Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry
Geochemical characterisation of hypersaline waters is difficult as high concentrations of salts hinder the analysis of constituents at low concentrations, such as trace metals, and the collection of samples for trace metal analysis in natural waters can be easily contaminated. This is particularly t...
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ftfhaachen:oai:opus-fhaachen:9725 2023-05-15T14:13:50+02:00 Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry German, Laura Mikucki, Jill A. Welch, Susan A. Welch, Kathleen A. Lutton, Anthony Dachwald, Bernd (Prof. Dr.-Ing.) Kowalski, Julia (Dr. sc.) Heinen, Dirk Feldmann, Marco (M.Sc.) Francke, Gero (M.Sc.) Espe, Clemens (B.Eng.) Lyons, W. Berry 2021-11-24 https://opus.bibliothek.fh-aachen.de/opus4/frontdoor/index/index/docId/9725 eng eng https://opus.bibliothek.fh-aachen.de/opus4/frontdoor/index/index/docId/9725 info:eu-repo/semantics/closedAccess article doc-type:article 2021 ftfhaachen 2023-04-07T14:43:46Z Geochemical characterisation of hypersaline waters is difficult as high concentrations of salts hinder the analysis of constituents at low concentrations, such as trace metals, and the collection of samples for trace metal analysis in natural waters can be easily contaminated. This is particularly the case if samples are collected by non-conventional techniques such as those required for aquatic subglacial environments. In this paper we present the first analysis of a subglacial brine from Taylor Valley, (~ 78°S), Antarctica for the trace metals: Ba, Co, Mo, Rb, Sr, V, and U. Samples were collected englacially using an electrothermal melting probe called the IceMole. This probe uses differential heating of a copper head as well as the probe’s sidewalls and an ice screw at the melting head to move through glacier ice. Detailed blanks, meltwater, and subglacial brine samples were collected to evaluate the impact of the IceMole and the borehole pump, the melting and collection process, filtration, and storage on the geochemistry of the samples collected by this device. Comparisons between melt water profiles through the glacier ice and blank analysis, with published studies on ice geochemistry, suggest the potential for minor contributions of some species Rb, As, Co, Mn, Ni, NH4+, and NO2−+NO3− from the IceMole. The ability to conduct detailed chemical analyses of subglacial fluids collected with melting probes is critical for the future exploration of the hundreds of deep subglacial lakes in Antarctica. Article in Journal/Newspaper Antarc* Antarctic Antarctica Publication Server of the FH Aachen University of Applied Sciences Antarctic Taylor Valley ENVELOPE(163.000,163.000,-77.617,-77.617) |
institution |
Open Polar |
collection |
Publication Server of the FH Aachen University of Applied Sciences |
op_collection_id |
ftfhaachen |
language |
English |
description |
Geochemical characterisation of hypersaline waters is difficult as high concentrations of salts hinder the analysis of constituents at low concentrations, such as trace metals, and the collection of samples for trace metal analysis in natural waters can be easily contaminated. This is particularly the case if samples are collected by non-conventional techniques such as those required for aquatic subglacial environments. In this paper we present the first analysis of a subglacial brine from Taylor Valley, (~ 78°S), Antarctica for the trace metals: Ba, Co, Mo, Rb, Sr, V, and U. Samples were collected englacially using an electrothermal melting probe called the IceMole. This probe uses differential heating of a copper head as well as the probe’s sidewalls and an ice screw at the melting head to move through glacier ice. Detailed blanks, meltwater, and subglacial brine samples were collected to evaluate the impact of the IceMole and the borehole pump, the melting and collection process, filtration, and storage on the geochemistry of the samples collected by this device. Comparisons between melt water profiles through the glacier ice and blank analysis, with published studies on ice geochemistry, suggest the potential for minor contributions of some species Rb, As, Co, Mn, Ni, NH4+, and NO2−+NO3− from the IceMole. The ability to conduct detailed chemical analyses of subglacial fluids collected with melting probes is critical for the future exploration of the hundreds of deep subglacial lakes in Antarctica. |
format |
Article in Journal/Newspaper |
author |
German, Laura Mikucki, Jill A. Welch, Susan A. Welch, Kathleen A. Lutton, Anthony Dachwald, Bernd (Prof. Dr.-Ing.) Kowalski, Julia (Dr. sc.) Heinen, Dirk Feldmann, Marco (M.Sc.) Francke, Gero (M.Sc.) Espe, Clemens (B.Eng.) Lyons, W. Berry |
spellingShingle |
German, Laura Mikucki, Jill A. Welch, Susan A. Welch, Kathleen A. Lutton, Anthony Dachwald, Bernd (Prof. Dr.-Ing.) Kowalski, Julia (Dr. sc.) Heinen, Dirk Feldmann, Marco (M.Sc.) Francke, Gero (M.Sc.) Espe, Clemens (B.Eng.) Lyons, W. Berry Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
author_facet |
German, Laura Mikucki, Jill A. Welch, Susan A. Welch, Kathleen A. Lutton, Anthony Dachwald, Bernd (Prof. Dr.-Ing.) Kowalski, Julia (Dr. sc.) Heinen, Dirk Feldmann, Marco (M.Sc.) Francke, Gero (M.Sc.) Espe, Clemens (B.Eng.) Lyons, W. Berry |
author_sort |
German, Laura |
title |
Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
title_short |
Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
title_full |
Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
title_fullStr |
Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
title_full_unstemmed |
Validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (IceMole) for environmental analytical geochemistry |
title_sort |
validation of sampling antarctic subglacial hypersaline waters with an electrothermal ice melting probe (icemole) for environmental analytical geochemistry |
publishDate |
2021 |
url |
https://opus.bibliothek.fh-aachen.de/opus4/frontdoor/index/index/docId/9725 |
long_lat |
ENVELOPE(163.000,163.000,-77.617,-77.617) |
geographic |
Antarctic Taylor Valley |
geographic_facet |
Antarctic Taylor Valley |
genre |
Antarc* Antarctic Antarctica |
genre_facet |
Antarc* Antarctic Antarctica |
op_relation |
https://opus.bibliothek.fh-aachen.de/opus4/frontdoor/index/index/docId/9725 |
op_rights |
info:eu-repo/semantics/closedAccess |
_version_ |
1766286369000259584 |