Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard
International audience Abstract. The Svalbard archipelago, between 74° and 81° N, is ∼60 % covered by glaciers and located at the Arctic sea ice edge. The region experiences rapid variations in atmospheric flow during the snow season (from late September to May) and can be affected by air advected b...
Main Authors: | , , , , , , , , , , , , |
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Other Authors: | , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2021
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Online Access: | https://hal.science/hal-03365920 https://hal.science/hal-03365920/document https://hal.science/hal-03365920/file/acp-2020-740.pdf https://doi.org/10.5194/acp-2020-740 |
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ftinsalyonhal:oai:HAL:hal-03365920v1 |
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record_format |
openpolar |
institution |
Open Polar |
collection |
INSA Lyon HAL (Institut National des Sciences Appliquées) |
op_collection_id |
ftinsalyonhal |
language |
English |
topic |
Snow Svalbard Arctic inorganic ions water isotopes 31 [SDE]Environmental Sciences |
spellingShingle |
Snow Svalbard Arctic inorganic ions water isotopes 31 [SDE]Environmental Sciences Barbaro, Elena Koziol, Krystyna Björkman, Mats, P Vega, Carmen, P Zdanowicz, Christian Gallet, Jean-Charles Kępski, Daniel Larose, Catherine Luks, Bartłomiej Tolle, Florian Schuler, Thomas, V Uszczyk, Aleksander Spolaor, Andrea Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
topic_facet |
Snow Svalbard Arctic inorganic ions water isotopes 31 [SDE]Environmental Sciences |
description |
International audience Abstract. The Svalbard archipelago, between 74° and 81° N, is ∼60 % covered by glaciers and located at the Arctic sea ice edge. The region experiences rapid variations in atmospheric flow during the snow season (from late September to May) and can be affected by air advected both from lower and higher latitudes, which likely impact the chemical composition of snowfall. While long-term changes in Svalbard snow chemistry have been documented in ice cores drilled from two high-elevation glaciers, the spatial variability of the snowpack composition across Svalbard is comparatively poorly understood. Here, we report the results of the most comprehensive seasonal snow chemistry survey to date, carried out in April 2016 across 22 sites on 7 glaciers across the archipelago. At each glacier, three snow pits were sampled along altitudinal profiles and the collected samples were analysed for major ions (Ca2+, K+, Na+, Mg2+, NH+4, SO42−, Br−, Cl− and NO3−) and stable water isotopes (δ18O, δ2H). The main aims were to investigate the natural and anthropogenic processes influencing the snowpack and to better understand the influence of atmospheric aerosol transport and deposition patterns on the snow chemical composition. The snow deposited in the southern region of Svalbard was characterized by the highest total ionic loads, mainly attributed to sea salt particles. Both NO3− and NH4+ in the seasonal snowpack reflected secondary aerosol formation and post-depositional changes, resulting in very different spatial deposition patterns: NO3− had its highest loading in northwestern Spitsbergen, and NH4+ in the southwest. The Br− enrichment in snow was highest in northeastern glacier sites closest to areas of extensive sea ice coverage. Spatial correlation patterns between Na+ and δ18O suggest that the influence of long-range transport of aerosols on snow chemistry is proportionally greater above 600–700 m a.s.l. |
author2 |
Ampère, Département Bioingénierie (BioIng) Ampère (AMPERE) École Centrale de Lyon (ECL) Université de Lyon-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon) Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-École Centrale de Lyon (ECL) Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE) Franche-Comté Électronique Mécanique, Thermique et Optique - Sciences et Technologies (UMR 6174) (FEMTO-ST) Université de Technologie de Belfort-Montbeliard (UTBM)-Ecole Nationale Supérieure de Mécanique et des Microtechniques (ENSMM)-Centre National de la Recherche Scientifique (CNRS)-Université de Franche-Comté (UFC) Université Bourgogne Franche-Comté COMUE (UBFC)-Université Bourgogne Franche-Comté COMUE (UBFC) |
format |
Article in Journal/Newspaper |
author |
Barbaro, Elena Koziol, Krystyna Björkman, Mats, P Vega, Carmen, P Zdanowicz, Christian Gallet, Jean-Charles Kępski, Daniel Larose, Catherine Luks, Bartłomiej Tolle, Florian Schuler, Thomas, V Uszczyk, Aleksander Spolaor, Andrea |
author_facet |
Barbaro, Elena Koziol, Krystyna Björkman, Mats, P Vega, Carmen, P Zdanowicz, Christian Gallet, Jean-Charles Kępski, Daniel Larose, Catherine Luks, Bartłomiej Tolle, Florian Schuler, Thomas, V Uszczyk, Aleksander Spolaor, Andrea |
author_sort |
Barbaro, Elena |
title |
Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
title_short |
Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
title_full |
Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
title_fullStr |
Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
title_full_unstemmed |
Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard |
title_sort |
measurement report: spatial variations in snowpack ionic chemistry and water stable isotopes across svalbard |
publisher |
HAL CCSD |
publishDate |
2021 |
url |
https://hal.science/hal-03365920 https://hal.science/hal-03365920/document https://hal.science/hal-03365920/file/acp-2020-740.pdf https://doi.org/10.5194/acp-2020-740 |
genre |
Arctic glacier Sea ice Svalbard Spitsbergen |
genre_facet |
Arctic glacier Sea ice Svalbard Spitsbergen |
op_source |
ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://hal.science/hal-03365920 Atmospheric Chemistry and Physics, 2021, ⟨10.5194/acp-2020-740⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.5194/acp-2020-740 hal-03365920 https://hal.science/hal-03365920 https://hal.science/hal-03365920/document https://hal.science/hal-03365920/file/acp-2020-740.pdf doi:10.5194/acp-2020-740 |
op_rights |
http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.5194/acp-2020-740 |
_version_ |
1799475036949577728 |
spelling |
ftinsalyonhal:oai:HAL:hal-03365920v1 2024-05-19T07:36:00+00:00 Measurement report: Spatial variations in snowpack ionic chemistry and water stable isotopes across Svalbard Barbaro, Elena Koziol, Krystyna Björkman, Mats, P Vega, Carmen, P Zdanowicz, Christian Gallet, Jean-Charles Kępski, Daniel Larose, Catherine Luks, Bartłomiej Tolle, Florian Schuler, Thomas, V Uszczyk, Aleksander Spolaor, Andrea Ampère, Département Bioingénierie (BioIng) Ampère (AMPERE) École Centrale de Lyon (ECL) Université de Lyon-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon) Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-École Centrale de Lyon (ECL) Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE) Franche-Comté Électronique Mécanique, Thermique et Optique - Sciences et Technologies (UMR 6174) (FEMTO-ST) Université de Technologie de Belfort-Montbeliard (UTBM)-Ecole Nationale Supérieure de Mécanique et des Microtechniques (ENSMM)-Centre National de la Recherche Scientifique (CNRS)-Université de Franche-Comté (UFC) Université Bourgogne Franche-Comté COMUE (UBFC)-Université Bourgogne Franche-Comté COMUE (UBFC) 2021-03-02 https://hal.science/hal-03365920 https://hal.science/hal-03365920/document https://hal.science/hal-03365920/file/acp-2020-740.pdf https://doi.org/10.5194/acp-2020-740 en eng HAL CCSD European Geosciences Union info:eu-repo/semantics/altIdentifier/doi/10.5194/acp-2020-740 hal-03365920 https://hal.science/hal-03365920 https://hal.science/hal-03365920/document https://hal.science/hal-03365920/file/acp-2020-740.pdf doi:10.5194/acp-2020-740 http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://hal.science/hal-03365920 Atmospheric Chemistry and Physics, 2021, ⟨10.5194/acp-2020-740⟩ Snow Svalbard Arctic inorganic ions water isotopes 31 [SDE]Environmental Sciences info:eu-repo/semantics/article Journal articles 2021 ftinsalyonhal https://doi.org/10.5194/acp-2020-740 2024-04-23T02:49:49Z International audience Abstract. The Svalbard archipelago, between 74° and 81° N, is ∼60 % covered by glaciers and located at the Arctic sea ice edge. The region experiences rapid variations in atmospheric flow during the snow season (from late September to May) and can be affected by air advected both from lower and higher latitudes, which likely impact the chemical composition of snowfall. While long-term changes in Svalbard snow chemistry have been documented in ice cores drilled from two high-elevation glaciers, the spatial variability of the snowpack composition across Svalbard is comparatively poorly understood. Here, we report the results of the most comprehensive seasonal snow chemistry survey to date, carried out in April 2016 across 22 sites on 7 glaciers across the archipelago. At each glacier, three snow pits were sampled along altitudinal profiles and the collected samples were analysed for major ions (Ca2+, K+, Na+, Mg2+, NH+4, SO42−, Br−, Cl− and NO3−) and stable water isotopes (δ18O, δ2H). The main aims were to investigate the natural and anthropogenic processes influencing the snowpack and to better understand the influence of atmospheric aerosol transport and deposition patterns on the snow chemical composition. The snow deposited in the southern region of Svalbard was characterized by the highest total ionic loads, mainly attributed to sea salt particles. Both NO3− and NH4+ in the seasonal snowpack reflected secondary aerosol formation and post-depositional changes, resulting in very different spatial deposition patterns: NO3− had its highest loading in northwestern Spitsbergen, and NH4+ in the southwest. The Br− enrichment in snow was highest in northeastern glacier sites closest to areas of extensive sea ice coverage. Spatial correlation patterns between Na+ and δ18O suggest that the influence of long-range transport of aerosols on snow chemistry is proportionally greater above 600–700 m a.s.l. Article in Journal/Newspaper Arctic glacier Sea ice Svalbard Spitsbergen INSA Lyon HAL (Institut National des Sciences Appliquées) |