Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil
S.13-33 The chemo-enzymatic epoxidation of Lallemantia iberica seed oil (LISO), a novel plant oil characterized by its exceptional high content of alpha-linolenic acid (> 60%), was developed using an immobilized lipase from Pseudozyma antarctica and hydrogen peroxide as oxidant. A statistical app...
Published in: | Applied Biochemistry and Biotechnology |
---|---|
Main Authors: | , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
2018
|
Subjects: | |
Online Access: | https://publica.fraunhofer.de/handle/publica/251354 https://doi.org/10.1007/s12010-017-2630-1 |
id |
ftfrauneprints:oai:publica.fraunhofer.de:publica/251354 |
---|---|
record_format |
openpolar |
spelling |
ftfrauneprints:oai:publica.fraunhofer.de:publica/251354 2024-05-12T07:53:42+00:00 Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil Haitz, Fabian Radloff, S. Rupp, S. Fröhling, M. Hirth, Thomas Zibek, S. 2018 https://publica.fraunhofer.de/handle/publica/251354 https://doi.org/10.1007/s12010-017-2630-1 en eng Applied biochemistry and biotechnology. Part A, Enzyme engineering and biotechnology doi:10.1007/s12010-017-2630-1 https://publica.fraunhofer.de/handle/publica/251354 660 610 620 journal article 2018 ftfrauneprints https://doi.org/10.1007/s12010-017-2630-1 2024-04-17T14:13:51Z S.13-33 The chemo-enzymatic epoxidation of Lallemantia iberica seed oil (LISO), a novel plant oil characterized by its exceptional high content of alpha-linolenic acid (> 60%), was developed using an immobilized lipase from Pseudozyma antarctica and hydrogen peroxide as oxidant. A statistical approach was used to study the effect of enzyme amount, temperature, time, and solvent amount on the oxirane oxygen content obtained during epoxidation. An oxirane oxygen content of 8.6 ± 0.2% corresponding to a yield of 82% was obtained under optimized conditions that were identified to be at an enzyme load of 8.2 g/mol of double bonds, a solvent amount of 56.4 wt.%, a temperature of 33 deg C, and an incubation time of 17 h. In addition, the experimental investigation was combined with a techno-economic and ecological assessment gaining detailed information regarding cost structure and environmental impact for the chemo-enzymatic epoxidation of the novel plant oil. 185 Nr.1 Article in Journal/Newspaper Antarc* Antarctica Publikationsdatenbank der Fraunhofer-Gesellschaft Applied Biochemistry and Biotechnology 185 1 13 33 |
institution |
Open Polar |
collection |
Publikationsdatenbank der Fraunhofer-Gesellschaft |
op_collection_id |
ftfrauneprints |
language |
English |
topic |
660 610 620 |
spellingShingle |
660 610 620 Haitz, Fabian Radloff, S. Rupp, S. Fröhling, M. Hirth, Thomas Zibek, S. Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
topic_facet |
660 610 620 |
description |
S.13-33 The chemo-enzymatic epoxidation of Lallemantia iberica seed oil (LISO), a novel plant oil characterized by its exceptional high content of alpha-linolenic acid (> 60%), was developed using an immobilized lipase from Pseudozyma antarctica and hydrogen peroxide as oxidant. A statistical approach was used to study the effect of enzyme amount, temperature, time, and solvent amount on the oxirane oxygen content obtained during epoxidation. An oxirane oxygen content of 8.6 ± 0.2% corresponding to a yield of 82% was obtained under optimized conditions that were identified to be at an enzyme load of 8.2 g/mol of double bonds, a solvent amount of 56.4 wt.%, a temperature of 33 deg C, and an incubation time of 17 h. In addition, the experimental investigation was combined with a techno-economic and ecological assessment gaining detailed information regarding cost structure and environmental impact for the chemo-enzymatic epoxidation of the novel plant oil. 185 Nr.1 |
format |
Article in Journal/Newspaper |
author |
Haitz, Fabian Radloff, S. Rupp, S. Fröhling, M. Hirth, Thomas Zibek, S. |
author_facet |
Haitz, Fabian Radloff, S. Rupp, S. Fröhling, M. Hirth, Thomas Zibek, S. |
author_sort |
Haitz, Fabian |
title |
Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
title_short |
Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
title_full |
Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
title_fullStr |
Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
title_full_unstemmed |
Chemo-Enzymatic Epoxidation of Lallemantia IbericaSeed Oil |
title_sort |
chemo-enzymatic epoxidation of lallemantia ibericaseed oil |
publishDate |
2018 |
url |
https://publica.fraunhofer.de/handle/publica/251354 https://doi.org/10.1007/s12010-017-2630-1 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
Applied biochemistry and biotechnology. Part A, Enzyme engineering and biotechnology doi:10.1007/s12010-017-2630-1 https://publica.fraunhofer.de/handle/publica/251354 |
op_doi |
https://doi.org/10.1007/s12010-017-2630-1 |
container_title |
Applied Biochemistry and Biotechnology |
container_volume |
185 |
container_issue |
1 |
container_start_page |
13 |
op_container_end_page |
33 |
_version_ |
1798844083745062912 |