Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems
Mantle-derived noble gases in volcanic gases are powerful tracers of terrestrial volatile evolution, as they contain mixtures of both primordial (from Earth's accretion) and secondary (e.g., radiogenic) isotope signals that characterize the composition of deep Earth. However, volcanic gases emi...
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American Association for the Advancement of Science
2023
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Online Access: | http://hdl.handle.net/2122/16672 https://doi.org/10.1126/sciadv.adg2566 |
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ftingv:oai:www.earth-prints.org:2122/16672 2024-02-11T10:05:09+01:00 Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems Bekaert, David V Barry, Peter H Broadley, Michael W Byrne, David J Marty, Bernard Ramirez, Carlos de Moor, J Maarten Rodriguez, Alejandro Hudak, Michael R Subhas, Adam Halldórsson, Sæmundur Ari Stefánsson, Andri Caracausi, Antonio Lloyd, Karen G Giovannelli, Donato Seltzer, Alan #PLACEHOLDER_PARENT_METADATA_VALUE# Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia 2023-04-14 http://hdl.handle.net/2122/16672 https://doi.org/10.1126/sciadv.adg2566 en eng American Association for the Advancement of Science Science Advances /9 (2023) 2375-2548 http://hdl.handle.net/2122/16672 doi:10.1126/sciadv.adg2566 open noble gases earth degassing article 2023 ftingv https://doi.org/10.1126/sciadv.adg2566 2024-01-16T23:26:25Z Mantle-derived noble gases in volcanic gases are powerful tracers of terrestrial volatile evolution, as they contain mixtures of both primordial (from Earth's accretion) and secondary (e.g., radiogenic) isotope signals that characterize the composition of deep Earth. However, volcanic gases emitted through subaerial hydrothermal systems also contain contributions from shallow reservoirs (groundwater, crust, atmosphere). Deconvolving deep and shallow source signals is critical for robust interpretations of mantle-derived signals. Here, we use a novel dynamic mass spectrometry technique to measure argon, krypton, and xenon isotopes in volcanic gas with ultrahigh precision. Data from Iceland, Germany, United States (Yellowstone, Salton Sea), Costa Rica, and Chile show that subsurface isotope fractionation within hydrothermal systems is a globally pervasive and previously unrecognized process causing substantial nonradiogenic Ar-Kr-Xe isotope variations. Quantitatively accounting for this process is vital for accurately interpreting mantle-derived volatile (e.g., noble gas and nitrogen) signals, with profound implications for our understanding of terrestrial volatile evolution. Published eadg2566 OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici JCR Journal Article in Journal/Newspaper Iceland Earth-Prints (Istituto Nazionale di Geofisica e Vulcanologia) Science Advances 9 15 |
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Open Polar |
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Earth-Prints (Istituto Nazionale di Geofisica e Vulcanologia) |
op_collection_id |
ftingv |
language |
English |
topic |
noble gases earth degassing |
spellingShingle |
noble gases earth degassing Bekaert, David V Barry, Peter H Broadley, Michael W Byrne, David J Marty, Bernard Ramirez, Carlos de Moor, J Maarten Rodriguez, Alejandro Hudak, Michael R Subhas, Adam Halldórsson, Sæmundur Ari Stefánsson, Andri Caracausi, Antonio Lloyd, Karen G Giovannelli, Donato Seltzer, Alan Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
topic_facet |
noble gases earth degassing |
description |
Mantle-derived noble gases in volcanic gases are powerful tracers of terrestrial volatile evolution, as they contain mixtures of both primordial (from Earth's accretion) and secondary (e.g., radiogenic) isotope signals that characterize the composition of deep Earth. However, volcanic gases emitted through subaerial hydrothermal systems also contain contributions from shallow reservoirs (groundwater, crust, atmosphere). Deconvolving deep and shallow source signals is critical for robust interpretations of mantle-derived signals. Here, we use a novel dynamic mass spectrometry technique to measure argon, krypton, and xenon isotopes in volcanic gas with ultrahigh precision. Data from Iceland, Germany, United States (Yellowstone, Salton Sea), Costa Rica, and Chile show that subsurface isotope fractionation within hydrothermal systems is a globally pervasive and previously unrecognized process causing substantial nonradiogenic Ar-Kr-Xe isotope variations. Quantitatively accounting for this process is vital for accurately interpreting mantle-derived volatile (e.g., noble gas and nitrogen) signals, with profound implications for our understanding of terrestrial volatile evolution. Published eadg2566 OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici JCR Journal |
author2 |
#PLACEHOLDER_PARENT_METADATA_VALUE# Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia |
format |
Article in Journal/Newspaper |
author |
Bekaert, David V Barry, Peter H Broadley, Michael W Byrne, David J Marty, Bernard Ramirez, Carlos de Moor, J Maarten Rodriguez, Alejandro Hudak, Michael R Subhas, Adam Halldórsson, Sæmundur Ari Stefánsson, Andri Caracausi, Antonio Lloyd, Karen G Giovannelli, Donato Seltzer, Alan |
author_facet |
Bekaert, David V Barry, Peter H Broadley, Michael W Byrne, David J Marty, Bernard Ramirez, Carlos de Moor, J Maarten Rodriguez, Alejandro Hudak, Michael R Subhas, Adam Halldórsson, Sæmundur Ari Stefánsson, Andri Caracausi, Antonio Lloyd, Karen G Giovannelli, Donato Seltzer, Alan |
author_sort |
Bekaert, David V |
title |
Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
title_short |
Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
title_full |
Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
title_fullStr |
Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
title_full_unstemmed |
Ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
title_sort |
ultrahigh-precision noble gas isotope analyses reveal pervasive subsurface fractionation in hydrothermal systems |
publisher |
American Association for the Advancement of Science |
publishDate |
2023 |
url |
http://hdl.handle.net/2122/16672 https://doi.org/10.1126/sciadv.adg2566 |
genre |
Iceland |
genre_facet |
Iceland |
op_relation |
Science Advances /9 (2023) 2375-2548 http://hdl.handle.net/2122/16672 doi:10.1126/sciadv.adg2566 |
op_rights |
open |
op_doi |
https://doi.org/10.1126/sciadv.adg2566 |
container_title |
Science Advances |
container_volume |
9 |
container_issue |
15 |
_version_ |
1790602030128037888 |