Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process
A novel microwave barrel reactor (MBR) was constructed and used in lipase catalyzed biolubricant synthesis. The MBR is thought as a versatile process tool for biotransformation and green chemistry that overcomes current size limitations in microwave reactors. A lipase mediated biotransformation in t...
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fthessoch:oai:hesso.tind.io:8997 2023-10-09T21:46:32+02:00 Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process Happe, Manuel Grand, Pascal Farquet, Sébastien Aeby, Sandrine Héritier, Jean-Claude Corthay, François Mabillard, Eric Marti, Roger Vanoli, Ennio Grogg, Alain-François Nussbaum, Samuel Roduit, Alain Tièche, François Salem, Sam Constantin, Carole Schmitt, Esther Zahno, Silvan Ellert, Christoph Habib, Ahmed Wyss, Julien Fischer, Fabian 2021-11-19T14:38:53Z https://doi.org/10.1039/c2gc35479a https://arodes.hes-so.ch/record/8997/files/Happe_2012_microwave_barrel_reactor_use_trimethylolpropane_oleate_synthesis_candida_antartica_lipase_biphasic_non-solvent_process.pdf http://arodes.hes-so.ch/record/8997 eng eng doi:10.1039/c2gc35479a https://arodes.hes-so.ch/record/8997/files/Happe_2012_microwave_barrel_reactor_use_trimethylolpropane_oleate_synthesis_candida_antartica_lipase_biphasic_non-solvent_process.pdf http://arodes.hes-so.ch/record/8997 http://arodes.hes-so.ch/record/8997 Text 2021 fthessoch https://doi.org/10.1039/c2gc35479a 2023-09-10T23:56:04Z A novel microwave barrel reactor (MBR) was constructed and used in lipase catalyzed biolubricant synthesis. The MBR is thought as a versatile process tool for biotransformation and green chemistry that overcomes current size limitations in microwave reactors. A lipase mediated biotransformation in the MBR was compared to a state of the art jacketed reactor with external heat exchanger. Oleic acid and trimethylolpropane converted quantitatively (96%) into biolubricants using microwave induction. The heat dissipation in the MBR was analyzed by thermal imaging and inside thermometry. Conversion rates, rate constants and pseudo reaction orders were in line with conventional processing and no microwave effect was detected. The MBR is a versatile new reactor for non solvent, minimal and common solvent processing in the microwave field. While the subject of investigations was biolubricant synthesis in the MBR, the technology described is of wider potential interest in the field of biomass processing and sustainable chemical manufacture. Text Antarc* Antarctica Hes-so: ArODES Open Archive (University of Applied Sciences and Arts Western Switzerland) Green Chemistry 14 8 2337 |
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Open Polar |
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Hes-so: ArODES Open Archive (University of Applied Sciences and Arts Western Switzerland) |
op_collection_id |
fthessoch |
language |
English |
description |
A novel microwave barrel reactor (MBR) was constructed and used in lipase catalyzed biolubricant synthesis. The MBR is thought as a versatile process tool for biotransformation and green chemistry that overcomes current size limitations in microwave reactors. A lipase mediated biotransformation in the MBR was compared to a state of the art jacketed reactor with external heat exchanger. Oleic acid and trimethylolpropane converted quantitatively (96%) into biolubricants using microwave induction. The heat dissipation in the MBR was analyzed by thermal imaging and inside thermometry. Conversion rates, rate constants and pseudo reaction orders were in line with conventional processing and no microwave effect was detected. The MBR is a versatile new reactor for non solvent, minimal and common solvent processing in the microwave field. While the subject of investigations was biolubricant synthesis in the MBR, the technology described is of wider potential interest in the field of biomass processing and sustainable chemical manufacture. |
format |
Text |
author |
Happe, Manuel Grand, Pascal Farquet, Sébastien Aeby, Sandrine Héritier, Jean-Claude Corthay, François Mabillard, Eric Marti, Roger Vanoli, Ennio Grogg, Alain-François Nussbaum, Samuel Roduit, Alain Tièche, François Salem, Sam Constantin, Carole Schmitt, Esther Zahno, Silvan Ellert, Christoph Habib, Ahmed Wyss, Julien Fischer, Fabian |
spellingShingle |
Happe, Manuel Grand, Pascal Farquet, Sébastien Aeby, Sandrine Héritier, Jean-Claude Corthay, François Mabillard, Eric Marti, Roger Vanoli, Ennio Grogg, Alain-François Nussbaum, Samuel Roduit, Alain Tièche, François Salem, Sam Constantin, Carole Schmitt, Esther Zahno, Silvan Ellert, Christoph Habib, Ahmed Wyss, Julien Fischer, Fabian Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
author_facet |
Happe, Manuel Grand, Pascal Farquet, Sébastien Aeby, Sandrine Héritier, Jean-Claude Corthay, François Mabillard, Eric Marti, Roger Vanoli, Ennio Grogg, Alain-François Nussbaum, Samuel Roduit, Alain Tièche, François Salem, Sam Constantin, Carole Schmitt, Esther Zahno, Silvan Ellert, Christoph Habib, Ahmed Wyss, Julien Fischer, Fabian |
author_sort |
Happe, Manuel |
title |
Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
title_short |
Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
title_full |
Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
title_fullStr |
Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
title_full_unstemmed |
Microwave barrel reactor use in trimethylolpropane oleate synthesis by Candida antarctica lipase in a biphasic non-solvent process |
title_sort |
microwave barrel reactor use in trimethylolpropane oleate synthesis by candida antarctica lipase in a biphasic non-solvent process |
publishDate |
2021 |
url |
https://doi.org/10.1039/c2gc35479a https://arodes.hes-so.ch/record/8997/files/Happe_2012_microwave_barrel_reactor_use_trimethylolpropane_oleate_synthesis_candida_antartica_lipase_biphasic_non-solvent_process.pdf http://arodes.hes-so.ch/record/8997 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
http://arodes.hes-so.ch/record/8997 |
op_relation |
doi:10.1039/c2gc35479a https://arodes.hes-so.ch/record/8997/files/Happe_2012_microwave_barrel_reactor_use_trimethylolpropane_oleate_synthesis_candida_antartica_lipase_biphasic_non-solvent_process.pdf http://arodes.hes-so.ch/record/8997 |
op_doi |
https://doi.org/10.1039/c2gc35479a |
container_title |
Green Chemistry |
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14 |
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8 |
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2337 |
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1779322251180507136 |