The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state
Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. In contrast to subjective post-hoc correlation analysis, a robust integration requires data fusion, capable of simultaneously decomposing data from mul...
Published in: | Analytical Chemistry |
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2018
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ftdtupubl:oai:pure.atira.dk:publications/24de4ecc-50b9-4d9c-b99e-1df10ed4213f 2024-09-09T19:24:56+00:00 The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state Wünsch, Urban Acar, Evrim Koch, Boris Peter Murphy, Kathleen Schmitt-Kopplin, Philippe Stedmon, Colin Andrew 2018 application/pdf https://orbit.dtu.dk/en/publications/24de4ecc-50b9-4d9c-b99e-1df10ed4213f https://doi.org/10.1021/acs.analchem.8b02863 https://backend.orbit.dtu.dk/ws/files/161125545/Postprint.pdf eng eng https://orbit.dtu.dk/en/publications/24de4ecc-50b9-4d9c-b99e-1df10ed4213f info:eu-repo/semantics/openAccess Wünsch , U , Acar , E , Koch , B P , Murphy , K , Schmitt-Kopplin , P & Stedmon , C A 2018 , ' The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state ' , Analytical Chemistry , vol. 90 , no. 24 , pp. 14188–14197 . https://doi.org/10.1021/acs.analchem.8b02863 article 2018 ftdtupubl https://doi.org/10.1021/acs.analchem.8b02863 2024-08-05T23:48:29Z Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. In contrast to subjective post-hoc correlation analysis, a robust integration requires data fusion, capable of simultaneously decomposing data from multiple instruments while identifying linked and unrelated signals. Here, Advanced Coupled Matrix and Tensor Factorization (ACMTF) was used to identify the molecular fingerprint of DOM fluorescence fractions in Arctic fjords. ACMTF explained 99.84 % of the variability with six fully shared components. Individual molecular formulas were linked to multiple fluorescence components and vice versa. Molecular fingerprints differed in diversity and oceanographic patterns, suggesting a link to the biogeochemical sources and diagenetic state of DOM. The fingerprints obtained through ACMTF were more specific compared to traditional correlation analysis and yielded greater compositional insight. Multivariate data fusion aligns extremely complex, heterogeneous DOM datasets, and thus facilitates a more holistic understanding of DOM biogeochemistry. Article in Journal/Newspaper Arctic Technical University of Denmark: DTU Orbit Arctic Analytical Chemistry 90 24 14188 14197 |
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Open Polar |
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Technical University of Denmark: DTU Orbit |
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ftdtupubl |
language |
English |
description |
Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. In contrast to subjective post-hoc correlation analysis, a robust integration requires data fusion, capable of simultaneously decomposing data from multiple instruments while identifying linked and unrelated signals. Here, Advanced Coupled Matrix and Tensor Factorization (ACMTF) was used to identify the molecular fingerprint of DOM fluorescence fractions in Arctic fjords. ACMTF explained 99.84 % of the variability with six fully shared components. Individual molecular formulas were linked to multiple fluorescence components and vice versa. Molecular fingerprints differed in diversity and oceanographic patterns, suggesting a link to the biogeochemical sources and diagenetic state of DOM. The fingerprints obtained through ACMTF were more specific compared to traditional correlation analysis and yielded greater compositional insight. Multivariate data fusion aligns extremely complex, heterogeneous DOM datasets, and thus facilitates a more holistic understanding of DOM biogeochemistry. |
format |
Article in Journal/Newspaper |
author |
Wünsch, Urban Acar, Evrim Koch, Boris Peter Murphy, Kathleen Schmitt-Kopplin, Philippe Stedmon, Colin Andrew |
spellingShingle |
Wünsch, Urban Acar, Evrim Koch, Boris Peter Murphy, Kathleen Schmitt-Kopplin, Philippe Stedmon, Colin Andrew The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
author_facet |
Wünsch, Urban Acar, Evrim Koch, Boris Peter Murphy, Kathleen Schmitt-Kopplin, Philippe Stedmon, Colin Andrew |
author_sort |
Wünsch, Urban |
title |
The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
title_short |
The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
title_full |
The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
title_fullStr |
The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
title_full_unstemmed |
The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
title_sort |
molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state |
publishDate |
2018 |
url |
https://orbit.dtu.dk/en/publications/24de4ecc-50b9-4d9c-b99e-1df10ed4213f https://doi.org/10.1021/acs.analchem.8b02863 https://backend.orbit.dtu.dk/ws/files/161125545/Postprint.pdf |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
Arctic |
genre_facet |
Arctic |
op_source |
Wünsch , U , Acar , E , Koch , B P , Murphy , K , Schmitt-Kopplin , P & Stedmon , C A 2018 , ' The molecular fingerprint of fluorescent natural organic matter offers insight into biogeochemical sources and diagenetic state ' , Analytical Chemistry , vol. 90 , no. 24 , pp. 14188–14197 . https://doi.org/10.1021/acs.analchem.8b02863 |
op_relation |
https://orbit.dtu.dk/en/publications/24de4ecc-50b9-4d9c-b99e-1df10ed4213f |
op_rights |
info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.1021/acs.analchem.8b02863 |
container_title |
Analytical Chemistry |
container_volume |
90 |
container_issue |
24 |
container_start_page |
14188 |
op_container_end_page |
14197 |
_version_ |
1809894750130536448 |