Spatial Distribution of Colored Dissolved Organic Matter in the Western Arctic Ocean

• Published in: Journal of Marine Science and Engineering
• Main Authors: Xiaoxia Cai, Yanpei Zhuang, Hongliang Li, Jing Xu, Haiyan Jin, Jianfang Chen
• Format: Article in Journal/Newspaper
• Language: English
• Published: MDPI AG 2022
• Subjects: colored DOM; marine carbon cycle; Arctic Ocean; ice melt; Pacific water inflow; Naval architecture. Shipbuilding. Marine engineering; VM1-989; Oceanography; GC1-1581; Arctic; Pacific
• Online Access: https://doi.org/10.3390/jmse10030352; https://doaj.org/article/fe1fc42979c94ac1bb39a485906373b3

Optical properties of colored dissolved organic matter (CDOM) were investigated along a latitudinal transect (67°–77° N) in upper water (<80 m depth) of the western Arctic Ocean. The absorption coefficient at 280 nm was 0.48–1.25 m −1 , with the average for the oligotrophic basin area (1.04 ± 0.08 m −1 ) being slightly higher than that of the productive shelf area (0.95 ± 0.16 m −1 ), implying a decoupling effect between CDOM concentration and biological productivity in the western Arctic Ocean. The spectral slope coefficient S 270–350 was negatively correlated with salinity, indicating that DOM molecular weight increases with salinity, and may be affected by melt-water input. Four fluorescent components were identified by excitation emission matrices elaborated by parallel factor analysis, including three humic-like (C1, C3, and C4) components and one protein-like (C2) component. Significant increases in concentrations of terrestrially derived humic-like C3 and C4 components with salinity were observed in the basin, mainly controlled by the physical mixing of surface fresh water and subsurface inflowing Pacific Ocean water. Terrestrial material carried by Pacific inflow is thus an important factor affecting the distribution of CDOM fluorescence components. The C3 and C4 fluorescence components may be useful as tracers of Pacific water in the western Arctic Ocean.