Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes

Novel manganese(I)carbonyl complexes of the general formula [Mn(CO)3(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrom...

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Main Authors: Üstün, E., Koç, Ş., Demir, S., Özdemir, I.
Language:unknown
Published: 2016
Subjects:
Orca
Online Access:http://hdl.handle.net/11616/36347
id ftinonuuniv:oai:abakus.inonu.edu.tr:11616/36347
record_format openpolar
spelling ftinonuuniv:oai:abakus.inonu.edu.tr:11616/36347 2023-05-15T17:53:36+02:00 Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes Üstün, E. Koç, Ş. Demir, S. Özdemir, I. 2016 http://hdl.handle.net/11616/36347 unknown 0022328X (ISSN) http://hdl.handle.net/11616/36347 2016 ftinonuuniv 2022-03-28T19:49:37Z Novel manganese(I)carbonyl complexes of the general formula [Mn(CO)3(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (1H NMR, 13C NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals. © 2016 Elsevier B.V. All rights reserved. Other/Unknown Material Orca Unknown
institution Open Polar
collection Unknown
op_collection_id ftinonuuniv
language unknown
description Novel manganese(I)carbonyl complexes of the general formula [Mn(CO)3(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (1H NMR, 13C NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals. © 2016 Elsevier B.V. All rights reserved.
author Üstün, E.
Koç, Ş.
Demir, S.
Özdemir, I.
spellingShingle Üstün, E.
Koç, Ş.
Demir, S.
Özdemir, I.
Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
author_facet Üstün, E.
Koç, Ş.
Demir, S.
Özdemir, I.
author_sort Üstün, E.
title Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
title_short Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
title_full Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
title_fullStr Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
title_full_unstemmed Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)3(bpy)L]PF6 type novel manganese complexes
title_sort carbon monoxide-releasing properties and dft/tddft analysis of [mn(co)3(bpy)l]pf6 type novel manganese complexes
publishDate 2016
url http://hdl.handle.net/11616/36347
genre Orca
genre_facet Orca
op_relation 0022328X (ISSN)
http://hdl.handle.net/11616/36347
_version_ 1766161303256170496

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