Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF
Lignocellulose can be converted sustainably to fuels, power and value-added chemicals like fatty acid esters. This study presents a concept for the first eco-friendly enzymatic synthesis of economically important fatty acid sugar esters based on lignocellulosic biomass. To achieve this, beech wood c...
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ftfrontimediafig:oai:figshare.com:article/7082759 2023-05-15T13:56:49+02:00 Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF Sascha Siebenhaller Jennifer Kirchhoff Frank Kirschhöfer Gerald Brenner-Weiß Claudia Muhle-Goll Burkhard Luy Fabian Haitz Thomas Hahn Susanne Zibek Christoph Syldatk Katrin Ochsenreither 2018-09-13T10:24:59Z https://doi.org/10.3389/fchem.2018.00421.s004 https://figshare.com/articles/Data_Sheet_4_Integrated_Process_for_the_Enzymatic_Production_of_Fatty_Acid_Sugar_Esters_Completely_Based_on_Lignocellulosic_Substrates_PDF/7082759 unknown doi:10.3389/fchem.2018.00421.s004 https://figshare.com/articles/Data_Sheet_4_Integrated_Process_for_the_Enzymatic_Production_of_Fatty_Acid_Sugar_Esters_Completely_Based_on_Lignocellulosic_Substrates_PDF/7082759 CC BY 4.0 CC-BY Biochemistry Environmental Chemistry Geochemistry Organic Chemistry Inorganic Chemistry Nuclear Chemistry Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics) Medical Biochemistry and Metabolomics not elsewhere classified Food Chemistry and Molecular Gastronomy (excl. Wine) Analytical Biochemistry Cell Neurochemistry Enzymes Electroanalytical Chemistry Analytical Chemistry not elsewhere classified Organic Green Chemistry Physical Organic Chemistry Catalysis and Mechanisms of Reactions Environmental Chemistry (incl. Atmospheric Chemistry) Cryptococcus curvatus single cell oil lignocellulose sugar esters synthesis deep eutectic solvents biorefinery Dataset 2018 ftfrontimediafig https://doi.org/10.3389/fchem.2018.00421.s004 2018-09-19T22:57:52Z Lignocellulose can be converted sustainably to fuels, power and value-added chemicals like fatty acid esters. This study presents a concept for the first eco-friendly enzymatic synthesis of economically important fatty acid sugar esters based on lignocellulosic biomass. To achieve this, beech wood cellulose fiber hydrolysate was applied in three manners: as sugar component, as part of the deep eutectic solvent (DES) reaction system and as carbon source for the microbial production of the fatty acid component. These fatty acids were gained from single cell oil produced by the oleaginous yeast Cryptococcus curvatus cultivated with cellulose fiber hydrolysate as carbon source. Afterwards, an immobilized Candida antarctica lipase B was used as the biocatalyst in DES to esterify sugars with fatty acids. Properties of the DES were determined and synthesized sugar mono- and di-esters were identified and characterized using TLC, MS, and NMR. Using this approach, sugar esters were successfully synthesized which are 100% based on lignocellulosic biomass. Dataset Antarc* Antarctica Frontiers: Figshare |
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Open Polar |
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Frontiers: Figshare |
op_collection_id |
ftfrontimediafig |
language |
unknown |
topic |
Biochemistry Environmental Chemistry Geochemistry Organic Chemistry Inorganic Chemistry Nuclear Chemistry Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics) Medical Biochemistry and Metabolomics not elsewhere classified Food Chemistry and Molecular Gastronomy (excl. Wine) Analytical Biochemistry Cell Neurochemistry Enzymes Electroanalytical Chemistry Analytical Chemistry not elsewhere classified Organic Green Chemistry Physical Organic Chemistry Catalysis and Mechanisms of Reactions Environmental Chemistry (incl. Atmospheric Chemistry) Cryptococcus curvatus single cell oil lignocellulose sugar esters synthesis deep eutectic solvents biorefinery |
spellingShingle |
Biochemistry Environmental Chemistry Geochemistry Organic Chemistry Inorganic Chemistry Nuclear Chemistry Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics) Medical Biochemistry and Metabolomics not elsewhere classified Food Chemistry and Molecular Gastronomy (excl. Wine) Analytical Biochemistry Cell Neurochemistry Enzymes Electroanalytical Chemistry Analytical Chemistry not elsewhere classified Organic Green Chemistry Physical Organic Chemistry Catalysis and Mechanisms of Reactions Environmental Chemistry (incl. Atmospheric Chemistry) Cryptococcus curvatus single cell oil lignocellulose sugar esters synthesis deep eutectic solvents biorefinery Sascha Siebenhaller Jennifer Kirchhoff Frank Kirschhöfer Gerald Brenner-Weiß Claudia Muhle-Goll Burkhard Luy Fabian Haitz Thomas Hahn Susanne Zibek Christoph Syldatk Katrin Ochsenreither Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
topic_facet |
Biochemistry Environmental Chemistry Geochemistry Organic Chemistry Inorganic Chemistry Nuclear Chemistry Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics) Medical Biochemistry and Metabolomics not elsewhere classified Food Chemistry and Molecular Gastronomy (excl. Wine) Analytical Biochemistry Cell Neurochemistry Enzymes Electroanalytical Chemistry Analytical Chemistry not elsewhere classified Organic Green Chemistry Physical Organic Chemistry Catalysis and Mechanisms of Reactions Environmental Chemistry (incl. Atmospheric Chemistry) Cryptococcus curvatus single cell oil lignocellulose sugar esters synthesis deep eutectic solvents biorefinery |
description |
Lignocellulose can be converted sustainably to fuels, power and value-added chemicals like fatty acid esters. This study presents a concept for the first eco-friendly enzymatic synthesis of economically important fatty acid sugar esters based on lignocellulosic biomass. To achieve this, beech wood cellulose fiber hydrolysate was applied in three manners: as sugar component, as part of the deep eutectic solvent (DES) reaction system and as carbon source for the microbial production of the fatty acid component. These fatty acids were gained from single cell oil produced by the oleaginous yeast Cryptococcus curvatus cultivated with cellulose fiber hydrolysate as carbon source. Afterwards, an immobilized Candida antarctica lipase B was used as the biocatalyst in DES to esterify sugars with fatty acids. Properties of the DES were determined and synthesized sugar mono- and di-esters were identified and characterized using TLC, MS, and NMR. Using this approach, sugar esters were successfully synthesized which are 100% based on lignocellulosic biomass. |
format |
Dataset |
author |
Sascha Siebenhaller Jennifer Kirchhoff Frank Kirschhöfer Gerald Brenner-Weiß Claudia Muhle-Goll Burkhard Luy Fabian Haitz Thomas Hahn Susanne Zibek Christoph Syldatk Katrin Ochsenreither |
author_facet |
Sascha Siebenhaller Jennifer Kirchhoff Frank Kirschhöfer Gerald Brenner-Weiß Claudia Muhle-Goll Burkhard Luy Fabian Haitz Thomas Hahn Susanne Zibek Christoph Syldatk Katrin Ochsenreither |
author_sort |
Sascha Siebenhaller |
title |
Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
title_short |
Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
title_full |
Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
title_fullStr |
Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
title_full_unstemmed |
Data_Sheet_4_Integrated Process for the Enzymatic Production of Fatty Acid Sugar Esters Completely Based on Lignocellulosic Substrates.PDF |
title_sort |
data_sheet_4_integrated process for the enzymatic production of fatty acid sugar esters completely based on lignocellulosic substrates.pdf |
publishDate |
2018 |
url |
https://doi.org/10.3389/fchem.2018.00421.s004 https://figshare.com/articles/Data_Sheet_4_Integrated_Process_for_the_Enzymatic_Production_of_Fatty_Acid_Sugar_Esters_Completely_Based_on_Lignocellulosic_Substrates_PDF/7082759 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
doi:10.3389/fchem.2018.00421.s004 https://figshare.com/articles/Data_Sheet_4_Integrated_Process_for_the_Enzymatic_Production_of_Fatty_Acid_Sugar_Esters_Completely_Based_on_Lignocellulosic_Substrates_PDF/7082759 |
op_rights |
CC BY 4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.3389/fchem.2018.00421.s004 |
_version_ |
1766264395668652032 |