Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4
The electrolytic hydrogen-deuterium separation factor has been measured, simultaneously for the first time, on both the cathode and the diffusion side of thin iron membranes in acid solution at room temperature as functions of time and current density. Both separation factors decreased with time and...
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ftdtic:AD0773999 2023-05-15T17:21:58+02:00 Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 Hammerli,M. Olmstead,W. J. Muju,B. L. Smith,F. R. ATOMIC ENERGY OF CANADA LTD CHALK RIVER (ONTARIO) 1972-08-14 text/html http://www.dtic.mil/docs/citations/AD0773999 http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=AD0773999 en eng http://www.dtic.mil/docs/citations/AD0773999 Availability: Pub. in Electroanalytical Chemistry and Interfacial Electrochemistry, v43 p45-58 1973. DTIC AND NTIS Physical Chemistry *Isotope separation *Hydrogen *Deuterium Membranes Electrolysis Experimental design Iron Diffusion Canada Text 1972 ftdtic 2016-02-19T03:42:45Z The electrolytic hydrogen-deuterium separation factor has been measured, simultaneously for the first time, on both the cathode and the diffusion side of thin iron membranes in acid solution at room temperature as functions of time and current density. Both separation factors decreased with time and reached plateau values; neither is a simple function of current density. Possible explanations for these observations are given. An estimate of the permeation rate of hydrogen was obtained and the variations in this quantity are accounted for in terms of the screened proton model. Prepared in cooperation with Memorial Univ. of Newfoundland, St. John's Dept. of Chemistry. Text Newfoundland Defense Technical Information Center: DTIC Technical Reports database Canada |
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Open Polar |
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Defense Technical Information Center: DTIC Technical Reports database |
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ftdtic |
language |
English |
topic |
Physical Chemistry *Isotope separation *Hydrogen *Deuterium Membranes Electrolysis Experimental design Iron Diffusion Canada |
spellingShingle |
Physical Chemistry *Isotope separation *Hydrogen *Deuterium Membranes Electrolysis Experimental design Iron Diffusion Canada Hammerli,M. Olmstead,W. J. Muju,B. L. Smith,F. R. Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
topic_facet |
Physical Chemistry *Isotope separation *Hydrogen *Deuterium Membranes Electrolysis Experimental design Iron Diffusion Canada |
description |
The electrolytic hydrogen-deuterium separation factor has been measured, simultaneously for the first time, on both the cathode and the diffusion side of thin iron membranes in acid solution at room temperature as functions of time and current density. Both separation factors decreased with time and reached plateau values; neither is a simple function of current density. Possible explanations for these observations are given. An estimate of the permeation rate of hydrogen was obtained and the variations in this quantity are accounted for in terms of the screened proton model. Prepared in cooperation with Memorial Univ. of Newfoundland, St. John's Dept. of Chemistry. |
author2 |
ATOMIC ENERGY OF CANADA LTD CHALK RIVER (ONTARIO) |
format |
Text |
author |
Hammerli,M. Olmstead,W. J. Muju,B. L. Smith,F. R. |
author_facet |
Hammerli,M. Olmstead,W. J. Muju,B. L. Smith,F. R. |
author_sort |
Hammerli,M. |
title |
Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
title_short |
Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
title_full |
Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
title_fullStr |
Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
title_full_unstemmed |
Electrolytic H/D Separation Factors on Cathode and Diffusion Sides of Iron Membranes in H2SO4 |
title_sort |
electrolytic h/d separation factors on cathode and diffusion sides of iron membranes in h2so4 |
publishDate |
1972 |
url |
http://www.dtic.mil/docs/citations/AD0773999 http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=AD0773999 |
geographic |
Canada |
geographic_facet |
Canada |
genre |
Newfoundland |
genre_facet |
Newfoundland |
op_source |
DTIC AND NTIS |
op_relation |
http://www.dtic.mil/docs/citations/AD0773999 |
op_rights |
Availability: Pub. in Electroanalytical Chemistry and Interfacial Electrochemistry, v43 p45-58 1973. |
_version_ |
1766108047457910784 |