Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf
In situ immobilization of enzyme into metal–organic frameworks (MOFs) is performed through a one-step and facile method. Candida antarctica lipase B (CalB) is directly embedded in zeolitic imidazolate framework (ZIF)-8 by simply mixing an aqueous solution of 2-methylimidazole and zinc nitrate hexahy...
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ftfrontimediafig:oai:figshare.com:article/12616973 2023-05-15T14:04:47+02:00 Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf Yangxin Wang Ningning Zhang Deming Tan Zhenhui Qi Changzhu Wu 2020-07-07T04:03:33Z https://doi.org/10.3389/fbioe.2020.00714.s001 https://figshare.com/articles/figure/Image_1_Facile_Synthesis_of_Enzyme-Embedded_Metal_Organic_Frameworks_for_Size-Selective_Biocatalysis_in_Organic_Solvent_pdf/12616973 unknown doi:10.3389/fbioe.2020.00714.s001 https://figshare.com/articles/figure/Image_1_Facile_Synthesis_of_Enzyme-Embedded_Metal_Organic_Frameworks_for_Size-Selective_Biocatalysis_in_Organic_Solvent_pdf/12616973 CC BY 4.0 CC-BY Biotechnology Biological Engineering Genetic Engineering Biomarkers Biomaterials Biomechanical Engineering Biomedical Engineering not elsewhere classified Synthetic Biology Agricultural Marine Biotechnology Bioremediation Bioprocessing Bioproduction and Bioproducts Industrial Biotechnology Diagnostics (incl. Biosensors) Industrial Microbiology (incl. Biofeedstocks) Industrial Molecular Engineering of Nucleic Acids and Proteins Industrial Biotechnology not elsewhere classified Medical Biotechnology Diagnostics (incl. Biosensors) Medical Molecular Engineering of Nucleic Acids and Proteins Regenerative Medicine (incl. Stem Cells and Tissue Engineering) Medical Biotechnology not elsewhere classified metal–organic frameworks enzymatic reactions size-selective catalysis heterogeneous catalysis biocatalysis Image Figure 2020 ftfrontimediafig https://doi.org/10.3389/fbioe.2020.00714.s001 2020-07-08T22:55:01Z In situ immobilization of enzyme into metal–organic frameworks (MOFs) is performed through a one-step and facile method. Candida antarctica lipase B (CalB) is directly embedded in zeolitic imidazolate framework (ZIF)-8 by simply mixing an aqueous solution of 2-methylimidazole and zinc nitrate hexahydrate [Zn(NO 3 ) 2 ⋅6H 2 O] containing CalB at room temperature. Due to the intrinsic micropores of ZIF-8, the obtained CalB@ZIF composite is successfully applied in size-selective transesterification reaction in organic solvent. CalB@ZIF not only shows much higher catalytic activity but also exhibits higher thermal stability than free CalB. Besides, the robust ZIF-8 shell also offers the hybrid composites excellent reusability. Still Image Antarc* Antarctica Frontiers: Figshare |
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Frontiers: Figshare |
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unknown |
topic |
Biotechnology Biological Engineering Genetic Engineering Biomarkers Biomaterials Biomechanical Engineering Biomedical Engineering not elsewhere classified Synthetic Biology Agricultural Marine Biotechnology Bioremediation Bioprocessing Bioproduction and Bioproducts Industrial Biotechnology Diagnostics (incl. Biosensors) Industrial Microbiology (incl. Biofeedstocks) Industrial Molecular Engineering of Nucleic Acids and Proteins Industrial Biotechnology not elsewhere classified Medical Biotechnology Diagnostics (incl. Biosensors) Medical Molecular Engineering of Nucleic Acids and Proteins Regenerative Medicine (incl. Stem Cells and Tissue Engineering) Medical Biotechnology not elsewhere classified metal–organic frameworks enzymatic reactions size-selective catalysis heterogeneous catalysis biocatalysis |
spellingShingle |
Biotechnology Biological Engineering Genetic Engineering Biomarkers Biomaterials Biomechanical Engineering Biomedical Engineering not elsewhere classified Synthetic Biology Agricultural Marine Biotechnology Bioremediation Bioprocessing Bioproduction and Bioproducts Industrial Biotechnology Diagnostics (incl. Biosensors) Industrial Microbiology (incl. Biofeedstocks) Industrial Molecular Engineering of Nucleic Acids and Proteins Industrial Biotechnology not elsewhere classified Medical Biotechnology Diagnostics (incl. Biosensors) Medical Molecular Engineering of Nucleic Acids and Proteins Regenerative Medicine (incl. Stem Cells and Tissue Engineering) Medical Biotechnology not elsewhere classified metal–organic frameworks enzymatic reactions size-selective catalysis heterogeneous catalysis biocatalysis Yangxin Wang Ningning Zhang Deming Tan Zhenhui Qi Changzhu Wu Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
topic_facet |
Biotechnology Biological Engineering Genetic Engineering Biomarkers Biomaterials Biomechanical Engineering Biomedical Engineering not elsewhere classified Synthetic Biology Agricultural Marine Biotechnology Bioremediation Bioprocessing Bioproduction and Bioproducts Industrial Biotechnology Diagnostics (incl. Biosensors) Industrial Microbiology (incl. Biofeedstocks) Industrial Molecular Engineering of Nucleic Acids and Proteins Industrial Biotechnology not elsewhere classified Medical Biotechnology Diagnostics (incl. Biosensors) Medical Molecular Engineering of Nucleic Acids and Proteins Regenerative Medicine (incl. Stem Cells and Tissue Engineering) Medical Biotechnology not elsewhere classified metal–organic frameworks enzymatic reactions size-selective catalysis heterogeneous catalysis biocatalysis |
description |
In situ immobilization of enzyme into metal–organic frameworks (MOFs) is performed through a one-step and facile method. Candida antarctica lipase B (CalB) is directly embedded in zeolitic imidazolate framework (ZIF)-8 by simply mixing an aqueous solution of 2-methylimidazole and zinc nitrate hexahydrate [Zn(NO 3 ) 2 ⋅6H 2 O] containing CalB at room temperature. Due to the intrinsic micropores of ZIF-8, the obtained CalB@ZIF composite is successfully applied in size-selective transesterification reaction in organic solvent. CalB@ZIF not only shows much higher catalytic activity but also exhibits higher thermal stability than free CalB. Besides, the robust ZIF-8 shell also offers the hybrid composites excellent reusability. |
format |
Still Image |
author |
Yangxin Wang Ningning Zhang Deming Tan Zhenhui Qi Changzhu Wu |
author_facet |
Yangxin Wang Ningning Zhang Deming Tan Zhenhui Qi Changzhu Wu |
author_sort |
Yangxin Wang |
title |
Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
title_short |
Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
title_full |
Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
title_fullStr |
Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
title_full_unstemmed |
Image_1_Facile Synthesis of Enzyme-Embedded Metal–Organic Frameworks for Size-Selective Biocatalysis in Organic Solvent.pdf |
title_sort |
image_1_facile synthesis of enzyme-embedded metal–organic frameworks for size-selective biocatalysis in organic solvent.pdf |
publishDate |
2020 |
url |
https://doi.org/10.3389/fbioe.2020.00714.s001 https://figshare.com/articles/figure/Image_1_Facile_Synthesis_of_Enzyme-Embedded_Metal_Organic_Frameworks_for_Size-Selective_Biocatalysis_in_Organic_Solvent_pdf/12616973 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
doi:10.3389/fbioe.2020.00714.s001 https://figshare.com/articles/figure/Image_1_Facile_Synthesis_of_Enzyme-Embedded_Metal_Organic_Frameworks_for_Size-Selective_Biocatalysis_in_Organic_Solvent_pdf/12616973 |
op_rights |
CC BY 4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.3389/fbioe.2020.00714.s001 |
_version_ |
1766276071831896064 |