Raman characterization of carbonaceous matter in CONCORDIA Antarctic micrometeorites

• Published in: Meteoritics & Planetary Science
• Main Authors: Dobrica, E., Engrand, C., Quirico, E., Montagnac, G., Duprat, J.
• Other Authors: CSNSM AS, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Institut de Planétologie et d'Astrophysique de Grenoble (IPAG), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS), École normale supérieure de Lyon (ENS de Lyon), Université de Lyon, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), Université de Lyon-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS)
• Format: Article in Journal/Newspaper
• Language: English
• Published: CCSD 2011
• Subjects: INTERPLANETARY DUST PARTICLES; COMET HALLEY DUST; INSOLUBLE ORGANIC-MATTER; MICRO-RAMAN; COSMIC SPHERULES; ACCRETION RATE; SPECTROSCOPY; CHONDRITES; NITROGEN; METEORITES; [PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]; [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]; Antarctic; Antarc*
• Online Access: https://in2p3.hal.science/in2p3-00634834; https://doi.org/10.1111/j.1945-5100.2011.01235.x

We report a multi-wavelength Raman spectroscopy study of carbonaceous matter in 38 Antarctic micrometeorites (AMMs) from the 2006 CONCORDIA collection. The particles were selected as a function of their degree of thermal alteration developed during the deceleration in the atmosphere. These samples range from unmelted (fine-grained-Fg; ultracarbonaceous-UCAMMs) to partially melted AMMs (scorias-Sc) and completely melted particles (cosmic spherules-CS). More than half of the analyzed AMMs contain a substantial amount of polyaromatic carbonaceous matter with a high degree of disorder. The proportion of particles where carbon is not detected increase from the Fg to the Fg-Sc and to the Sc-AMMs, and no carbon is detected in CS. In addition, the spectral characteristics of the G and D bands of the carbonaceous matter in Sc-AMMs plot apart from the trend formed by the data from Fg-AMMs and UCAMMs. These results suggest that oxidation processes occurred during the deceleration of the particles in the atmosphere. In Fg-AMMs and UCAMMs, the spectral characteristics of the G and D bands reveal the high degree of disorder of the carbonaceous matter, precluding a long duration thermal metamorphism on the parent body and suggesting that AMMs have a connection with C1-C2 chondrites. The Raman parameters of the deuterium-rich carbonaceous matter of UCAMMs do not differ from that of Fg-AMMs. Using a 244 nm excitation, we detected the cyanide (-CN) functional group for the first time in a UCAMM, reinforcing the likely cometary origin of this type of micrometeorites.