Kinetic Analysis of Methane Hydrate Formation with Butterfly Turbine Impellers

• Published in: Molecules
• Main Authors: Sotirios Nik. Longinos, Dionisia Dimitra Longinou, Nurbala Myrzakhmetova, Nazgul Akimbayeva, Mariamkul Zhursumbaeva, Kaldibek Abdiyev, Zhexenbek Toktarbay, Mahmut Parlaktuna
• Format: Article in Journal/Newspaper
• Language: English
• Published: MDPI AG 2022
• Subjects: gas hydrates; hydrate formation; butterfly turbine; induction time; Organic chemistry; QD241-441; Baffle; Methane hydrate
• Online Access: https://doi.org/10.3390/molecules27144388; https://doaj.org/article/fc784ab7599d416891810b4125eb6ff7

Heat generation during gas hydrate formation is an important problem because it reduces the amount of water and gas that become gas hydrates. In this research work, we present a new design of an impeller to be used for hydrate formation and to overcome this concern by following the hydrodynamic literature. CH 4 hydrate formation experiments were performed in a 5.7 L continuously stirred tank reactor using a butterfly turbine (BT) impeller with no baffle (NB), full baffle (FB), half baffle (HB), and surface baffle (SB) under mixed flow conditions. Four experiments were conducted separately using single and dual impellers. In addition to the estimated induction time, the rate of hydrate formation, hydrate productivity and hydrate formation rate, constant for a maximum of 3 h, were calculated. The induction time was less for both single and dual-impeller experiments that used full baffle for less than 3 min and more than 1 h for all other experiments. In an experiment with a single impeller, a surface baffle yielded higher hydrate growth with a value of 42 × 10 −8 mol/s, while in an experiment with dual impellers, a half baffle generated higher hydrate growth with a value of 28.8 × 10 −8 mol/s. Both single and dual impellers achieved the highest values for the hydrate formation rates that were constant in the full-baffle experiments.