DIPOLE MOMENTS OF CYCLIC CARBONIC ACID ESTERS

Dipole moments of cyclic esters of carbonic acid in benzene solution are measured and compared with theoretical calculations. Dipole moments are reported for ethylene carbonate (4-80D), 1:3 propylene carbonate (5-21D) and 1:3 butylene carbonate (5-23D). These values are shown to be consistent with t...

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Bibliographic Details
Main Authors: Arbuzov,B. A., Shavsha,T. G.
Other Authors: AIR FORCE CAMBRIDGE RESEARCH LABS L G HANSCOM FIELD MASS
Format: Text
Language:English
Published: 1969
Subjects:
Physical Chemistry
(*CARBONATES
*DIPOLE MOMENTS)
(*ESTERS
DIPOLE MOMENTS)
DIELECTRIC PROPERTIES
USSR
OXYGEN HETEROCYCLIC COMPOUNDS
CARBONATE/1-3-BUTYLENE
CYCLOBUTENE CARBONATE
CYCLOPROPENE CARBONATE
ETHYLENE CARBONATES
PROPYLENE CARBONATES
TRANSLATIONS
Carbonic acid
Online Access:http://www.dtic.mil/docs/citations/AD0698332
http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=AD0698332
Description
Summary:Dipole moments of cyclic esters of carbonic acid in benzene solution are measured and compared with theoretical calculations. Dipole moments are reported for ethylene carbonate (4-80D), 1:3 propylene carbonate (5-21D) and 1:3 butylene carbonate (5-23D). These values are shown to be consistent with theoretically calculated values for the corresponding open chain compounds dimethyl carbonate and diethyl carbonate in the appropriate stereochemical configurations. (Author) Trans. of Akademiya Nauk SSSR. Doklady, v68 p1045-1048 1949.

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