A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid
This paper reports a kinetic model for the selfepoxidation of oleic acid with toluene as solvent and Novozym 435 (a commercially available preparation of immobilized Candida antarctica lipase) as catalyst at 30°C. The effects of various parameters on the conversion and rates of reaction were studied...
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Springer Verlag
2001
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| Online Access: | http://repository.ias.ac.in/111866/ https://link.springer.com/article/10.1007/s11746-001-0267-2 |
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ftindianacasci:oai:repository.ias.ac.in:111866 2023-05-15T13:39:33+02:00 A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid Yadav, G. D. Manjula Devi, K. 2001-04 http://repository.ias.ac.in/111866/ https://link.springer.com/article/10.1007/s11746-001-0267-2 unknown Springer Verlag Yadav, G. D. Manjula Devi, K. (2001) A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid Journal of the American Oil Chemists' Society, 78 (4). pp. 347-351. ISSN 0003-021X T Technology (General) Article PeerReviewed 2001 ftindianacasci 2017-09-22T22:09:35Z This paper reports a kinetic model for the selfepoxidation of oleic acid with toluene as solvent and Novozym 435 (a commercially available preparation of immobilized Candida antarctica lipase) as catalyst at 30°C. The effects of various parameters on the conversion and rates of reaction were studied. Both the initial rate and the progress curve data were used to fit an ordered bi-bi model. At low temperatures, the rate of epoxidation was faster than the rate of deactivation of the enzyme by hydrogen peroxide. Article in Journal/Newspaper Antarc* Antarctica Indian Academy of Sciences: Publication of Fellows |
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Open Polar |
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Indian Academy of Sciences: Publication of Fellows |
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ftindianacasci |
| language |
unknown |
| topic |
T Technology (General) |
| spellingShingle |
T Technology (General) Yadav, G. D. Manjula Devi, K. A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| topic_facet |
T Technology (General) |
| description |
This paper reports a kinetic model for the selfepoxidation of oleic acid with toluene as solvent and Novozym 435 (a commercially available preparation of immobilized Candida antarctica lipase) as catalyst at 30°C. The effects of various parameters on the conversion and rates of reaction were studied. Both the initial rate and the progress curve data were used to fit an ordered bi-bi model. At low temperatures, the rate of epoxidation was faster than the rate of deactivation of the enzyme by hydrogen peroxide. |
| format |
Article in Journal/Newspaper |
| author |
Yadav, G. D. Manjula Devi, K. |
| author_facet |
Yadav, G. D. Manjula Devi, K. |
| author_sort |
Yadav, G. D. |
| title |
A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| title_short |
A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| title_full |
A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| title_fullStr |
A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| title_full_unstemmed |
A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| title_sort |
kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid |
| publisher |
Springer Verlag |
| publishDate |
2001 |
| url |
http://repository.ias.ac.in/111866/ https://link.springer.com/article/10.1007/s11746-001-0267-2 |
| genre |
Antarc* Antarctica |
| genre_facet |
Antarc* Antarctica |
| op_relation |
Yadav, G. D. Manjula Devi, K. (2001) A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid Journal of the American Oil Chemists' Society, 78 (4). pp. 347-351. ISSN 0003-021X |
| _version_ |
1766120219646885888 |