Enzymatic synthesis of perlauric acid using Novozym 435
For the biocatalytic synthesis of perlauric acid, Novozym 435 (Candida antarctica lipase immobilized on polyacrylic resin) was found to be the most active catalyst and toluene was the most suitable solvent. The effects of various parameters on conversion and rates of reaction were studied in the abs...
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ftindianacasci:oai:repository.ias.ac.in:111860 2023-05-15T13:39:33+02:00 Enzymatic synthesis of perlauric acid using Novozym 435 Yadav, Ganapati D. Manjula Devi, K. 2002-03 http://repository.ias.ac.in/111860/ http://www.sciencedirect.com/science/article/pii/S1369703X01001644 unknown Elsevier Science Yadav, Ganapati D. Manjula Devi, K. (2002) Enzymatic synthesis of perlauric acid using Novozym 435 Biochemical Engineering Journal, 10 (2). pp. 93-101. ISSN 1369-703X T Technology (General) Article PeerReviewed 2002 ftindianacasci 2017-09-22T22:09:35Z For the biocatalytic synthesis of perlauric acid, Novozym 435 (Candida antarctica lipase immobilized on polyacrylic resin) was found to be the most active catalyst and toluene was the most suitable solvent. The effects of various parameters on conversion and rates of reaction were studied in the absence of mass transfer limitations. Reusability studies indicated that there was enzyme deactivation and from a preliminary study of the deactivation, it was observed that the deactivation obeys a pseudo-first-order model. Lineweaver–Burk plots indicated the formation of a ternary complex. A model based on ordered bi–bi mechanism was found to fit the initial rate data very well and using this model, some kinetic parameters were calculated by non-linear regression analysis. Article in Journal/Newspaper Antarc* Antarctica Indian Academy of Sciences: Publication of Fellows |
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Indian Academy of Sciences: Publication of Fellows |
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T Technology (General) |
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T Technology (General) Yadav, Ganapati D. Manjula Devi, K. Enzymatic synthesis of perlauric acid using Novozym 435 |
topic_facet |
T Technology (General) |
description |
For the biocatalytic synthesis of perlauric acid, Novozym 435 (Candida antarctica lipase immobilized on polyacrylic resin) was found to be the most active catalyst and toluene was the most suitable solvent. The effects of various parameters on conversion and rates of reaction were studied in the absence of mass transfer limitations. Reusability studies indicated that there was enzyme deactivation and from a preliminary study of the deactivation, it was observed that the deactivation obeys a pseudo-first-order model. Lineweaver–Burk plots indicated the formation of a ternary complex. A model based on ordered bi–bi mechanism was found to fit the initial rate data very well and using this model, some kinetic parameters were calculated by non-linear regression analysis. |
format |
Article in Journal/Newspaper |
author |
Yadav, Ganapati D. Manjula Devi, K. |
author_facet |
Yadav, Ganapati D. Manjula Devi, K. |
author_sort |
Yadav, Ganapati D. |
title |
Enzymatic synthesis of perlauric acid using Novozym 435 |
title_short |
Enzymatic synthesis of perlauric acid using Novozym 435 |
title_full |
Enzymatic synthesis of perlauric acid using Novozym 435 |
title_fullStr |
Enzymatic synthesis of perlauric acid using Novozym 435 |
title_full_unstemmed |
Enzymatic synthesis of perlauric acid using Novozym 435 |
title_sort |
enzymatic synthesis of perlauric acid using novozym 435 |
publisher |
Elsevier Science |
publishDate |
2002 |
url |
http://repository.ias.ac.in/111860/ http://www.sciencedirect.com/science/article/pii/S1369703X01001644 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
Yadav, Ganapati D. Manjula Devi, K. (2002) Enzymatic synthesis of perlauric acid using Novozym 435 Biochemical Engineering Journal, 10 (2). pp. 93-101. ISSN 1369-703X |
_version_ |
1766120217443827712 |