Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx
We investigated the pore fluid and methane-derived authigenic carbonate (MDAC) chemistry from the ARAON Mounds in the Chukchi Sea to reveal how methane (CH 4 ) seepage impacts their compositional and isotopic properties. During the ARA07C and ARA09C Expeditions, many in situ gas hydrates (GHs) and M...
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2022
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Online Access: | https://doi.org/10.3389/fmars.2022.944841.s001 https://figshare.com/articles/dataset/Table_1_Impact_of_High_Methane_Flux_on_the_Properties_of_Pore_Fluid_and_Methane-Derived_Authigenic_Carbonate_in_the_ARAON_Mounds_Chukchi_Sea_xlsx/20295540 |
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ftfrontimediafig:oai:figshare.com:article/20295540 2023-05-15T15:15:24+02:00 Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx Ji-Hoon Kim Myong-Ho Park Dong-Hun Lee Hirotsugu Minami Young-Keun Jin Akihiro Hachikubo Jin Hur Jong-Sik Ryu Moo-Hee Kang Kwangchul Jang Masato Kida Yongwon Seo Meilian Chen Jong Kuk Hong Yungoo Song Sanghee Park 2022-07-13T05:13:28Z https://doi.org/10.3389/fmars.2022.944841.s001 https://figshare.com/articles/dataset/Table_1_Impact_of_High_Methane_Flux_on_the_Properties_of_Pore_Fluid_and_Methane-Derived_Authigenic_Carbonate_in_the_ARAON_Mounds_Chukchi_Sea_xlsx/20295540 unknown doi:10.3389/fmars.2022.944841.s001 https://figshare.com/articles/dataset/Table_1_Impact_of_High_Methane_Flux_on_the_Properties_of_Pore_Fluid_and_Methane-Derived_Authigenic_Carbonate_in_the_ARAON_Mounds_Chukchi_Sea_xlsx/20295540 CC BY 4.0 CC-BY Oceanography Marine Biology Marine Geoscience Biological Oceanography Chemical Oceanography Physical Oceanography Marine Engineering pore fluid methane flux gas hydrate MDAC ARAON Mounds Dataset 2022 ftfrontimediafig https://doi.org/10.3389/fmars.2022.944841.s001 2022-07-13T23:03:55Z We investigated the pore fluid and methane-derived authigenic carbonate (MDAC) chemistry from the ARAON Mounds in the Chukchi Sea to reveal how methane (CH 4 ) seepage impacts their compositional and isotopic properties. During the ARA07C and ARA09C Expeditions, many in situ gas hydrates (GHs) and MDACs were found near the seafloor. The fluid chemistry has been considerably modified in association with the high CH 4 flux and its related byproducts (GHs and MDACs). Compared to Site ARA09C-St 08 (reference site), which displays a linear SO 4 2- downcore profile, the other sites (e.g., ARA07C-St 13, ARA07C-St 14, ARA09C-St 04, ARA09C-St 07, and ARA09C-St 12) that are found byproducts exhibit concave-up and/or kink type SO 4 2- profiles. The physical properties and fluid pathways in sediment columns have been altered by these byproducts, which prevents the steady state condition of the dissolved species through them. Consequently, chemical zones are separated between bearing and non-bearing byproducts intervals under non-steady state condition from the seafloor to the sulfate-methane transition (SMT). GH dissociation also significantly impacts pore fluid properties (e.g., low Cl - , enriched δD and δ 18 O). The upward CH 4 with depleted δ 13 C from the thermogenic origin affects the chemical signatures of MDACs. The enriched δ 18 O fluid from GH dissociation also influences the properties of MDACs. Thus, in the ARAON Mounds, the chemistry of the fluid and MDAC has significantly changed, most likely responding to the CH 4 flux and GH dissociation through geological time. Overall, our findings will improve the understanding and prediction of the pore fluid and MDAC chemistry in the Arctic Ocean related to CH 4 seepage by global climate change. Dataset Arctic Arctic Ocean Chukchi Chukchi Sea Climate change Frontiers: Figshare Arctic Arctic Ocean Chukchi Sea |
institution |
Open Polar |
collection |
Frontiers: Figshare |
op_collection_id |
ftfrontimediafig |
language |
unknown |
topic |
Oceanography Marine Biology Marine Geoscience Biological Oceanography Chemical Oceanography Physical Oceanography Marine Engineering pore fluid methane flux gas hydrate MDAC ARAON Mounds |
spellingShingle |
Oceanography Marine Biology Marine Geoscience Biological Oceanography Chemical Oceanography Physical Oceanography Marine Engineering pore fluid methane flux gas hydrate MDAC ARAON Mounds Ji-Hoon Kim Myong-Ho Park Dong-Hun Lee Hirotsugu Minami Young-Keun Jin Akihiro Hachikubo Jin Hur Jong-Sik Ryu Moo-Hee Kang Kwangchul Jang Masato Kida Yongwon Seo Meilian Chen Jong Kuk Hong Yungoo Song Sanghee Park Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
topic_facet |
Oceanography Marine Biology Marine Geoscience Biological Oceanography Chemical Oceanography Physical Oceanography Marine Engineering pore fluid methane flux gas hydrate MDAC ARAON Mounds |
description |
We investigated the pore fluid and methane-derived authigenic carbonate (MDAC) chemistry from the ARAON Mounds in the Chukchi Sea to reveal how methane (CH 4 ) seepage impacts their compositional and isotopic properties. During the ARA07C and ARA09C Expeditions, many in situ gas hydrates (GHs) and MDACs were found near the seafloor. The fluid chemistry has been considerably modified in association with the high CH 4 flux and its related byproducts (GHs and MDACs). Compared to Site ARA09C-St 08 (reference site), which displays a linear SO 4 2- downcore profile, the other sites (e.g., ARA07C-St 13, ARA07C-St 14, ARA09C-St 04, ARA09C-St 07, and ARA09C-St 12) that are found byproducts exhibit concave-up and/or kink type SO 4 2- profiles. The physical properties and fluid pathways in sediment columns have been altered by these byproducts, which prevents the steady state condition of the dissolved species through them. Consequently, chemical zones are separated between bearing and non-bearing byproducts intervals under non-steady state condition from the seafloor to the sulfate-methane transition (SMT). GH dissociation also significantly impacts pore fluid properties (e.g., low Cl - , enriched δD and δ 18 O). The upward CH 4 with depleted δ 13 C from the thermogenic origin affects the chemical signatures of MDACs. The enriched δ 18 O fluid from GH dissociation also influences the properties of MDACs. Thus, in the ARAON Mounds, the chemistry of the fluid and MDAC has significantly changed, most likely responding to the CH 4 flux and GH dissociation through geological time. Overall, our findings will improve the understanding and prediction of the pore fluid and MDAC chemistry in the Arctic Ocean related to CH 4 seepage by global climate change. |
format |
Dataset |
author |
Ji-Hoon Kim Myong-Ho Park Dong-Hun Lee Hirotsugu Minami Young-Keun Jin Akihiro Hachikubo Jin Hur Jong-Sik Ryu Moo-Hee Kang Kwangchul Jang Masato Kida Yongwon Seo Meilian Chen Jong Kuk Hong Yungoo Song Sanghee Park |
author_facet |
Ji-Hoon Kim Myong-Ho Park Dong-Hun Lee Hirotsugu Minami Young-Keun Jin Akihiro Hachikubo Jin Hur Jong-Sik Ryu Moo-Hee Kang Kwangchul Jang Masato Kida Yongwon Seo Meilian Chen Jong Kuk Hong Yungoo Song Sanghee Park |
author_sort |
Ji-Hoon Kim |
title |
Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
title_short |
Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
title_full |
Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
title_fullStr |
Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
title_full_unstemmed |
Table_1_Impact of High Methane Flux on the Properties of Pore Fluid and Methane-Derived Authigenic Carbonate in the ARAON Mounds, Chukchi Sea.xlsx |
title_sort |
table_1_impact of high methane flux on the properties of pore fluid and methane-derived authigenic carbonate in the araon mounds, chukchi sea.xlsx |
publishDate |
2022 |
url |
https://doi.org/10.3389/fmars.2022.944841.s001 https://figshare.com/articles/dataset/Table_1_Impact_of_High_Methane_Flux_on_the_Properties_of_Pore_Fluid_and_Methane-Derived_Authigenic_Carbonate_in_the_ARAON_Mounds_Chukchi_Sea_xlsx/20295540 |
geographic |
Arctic Arctic Ocean Chukchi Sea |
geographic_facet |
Arctic Arctic Ocean Chukchi Sea |
genre |
Arctic Arctic Ocean Chukchi Chukchi Sea Climate change |
genre_facet |
Arctic Arctic Ocean Chukchi Chukchi Sea Climate change |
op_relation |
doi:10.3389/fmars.2022.944841.s001 https://figshare.com/articles/dataset/Table_1_Impact_of_High_Methane_Flux_on_the_Properties_of_Pore_Fluid_and_Methane-Derived_Authigenic_Carbonate_in_the_ARAON_Mounds_Chukchi_Sea_xlsx/20295540 |
op_rights |
CC BY 4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.3389/fmars.2022.944841.s001 |
_version_ |
1766345761856946176 |