Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern
International audience We present Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of tropospheric BrO carried out on board the German research vessel Polarstern during the Antarctic winter 2006. Polarstern entered the area of first year sea ice around Antarctica on 24...
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ftinsu:oai:HAL:hal-00302568v1 2023-11-12T04:02:25+01:00 Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern Wagner, T. Ibrahim, O. Sinreich, R. Friess, U. Platt, U. Atmospheric Chemistry Department MPIC Max Planck Institute for Chemistry (MPIC) Max-Planck-Gesellschaft-Max-Planck-Gesellschaft Institut für Umweltphysik Heidelberg Universität Heidelberg Heidelberg = Heidelberg University 2007-02-05 https://hal.science/hal-00302568 https://hal.science/hal-00302568/document https://hal.science/hal-00302568/file/acpd-7-1823-2007.pdf en eng HAL CCSD European Geosciences Union hal-00302568 https://hal.science/hal-00302568 https://hal.science/hal-00302568/document https://hal.science/hal-00302568/file/acpd-7-1823-2007.pdf info:eu-repo/semantics/OpenAccess ISSN: 1680-7367 EISSN: 1680-7375 Atmospheric Chemistry and Physics Discussions https://hal.science/hal-00302568 Atmospheric Chemistry and Physics Discussions, 2007, 7 (1), pp.1823-1847 [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere info:eu-repo/semantics/article Journal articles 2007 ftinsu 2023-10-25T16:26:34Z International audience We present Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of tropospheric BrO carried out on board the German research vessel Polarstern during the Antarctic winter 2006. Polarstern entered the area of first year sea ice around Antarctica on 24 June 2006 and stayed within this area until 15 August 2006. For the period when the ship cruised inside the first year sea ice belt, enhanced BrO concentrations were almost continuously observed. One interesting exception appeared on 7 July 2006, when the sun elevation angle was < about ?2.8° indicating that for low insulation the photolysis of Br 2 and/or HOBr is too slow to provide sufficient amounts of Br radicals. Before and after the period inside the first year sea ice belt, typically low BrO concentrations were observed. Our observations indicate that enhanced BrO concentrations around Antarctica exist about one month earlier than observed by satellite instruments. The small BrO concentrations over the open oceans indicate a short atmospheric lifetime of activated bromine without contact to areas of first year sea ice. From detailed radiative transfer simulations we find that MAX-DOAS observations are about one order of magnitude more sensitive to near-surface BrO than satellite observations. In contrast to satellite observations the MAX-DOAS sensitivity hardly decreases for large solar zenith angles and is almost independent from the ground albedo. Thus this technique is very well suited for observations in polar regions close to the solar terminator. Furthermore, combination of both techniques could yield additional information on the vertical distribution of BrO in the lower troposphere. Article in Journal/Newspaper Antarc* Antarctic Antarctica Sea ice Institut national des sciences de l'Univers: HAL-INSU Antarctic The Antarctic |
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Open Polar |
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Institut national des sciences de l'Univers: HAL-INSU |
op_collection_id |
ftinsu |
language |
English |
topic |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
spellingShingle |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere Wagner, T. Ibrahim, O. Sinreich, R. Friess, U. Platt, U. Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
topic_facet |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
description |
International audience We present Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of tropospheric BrO carried out on board the German research vessel Polarstern during the Antarctic winter 2006. Polarstern entered the area of first year sea ice around Antarctica on 24 June 2006 and stayed within this area until 15 August 2006. For the period when the ship cruised inside the first year sea ice belt, enhanced BrO concentrations were almost continuously observed. One interesting exception appeared on 7 July 2006, when the sun elevation angle was < about ?2.8° indicating that for low insulation the photolysis of Br 2 and/or HOBr is too slow to provide sufficient amounts of Br radicals. Before and after the period inside the first year sea ice belt, typically low BrO concentrations were observed. Our observations indicate that enhanced BrO concentrations around Antarctica exist about one month earlier than observed by satellite instruments. The small BrO concentrations over the open oceans indicate a short atmospheric lifetime of activated bromine without contact to areas of first year sea ice. From detailed radiative transfer simulations we find that MAX-DOAS observations are about one order of magnitude more sensitive to near-surface BrO than satellite observations. In contrast to satellite observations the MAX-DOAS sensitivity hardly decreases for large solar zenith angles and is almost independent from the ground albedo. Thus this technique is very well suited for observations in polar regions close to the solar terminator. Furthermore, combination of both techniques could yield additional information on the vertical distribution of BrO in the lower troposphere. |
author2 |
Atmospheric Chemistry Department MPIC Max Planck Institute for Chemistry (MPIC) Max-Planck-Gesellschaft-Max-Planck-Gesellschaft Institut für Umweltphysik Heidelberg Universität Heidelberg Heidelberg = Heidelberg University |
format |
Article in Journal/Newspaper |
author |
Wagner, T. Ibrahim, O. Sinreich, R. Friess, U. Platt, U. |
author_facet |
Wagner, T. Ibrahim, O. Sinreich, R. Friess, U. Platt, U. |
author_sort |
Wagner, T. |
title |
Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
title_short |
Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
title_full |
Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
title_fullStr |
Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
title_full_unstemmed |
Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern |
title_sort |
enhanced tropospheric bro concentrations over the antarctic sea ice belt in mid winter observed from max-doas observations on board the research vessel polarstern |
publisher |
HAL CCSD |
publishDate |
2007 |
url |
https://hal.science/hal-00302568 https://hal.science/hal-00302568/document https://hal.science/hal-00302568/file/acpd-7-1823-2007.pdf |
geographic |
Antarctic The Antarctic |
geographic_facet |
Antarctic The Antarctic |
genre |
Antarc* Antarctic Antarctica Sea ice |
genre_facet |
Antarc* Antarctic Antarctica Sea ice |
op_source |
ISSN: 1680-7367 EISSN: 1680-7375 Atmospheric Chemistry and Physics Discussions https://hal.science/hal-00302568 Atmospheric Chemistry and Physics Discussions, 2007, 7 (1), pp.1823-1847 |
op_relation |
hal-00302568 https://hal.science/hal-00302568 https://hal.science/hal-00302568/document https://hal.science/hal-00302568/file/acpd-7-1823-2007.pdf |
op_rights |
info:eu-repo/semantics/OpenAccess |
_version_ |
1782334318654259200 |