Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air
A first year-round firn air sampling carried out at the British Antarctic station Halley in 2003 shows isotope and CO2 changes owing to diffusive mixing driven by seasonal variations of surface temperature, and gas composition of the atmosphere. Seasonal firn temperatures are well reproduced from th...
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fthokunivhus:oai:eprints.lib.hokudai.ac.jp:2115/45452 2023-05-15T13:42:37+02:00 Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air Weiler, Karin Schwander, Jakob Leuenberger, Markus Blunier, Thomas Mulvaney, Robert Anderson, Philip S. Salmon, Rhian Sturges, William T. http://hdl.handle.net/2115/45452 eng eng Institute of Low Temperature Science, Hokkaido University Physics of Ice Core Records II : Papers collected after the 2nd International Workshop on Physics of Ice Core Records, held in Sapporo, Japan, 2-6 February 2007. Edited by Takeo Hondoh http://hdl.handle.net/2115/45452 firn air thermal diffusion thermal diffusion sensitivity C02 Halley 400 bulletin (article) fthokunivhus 2022-11-18T01:02:09Z A first year-round firn air sampling carried out at the British Antarctic station Halley in 2003 shows isotope and CO2 changes owing to diffusive mixing driven by seasonal variations of surface temperature, and gas composition of the atmosphere. Seasonal firn temperatures are well reproduced from the atmospheric temperature history. Based on these profiles thermal diffusion is forced with thermal diffusion factors αT with respect to air. Application of the available literature data for αT (15N14 / N2) leads to a proper prediction of the seasonal thermal amplitude during the entire year. By forcing thermal fractionation with αT as derived from two different model approaches and taking into account literature data reasonable results can be achieved for CO2 but not for thermal fractionation of 18016O and 16O2 in air. The latter is attributed to an inappropriate reproduction of the intermolecular interaction forces by either model. Neither thermal diffusion nor annual variations in the atmospheric CO2 concentration seem to have a substancial effect on the CO2 concentration finally conserved in air bubbles at the close-off level. III. Firn densification, close-off and chronology Article in Journal/Newspaper Antarc* Antarctic Hokkaido University Collection of Scholarly and Academic Papers (HUSCAP) Antarctic |
institution |
Open Polar |
collection |
Hokkaido University Collection of Scholarly and Academic Papers (HUSCAP) |
op_collection_id |
fthokunivhus |
language |
English |
topic |
firn air thermal diffusion thermal diffusion sensitivity C02 Halley 400 |
spellingShingle |
firn air thermal diffusion thermal diffusion sensitivity C02 Halley 400 Weiler, Karin Schwander, Jakob Leuenberger, Markus Blunier, Thomas Mulvaney, Robert Anderson, Philip S. Salmon, Rhian Sturges, William T. Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
topic_facet |
firn air thermal diffusion thermal diffusion sensitivity C02 Halley 400 |
description |
A first year-round firn air sampling carried out at the British Antarctic station Halley in 2003 shows isotope and CO2 changes owing to diffusive mixing driven by seasonal variations of surface temperature, and gas composition of the atmosphere. Seasonal firn temperatures are well reproduced from the atmospheric temperature history. Based on these profiles thermal diffusion is forced with thermal diffusion factors αT with respect to air. Application of the available literature data for αT (15N14 / N2) leads to a proper prediction of the seasonal thermal amplitude during the entire year. By forcing thermal fractionation with αT as derived from two different model approaches and taking into account literature data reasonable results can be achieved for CO2 but not for thermal fractionation of 18016O and 16O2 in air. The latter is attributed to an inappropriate reproduction of the intermolecular interaction forces by either model. Neither thermal diffusion nor annual variations in the atmospheric CO2 concentration seem to have a substancial effect on the CO2 concentration finally conserved in air bubbles at the close-off level. III. Firn densification, close-off and chronology |
format |
Article in Journal/Newspaper |
author |
Weiler, Karin Schwander, Jakob Leuenberger, Markus Blunier, Thomas Mulvaney, Robert Anderson, Philip S. Salmon, Rhian Sturges, William T. |
author_facet |
Weiler, Karin Schwander, Jakob Leuenberger, Markus Blunier, Thomas Mulvaney, Robert Anderson, Philip S. Salmon, Rhian Sturges, William T. |
author_sort |
Weiler, Karin |
title |
Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
title_short |
Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
title_full |
Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
title_fullStr |
Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
title_full_unstemmed |
Seasonal Variations of Isotope Ratios and CO2 Concentrations in Firn Air |
title_sort |
seasonal variations of isotope ratios and co2 concentrations in firn air |
publisher |
Institute of Low Temperature Science, Hokkaido University |
url |
http://hdl.handle.net/2115/45452 |
geographic |
Antarctic |
geographic_facet |
Antarctic |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_relation |
Physics of Ice Core Records II : Papers collected after the 2nd International Workshop on Physics of Ice Core Records, held in Sapporo, Japan, 2-6 February 2007. Edited by Takeo Hondoh http://hdl.handle.net/2115/45452 |
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1766170125934788608 |