Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago
International audience Determining the factors controlling the neodymium (Nd) isotopic compositions (expressed as ε Nd) and rare earth element (REE) concentrations of rivers is imperative to improve our understanding of the distribution of these water mass tracers in the ocean. Here we present the f...
Published in: | Earth and Planetary Science Letters |
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Main Authors: | , , , , , , , , , |
Other Authors: | , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2022
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Subjects: | |
Online Access: | https://hal.science/hal-03805808 https://hal.science/hal-03805808/document https://hal.science/hal-03805808/file/Grenier-etal_eNd-REE-CAArivers_EPSL_22.pdf https://doi.org/10.1016/j.epsl.2021.117341 |
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Open Polar |
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Institut national des sciences de l'Univers: HAL-INSU |
op_collection_id |
ftinsu |
language |
English |
topic |
Rare Earth Elements neodymium isotopes bedrock geology dissolved riverine inputs Canadian Arctic Archipelago river geochemistry [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography |
spellingShingle |
Rare Earth Elements neodymium isotopes bedrock geology dissolved riverine inputs Canadian Arctic Archipelago river geochemistry [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography Grenier, Mélanie Brown, K.A. Colombo, M. Belhadj, M. Baconnais, I. Pham, V. Soon, M. Myers, P.G. Jeandel, C. François, R. Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
topic_facet |
Rare Earth Elements neodymium isotopes bedrock geology dissolved riverine inputs Canadian Arctic Archipelago river geochemistry [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography |
description |
International audience Determining the factors controlling the neodymium (Nd) isotopic compositions (expressed as ε Nd) and rare earth element (REE) concentrations of rivers is imperative to improve our understanding of the distribution of these water mass tracers in the ocean. Here we present the first measurements of <0.45 μm-filtrate REE concentrations (i.e., the concentration of truly dissolved, nano-particulate and colloidal REEs passing through a 0.45 μm filter, hereafter referred to as dissolved) and ε Nd in rivers draining into the Canadian Arctic Archipelago (CAA). Results show a large variation in both REE concentrations (Nd = [8; 37, 260] pmol/kg) and ε Nd ([−32.1; −15.1]) in the thirteen rivers sampled. Dissolved REE concentrations increase with increasing fractions of metamorphic rocks and ice cover in the rivers' watersheds, while ε Nd and PAAS-normalized REE patterns are inherited from the watershed's bedrock lithology. The four rivers draining watersheds composed of Precambrian metamorphic rocks exhibit the highest REE concentrations, the least radiogenic ε Nd , and shale-normalized patterns enriched in light REEs. The remaining nine rivers drain mainly or exclusively sedimentary bedrock and have lower REE concentrations, more radiogenic ε Nd and generally show heavy REE enrichment, with variable negative cerium (Ce) anomalies. The presence of ice sheets in the drainage area, and the ionic strength, pH, and dissolved organic carbon concentration of river water are the main factors determining riverine dissolved REE concentrations by controlling the formation and stabilization of colloids. We estimate a flow of dissolved Nd transported by Arctic rivers discharging into the CAA equivalent to the Nd flux of seawater entering the CAA. Depending on the percentage of Nd removal during mixing with seawater, the impact of river water on the ε Nd of seawater exiting the CAA could be modest (if 90% removal) or more significant (if 90% removal). This riverine contribution could potentially impart a ... |
author2 |
Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS) Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP) Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Centre National de la Recherche Scientifique (CNRS) Institute of Ocean Sciences Sidney (IOS) Fisheries and Oceans Canada (DFO) University of British Columbia (UBC) University of Saskatchewan Saskatoon (U of S) University of Alberta |
format |
Article in Journal/Newspaper |
author |
Grenier, Mélanie Brown, K.A. Colombo, M. Belhadj, M. Baconnais, I. Pham, V. Soon, M. Myers, P.G. Jeandel, C. François, R. |
author_facet |
Grenier, Mélanie Brown, K.A. Colombo, M. Belhadj, M. Baconnais, I. Pham, V. Soon, M. Myers, P.G. Jeandel, C. François, R. |
author_sort |
Grenier, Mélanie |
title |
Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
title_short |
Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
title_full |
Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
title_fullStr |
Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
title_full_unstemmed |
Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago |
title_sort |
controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the canadian arctic archipelago |
publisher |
HAL CCSD |
publishDate |
2022 |
url |
https://hal.science/hal-03805808 https://hal.science/hal-03805808/document https://hal.science/hal-03805808/file/Grenier-etal_eNd-REE-CAArivers_EPSL_22.pdf https://doi.org/10.1016/j.epsl.2021.117341 |
geographic |
Arctic Canadian Arctic Archipelago |
geographic_facet |
Arctic Canadian Arctic Archipelago |
genre |
Arctic Archipelago Arctic Canadian Arctic Archipelago |
genre_facet |
Arctic Archipelago Arctic Canadian Arctic Archipelago |
op_source |
ISSN: 0012-821X Earth and Planetary Science Letters https://hal.science/hal-03805808 Earth and Planetary Science Letters, 2022, 578, pp.117341. ⟨10.1016/j.epsl.2021.117341⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.epsl.2021.117341 hal-03805808 https://hal.science/hal-03805808 https://hal.science/hal-03805808/document https://hal.science/hal-03805808/file/Grenier-etal_eNd-REE-CAArivers_EPSL_22.pdf doi:10.1016/j.epsl.2021.117341 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1016/j.epsl.2021.117341 |
container_title |
Earth and Planetary Science Letters |
container_volume |
578 |
container_start_page |
117341 |
_version_ |
1785559280676503552 |
spelling |
ftinsu:oai:HAL:hal-03805808v1 2023-12-17T10:23:37+01:00 Controlling factors and impacts of river-borne neodymium isotope signatures and rare earth element concentrations supplied to the Canadian Arctic Archipelago Grenier, Mélanie Brown, K.A. Colombo, M. Belhadj, M. Baconnais, I. Pham, V. Soon, M. Myers, P.G. Jeandel, C. François, R. Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS) Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP) Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Centre National de la Recherche Scientifique (CNRS) Institute of Ocean Sciences Sidney (IOS) Fisheries and Oceans Canada (DFO) University of British Columbia (UBC) University of Saskatchewan Saskatoon (U of S) University of Alberta 2022 https://hal.science/hal-03805808 https://hal.science/hal-03805808/document https://hal.science/hal-03805808/file/Grenier-etal_eNd-REE-CAArivers_EPSL_22.pdf https://doi.org/10.1016/j.epsl.2021.117341 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.epsl.2021.117341 hal-03805808 https://hal.science/hal-03805808 https://hal.science/hal-03805808/document https://hal.science/hal-03805808/file/Grenier-etal_eNd-REE-CAArivers_EPSL_22.pdf doi:10.1016/j.epsl.2021.117341 info:eu-repo/semantics/OpenAccess ISSN: 0012-821X Earth and Planetary Science Letters https://hal.science/hal-03805808 Earth and Planetary Science Letters, 2022, 578, pp.117341. ⟨10.1016/j.epsl.2021.117341⟩ Rare Earth Elements neodymium isotopes bedrock geology dissolved riverine inputs Canadian Arctic Archipelago river geochemistry [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography info:eu-repo/semantics/article Journal articles 2022 ftinsu https://doi.org/10.1016/j.epsl.2021.117341 2023-11-22T17:29:53Z International audience Determining the factors controlling the neodymium (Nd) isotopic compositions (expressed as ε Nd) and rare earth element (REE) concentrations of rivers is imperative to improve our understanding of the distribution of these water mass tracers in the ocean. Here we present the first measurements of <0.45 μm-filtrate REE concentrations (i.e., the concentration of truly dissolved, nano-particulate and colloidal REEs passing through a 0.45 μm filter, hereafter referred to as dissolved) and ε Nd in rivers draining into the Canadian Arctic Archipelago (CAA). Results show a large variation in both REE concentrations (Nd = [8; 37, 260] pmol/kg) and ε Nd ([−32.1; −15.1]) in the thirteen rivers sampled. Dissolved REE concentrations increase with increasing fractions of metamorphic rocks and ice cover in the rivers' watersheds, while ε Nd and PAAS-normalized REE patterns are inherited from the watershed's bedrock lithology. The four rivers draining watersheds composed of Precambrian metamorphic rocks exhibit the highest REE concentrations, the least radiogenic ε Nd , and shale-normalized patterns enriched in light REEs. The remaining nine rivers drain mainly or exclusively sedimentary bedrock and have lower REE concentrations, more radiogenic ε Nd and generally show heavy REE enrichment, with variable negative cerium (Ce) anomalies. The presence of ice sheets in the drainage area, and the ionic strength, pH, and dissolved organic carbon concentration of river water are the main factors determining riverine dissolved REE concentrations by controlling the formation and stabilization of colloids. We estimate a flow of dissolved Nd transported by Arctic rivers discharging into the CAA equivalent to the Nd flux of seawater entering the CAA. Depending on the percentage of Nd removal during mixing with seawater, the impact of river water on the ε Nd of seawater exiting the CAA could be modest (if 90% removal) or more significant (if 90% removal). This riverine contribution could potentially impart a ... Article in Journal/Newspaper Arctic Archipelago Arctic Canadian Arctic Archipelago Institut national des sciences de l'Univers: HAL-INSU Arctic Canadian Arctic Archipelago Earth and Planetary Science Letters 578 117341 |