Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs)
International audience A PSC was detected on 6 February 2003 in the Arctic stratosphere by in-situ measurements onboard the high-altitude research aircraft Geophysica. Low number densities (~10 -4 cm -3 ) of small nitric acid (HNO 3 ) containing particles ( d <6µm) were observed at altitudes betw...
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ftinsu:oai:HAL:hal-00295666v1 2024-02-11T10:01:17+01:00 Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) Voigt, C. Schlager, H. Luo, B. P. Dörnbrack, A. Roiger, Anke Stock, P. Curtius, J. Vössing, H. Borrmann, S. Davies, S. Konopka, P. Schiller, C. Shur, G. Peter, T. DLR Institut für Physik der Atmosphäre (IPA) Deutsches Zentrum für Luft- und Raumfahrt Oberpfaffenhofen-Wessling (DLR) Institute for Atmospheric and Climate Science Zürich (IAC) Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology Zürich (ETH Zürich) Max-Planck-Institut für Chemie (MPIC) Max-Planck-Gesellschaft School of Environment Forschungszentrum Jülich GmbH Helmholtz-Gemeinschaft = Helmholtz Association Central Aerological Observatory (CAO) Russian Federal Service for Hydrometeorology and Environmental Monitoring (Roshydromet) 2005-06-08 https://hal.science/hal-00295666 https://hal.science/hal-00295666/document https://hal.science/hal-00295666/file/acp-5-1371-2005.pdf en eng HAL CCSD European Geosciences Union hal-00295666 https://hal.science/hal-00295666 https://hal.science/hal-00295666/document https://hal.science/hal-00295666/file/acp-5-1371-2005.pdf info:eu-repo/semantics/OpenAccess ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://hal.science/hal-00295666 Atmospheric Chemistry and Physics, 2005, 5 (5), pp.1371-1380 [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere info:eu-repo/semantics/article Journal articles 2005 ftinsu 2024-01-17T17:27:37Z International audience A PSC was detected on 6 February 2003 in the Arctic stratosphere by in-situ measurements onboard the high-altitude research aircraft Geophysica. Low number densities (~10 -4 cm -3 ) of small nitric acid (HNO 3 ) containing particles ( d <6µm) were observed at altitudes between 18 and 20km. Provided the temperatures remain below the NAT equilibrium temperature T NAT , these NAT particles have the potential to grow further and to remove HNO 3 from the stratosphere, thereby enhancing polar ozone loss. Interestingly, the NAT particles formed in less than a day at temperatures just slightly below T NAT ( T > T NAT -3.1K). This unique measurement of PSC formation at extremely low NAT saturation ratios ( S NAT ?10) constrains current NAT nucleation theories. We suggest, that the NAT particles have formed heterogeneously, but for certain not on ice. Conversely, meteoritic particles may be favorable candidates for triggering NAT nucleation at the observed low number densities. Article in Journal/Newspaper Arctic Institut national des sciences de l'Univers: HAL-INSU Arctic |
institution |
Open Polar |
collection |
Institut national des sciences de l'Univers: HAL-INSU |
op_collection_id |
ftinsu |
language |
English |
topic |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
spellingShingle |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere Voigt, C. Schlager, H. Luo, B. P. Dörnbrack, A. Roiger, Anke Stock, P. Curtius, J. Vössing, H. Borrmann, S. Davies, S. Konopka, P. Schiller, C. Shur, G. Peter, T. Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
topic_facet |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
description |
International audience A PSC was detected on 6 February 2003 in the Arctic stratosphere by in-situ measurements onboard the high-altitude research aircraft Geophysica. Low number densities (~10 -4 cm -3 ) of small nitric acid (HNO 3 ) containing particles ( d <6µm) were observed at altitudes between 18 and 20km. Provided the temperatures remain below the NAT equilibrium temperature T NAT , these NAT particles have the potential to grow further and to remove HNO 3 from the stratosphere, thereby enhancing polar ozone loss. Interestingly, the NAT particles formed in less than a day at temperatures just slightly below T NAT ( T > T NAT -3.1K). This unique measurement of PSC formation at extremely low NAT saturation ratios ( S NAT ?10) constrains current NAT nucleation theories. We suggest, that the NAT particles have formed heterogeneously, but for certain not on ice. Conversely, meteoritic particles may be favorable candidates for triggering NAT nucleation at the observed low number densities. |
author2 |
DLR Institut für Physik der Atmosphäre (IPA) Deutsches Zentrum für Luft- und Raumfahrt Oberpfaffenhofen-Wessling (DLR) Institute for Atmospheric and Climate Science Zürich (IAC) Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology Zürich (ETH Zürich) Max-Planck-Institut für Chemie (MPIC) Max-Planck-Gesellschaft School of Environment Forschungszentrum Jülich GmbH Helmholtz-Gemeinschaft = Helmholtz Association Central Aerological Observatory (CAO) Russian Federal Service for Hydrometeorology and Environmental Monitoring (Roshydromet) |
format |
Article in Journal/Newspaper |
author |
Voigt, C. Schlager, H. Luo, B. P. Dörnbrack, A. Roiger, Anke Stock, P. Curtius, J. Vössing, H. Borrmann, S. Davies, S. Konopka, P. Schiller, C. Shur, G. Peter, T. |
author_facet |
Voigt, C. Schlager, H. Luo, B. P. Dörnbrack, A. Roiger, Anke Stock, P. Curtius, J. Vössing, H. Borrmann, S. Davies, S. Konopka, P. Schiller, C. Shur, G. Peter, T. |
author_sort |
Voigt, C. |
title |
Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
title_short |
Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
title_full |
Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
title_fullStr |
Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
title_full_unstemmed |
Nitric Acid Trihydrate (NAT) formation at low NAT supersaturation in Polar Stratospheric Clouds (PSCs) |
title_sort |
nitric acid trihydrate (nat) formation at low nat supersaturation in polar stratospheric clouds (pscs) |
publisher |
HAL CCSD |
publishDate |
2005 |
url |
https://hal.science/hal-00295666 https://hal.science/hal-00295666/document https://hal.science/hal-00295666/file/acp-5-1371-2005.pdf |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
Arctic |
genre_facet |
Arctic |
op_source |
ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://hal.science/hal-00295666 Atmospheric Chemistry and Physics, 2005, 5 (5), pp.1371-1380 |
op_relation |
hal-00295666 https://hal.science/hal-00295666 https://hal.science/hal-00295666/document https://hal.science/hal-00295666/file/acp-5-1371-2005.pdf |
op_rights |
info:eu-repo/semantics/OpenAccess |
_version_ |
1790597090860072960 |