Möbius-Hückel topology switching in an expanded porphyrin cation radical as studied by EPR and ENDOR spectroscopy

• Main Authors: Möbius, Klaus, Plato, Martin, Klihm, Gudrun, Laurich, Christoph, Savitsky, Anton, Lubitz, Wolfgang, Szyszko, Bartosz, Stępień, Marcin, Latos-Grażyński, Lechosław
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2015
• Subjects: ddc:540; ddc:530; Möbius; Orca
• Online Access: https://refubium.fu-berlin.de/handle/fub188/15004; https://doi.org/10.17169/refubium-19192; https://doi.org/10.1039/c4cp05745g

The symmetry of the arrangement of objects has fascinated philosophers, artists and scientists for a long time, and still does. Symmetries often exist in nature, but are also created artificially, for instance by chemical synthesis of novel molecules and materials. The one-sided, non-orientable Möbi...