Structure, CO-releasing property, electrochemistry, DFT calculation, and

Metal carbonyl complexes are prominent group organometallic compounds because of their applications in industrial and pharmaceutical chemistry. In recent years, metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important signaling molecul...

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Main Authors: Ustun, E, Ayvaz, MC, Celebi, MS, Asci, G, Demir, S, Ozdemir, I
Language:unknown
Published: 2016
Subjects:
Orca
Online Access:http://hdl.handle.net/11616/26073
id ftinonuuniv:oai:abakus.inonu.edu.tr:11616/26073
record_format openpolar
spelling ftinonuuniv:oai:abakus.inonu.edu.tr:11616/26073 2023-05-15T17:53:47+02:00 Structure, CO-releasing property, electrochemistry, DFT calculation, and antioxidant activity of benzimidazole derivative substituted [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexes Ustun, E Ayvaz, MC Celebi, MS Asci, G Demir, S Ozdemir, I 2016 http://hdl.handle.net/11616/26073 unknown http://hdl.handle.net/11616/26073 INORGANICA CHIMICA ACTA 2016 ftinonuuniv 2022-03-28T19:47:53Z Metal carbonyl complexes are prominent group organometallic compounds because of their applications in industrial and pharmaceutical chemistry. In recent years, metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important signaling molecule significantly in pathogenesis of some diseases. Thus, we designed and synthesized novel manganese (I) carbonyl complexes with general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-chlorobenzyl) benzimidazole, N-(2-methoxybenzyl) benzimidazole, N-(2-methylbenzyl) benzimidazole). The complex molecules were characterized by LC-MS, H-1-NMR, C-13-NMR, IR spectroscopy methods and elemental analysis. The CO-releasing properties, antioxidant activities and redox properties of these complexes were investigated. The DFT/TDDFT analyses were made by ORCA package program. (C) 2016 Elsevier B.V. All rights reserved. C1 [Ustun, Elvan; Ayvaz, Melek Col; Celebi, Mutlu Sonmez; Asci, Gizem] Ordu Univ, Fac Sci & Arts, Dept Chem, TR-52200 Ordu, Turkey. [Demir, Serpil; Ozdemir, Ismail] Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey. Other/Unknown Material Orca Unknown
institution Open Polar
collection Unknown
op_collection_id ftinonuuniv
language unknown
description Metal carbonyl complexes are prominent group organometallic compounds because of their applications in industrial and pharmaceutical chemistry. In recent years, metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important signaling molecule significantly in pathogenesis of some diseases. Thus, we designed and synthesized novel manganese (I) carbonyl complexes with general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-chlorobenzyl) benzimidazole, N-(2-methoxybenzyl) benzimidazole, N-(2-methylbenzyl) benzimidazole). The complex molecules were characterized by LC-MS, H-1-NMR, C-13-NMR, IR spectroscopy methods and elemental analysis. The CO-releasing properties, antioxidant activities and redox properties of these complexes were investigated. The DFT/TDDFT analyses were made by ORCA package program. (C) 2016 Elsevier B.V. All rights reserved. C1 [Ustun, Elvan; Ayvaz, Melek Col; Celebi, Mutlu Sonmez; Asci, Gizem] Ordu Univ, Fac Sci & Arts, Dept Chem, TR-52200 Ordu, Turkey. [Demir, Serpil; Ozdemir, Ismail] Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey.
author Ustun, E
Ayvaz, MC
Celebi, MS
Asci, G
Demir, S
Ozdemir, I
spellingShingle Ustun, E
Ayvaz, MC
Celebi, MS
Asci, G
Demir, S
Ozdemir, I
Structure, CO-releasing property, electrochemistry, DFT calculation, and
author_facet Ustun, E
Ayvaz, MC
Celebi, MS
Asci, G
Demir, S
Ozdemir, I
author_sort Ustun, E
title Structure, CO-releasing property, electrochemistry, DFT calculation, and
title_short Structure, CO-releasing property, electrochemistry, DFT calculation, and
title_full Structure, CO-releasing property, electrochemistry, DFT calculation, and
title_fullStr Structure, CO-releasing property, electrochemistry, DFT calculation, and
title_full_unstemmed Structure, CO-releasing property, electrochemistry, DFT calculation, and
title_sort structure, co-releasing property, electrochemistry, dft calculation, and
publishDate 2016
url http://hdl.handle.net/11616/26073
genre Orca
genre_facet Orca
op_source INORGANICA CHIMICA ACTA
op_relation http://hdl.handle.net/11616/26073
_version_ 1766161493563277312

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