, Lee, T Alexander, Becky Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA (UMR_7583)) Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité) 2021-07-28 https://hal.science/hal-04278530 https://hal.science/hal-04278530/document https://hal.science/hal-04278530/file/Zhai_et_al_2021GL093808.pdf https://doi.org/10.1029/2021GL093808 en eng HAL CCSD American Geophysical Union info:eu-repo/semantics/altIdentifier/doi/10.1029/2021GL093808 hal-04278530 https://hal.science/hal-04278530 https://hal.science/hal-04278530/document https://hal.science/hal-04278530/file/Zhai_et_al_2021GL093808.pdf doi:10.1029/2021GL093808 info:eu-repo/semantics/OpenAccess ISSN: 0094-8276 EISSN: 1944-8007 Geophysical Research Letters https://hal.science/hal-04278530 Geophysical Research Letters, 2021, 48 (14), ⟨10.1029/2021GL093808⟩ [SDE]Environmental Sciences info:eu-repo/semantics/article Journal articles 2021 ftinsu https://doi.org/10.1029/2021GL093808 2023-11-22T17:25:49Z Abstract Tropospheric reactive gaseous chlorine (Cl y ) impacts the atmosphere's oxidation capacity with implications for chemically reduced gases such as methane. Here we use Greenland ice‐core records of chlorine, sodium, and acidity, and global model simulations to show how tropospheric Cl y has been impacted by anthropogenic emissions since the 1940s. We show that anthropogenic contribution of nonsea‐salt chlorine significantly influenced total chlorine and its trends after the 1940s. The modeled regional 170% Cl y increase from preindustrial to the 1970s was driven by acid displacement from sea‐salt‐aerosol, direct emission of hydrochloric acid (HCl) from combustion, and chemical reactions driven by anthropogenic nitrogen oxide (NO x ) emissions. Since the 1970s, the modeled 6% Cl y decrease was caused mainly by reduced anthropogenic HCl emissions from air pollution mitigation policies. Our findings suggest that anthropogenic emissions of acidic gases and their emission control strategies have substantial impacts on Cl y with implications for tropospheric oxidants, methane, and mercury. Article in Journal/Newspaper Greenland Greenland ice core ice core Institut national des sciences de l'Univers: HAL-INSU Greenland Geophysical Research Letters 48 14 |
institution |
Open Polar |
collection |
Institut national des sciences de l'Univers: HAL-INSU |
op_collection_id |
ftinsu |
language |
English |
topic |
[SDE]Environmental Sciences |
spellingShingle |
[SDE]Environmental Sciences Zhai, Shuting Wang, Xuan Mcconnell, Joseph, R Geng, Lei Cole‐dai, Jihong Sigl, Michael Chellman, Nathan Sherwen, Tomás Pound, Ryan Fujita, Koji Hattori, Shohei Moch, Jonathan, M Zhu, Lei Evans, Mat Legrand, Michel Liu, Pengfei Pasteris, Daniel Chan, Yuk‐chun Murray, Lee, T Alexander, Becky Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
topic_facet |
[SDE]Environmental Sciences |
description |
Abstract Tropospheric reactive gaseous chlorine (Cl y ) impacts the atmosphere's oxidation capacity with implications for chemically reduced gases such as methane. Here we use Greenland ice‐core records of chlorine, sodium, and acidity, and global model simulations to show how tropospheric Cl y has been impacted by anthropogenic emissions since the 1940s. We show that anthropogenic contribution of nonsea‐salt chlorine significantly influenced total chlorine and its trends after the 1940s. The modeled regional 170% Cl y increase from preindustrial to the 1970s was driven by acid displacement from sea‐salt‐aerosol, direct emission of hydrochloric acid (HCl) from combustion, and chemical reactions driven by anthropogenic nitrogen oxide (NO x ) emissions. Since the 1970s, the modeled 6% Cl y decrease was caused mainly by reduced anthropogenic HCl emissions from air pollution mitigation policies. Our findings suggest that anthropogenic emissions of acidic gases and their emission control strategies have substantial impacts on Cl y with implications for tropospheric oxidants, methane, and mercury. |
author2 |
Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA (UMR_7583)) Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité) |
format |
Article in Journal/Newspaper |
author |
Zhai, Shuting Wang, Xuan Mcconnell, Joseph, R Geng, Lei Cole‐dai, Jihong Sigl, Michael Chellman, Nathan Sherwen, Tomás Pound, Ryan Fujita, Koji Hattori, Shohei Moch, Jonathan, M Zhu, Lei Evans, Mat Legrand, Michel Liu, Pengfei Pasteris, Daniel Chan, Yuk‐chun Murray, Lee, T Alexander, Becky |
author_facet |
Zhai, Shuting Wang, Xuan Mcconnell, Joseph, R Geng, Lei Cole‐dai, Jihong Sigl, Michael Chellman, Nathan Sherwen, Tomás Pound, Ryan Fujita, Koji Hattori, Shohei Moch, Jonathan, M Zhu, Lei Evans, Mat Legrand, Michel Liu, Pengfei Pasteris, Daniel Chan, Yuk‐chun Murray, Lee, T Alexander, Becky |
author_sort |
Zhai, Shuting |
title |
Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
title_short |
Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
title_full |
Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
title_fullStr |
Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
title_full_unstemmed |
Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial |
title_sort |
anthropogenic impacts on tropospheric reactive chlorine since the preindustrial |
publisher |
HAL CCSD |
publishDate |
2021 |
url |
https://hal.science/hal-04278530 https://hal.science/hal-04278530/document https://hal.science/hal-04278530/file/Zhai_et_al_2021GL093808.pdf https://doi.org/10.1029/2021GL093808 |
geographic |
Greenland |
geographic_facet |
Greenland |
genre |
Greenland Greenland ice core ice core |
genre_facet |
Greenland Greenland ice core ice core |
op_source |
ISSN: 0094-8276 EISSN: 1944-8007 Geophysical Research Letters https://hal.science/hal-04278530 Geophysical Research Letters, 2021, 48 (14), ⟨10.1029/2021GL093808⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1029/2021GL093808 hal-04278530 https://hal.science/hal-04278530 https://hal.science/hal-04278530/document https://hal.science/hal-04278530/file/Zhai_et_al_2021GL093808.pdf doi:10.1029/2021GL093808 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1029/2021GL093808 |
container_title |
Geophysical Research Letters |
container_volume |
48 |
container_issue |
14 |
_version_ |
1785584120036851712 |