The isotopic fingerprint of the pre-industrial and the anthropogenic N 2 O source

• Main Authors: Röckmann, T., Kaiser, J., Brenninkmeijer, C. A. M.
• Other Authors: Max Planck Institute for Nuclear Physics (MPIK), Max-Planck-Gesellschaft, Max Planck Institute for Chemistry (MPIC)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2002
• Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean; Atmosphere; Antarctic; Antarc*
• Online Access: https://hal.science/hal-00300977; https://hal.science/hal-00300977/document; https://hal.science/hal-00300977/file/acpd-2-2021-2002.pdf

International audience We have performed high-precision measurements of the 18 O and position dependent 15 N isotopic composition of N 2 O from Antarctic firn air samples. By comparing these data to simulations carried out with a firn air diffusion model, we have reconstructed the temporal evolution of the N 2 O isotope signatures since pre-industrial times. The heavy isotope content of atmospheric N 2 O is presently decreasing for all signatures at rates of about -0.038%o yr -1 for 1 d 15 N, -0.044%o yr -1 for 2 d 15 N and -0.025%o yr -1 for d 18 O. The total decrease since pre-industrial times is estimated to be about -2%o for d 15 N at both positions and -1.2%o for d 18 O. Isotope budget calculations using these trends and recent stratospheric measurements allow to isotopically characterize the present and the pre-industrial global average N 2 O source, as well as the anthropogenic N 2 O emissions that have caused the global N 2 O increase since pre-industrial times. The increased fluxes from the depleted surface sources alone are insufficient to explain the inferred temporal isotope changes. In addition, the global average N 2 O source signature is calculated to be significantly depleted today relative to the pre-industrial value, in agreement with recent indications from soil emission measurements.