Data_Sheet_1_Carbon Dynamics During the Formation of Sea Ice at Different Growth Rates.docx

• Main Authors: Daniela König, Lisa A. Miller, Kyle G. Simpson, Svein Vagle
• Format: Dataset
• Language: unknown
• Published: 2018
• Subjects: Solid Earth Sciences; Climate Science; Atmospheric Sciences not elsewhere classified; Exploration Geochemistry; Inorganic Geochemistry; Isotope Geochemistry; Organic Geochemistry; Geochemistry not elsewhere classified; Igneous and Metamorphic Petrology; Ore Deposit Petrology; Palaeontology (incl. Palynology); Structural Geology; Tectonics; Volcanology; Geology not elsewhere classified; Seismology and Seismic Exploration; Glaciology; Hydrogeology; Natural Hazards; Quaternary Environments; Earth Sciences not elsewhere classified; Evolutionary Impacts of Climate Change; sea ice; growth rates; CO2 system; brine drainage; tank experiment; Sea ice
• Online Access: https://doi.org/10.3389/feart.2018.00234.s001; https://figshare.com/articles/Data_Sheet_1_Carbon_Dynamics_During_the_Formation_of_Sea_Ice_at_Different_Growth_Rates_docx/7477832

Controlled laboratory experiments have shed new light on the potential importance of brine rejection during sea-ice formation for carbon dioxide sequestration in the ocean. We grew ice in an experimental seawater tank (1 m 3 ) under abiotic conditions at three different air temperatures (−40°C, −25°C, −15°C) to determine how different ice growth rates affect the allocation of carbon to ice, water, or air. Carbonate system parameters were determined by discrete sampling of ice cores and water, as well as continuous measurements by multiple sensors deployed mainly in the water phase. A budgetary approach revealed that of the initial total inorganic carbon (TIC) content of the water converted to ice, only 28–29% was located in the ice phase by the end of the experiments run at the warmest temperature, whereas for the coldest ambient temperature, 46–47% of the carbon remained in the ice. Exchange with air appeared to be negligible, with the majority of the TIC remaining in the under-ice water (53–72%). Along with a good correlation between salinity and TIC in the ice and water samples, these observations highlight the importance of brine drainage to TIC redistribution during ice formation. For experiments without mixing of the under-ice water, the sensor data further suggested stronger stratification, likely related to release of denser brine, and thus potentially larger carbon sequestration for ice grown at a colder temperature and faster growth rate.