Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process
The aim of this study was to increase feedstock availability for mineral carbonation. Acid dissolution and carbonic acid dissolution approaches were used to achieve higher Mg extractions from peridotites. Acid dissolution studies of raw dunite, heat-activated dunite, heat-transformed dunite, and twi...
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2020
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ftdoajarticles:oai:doaj.org/article:f1735b87102a4886b87ff0b470bb14de 2023-05-15T15:52:23+02:00 Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process Muhammad Imran Rashid Emad Benhelal Faezeh Farhang Michael Stockenhuber Eric M. Kennedy 2020-12-01T00:00:00Z https://doi.org/10.3390/min10121091 https://doaj.org/article/f1735b87102a4886b87ff0b470bb14de EN eng MDPI AG https://www.mdpi.com/2075-163X/10/12/1091 https://doaj.org/toc/2075-163X doi:10.3390/min10121091 2075-163X https://doaj.org/article/f1735b87102a4886b87ff0b470bb14de Minerals, Vol 10, Iss 1091, p 1091 (2020) acid dissolution dunite rock olivine carbonic acid dissolution peridotites Mineralogy QE351-399.2 article 2020 ftdoajarticles https://doi.org/10.3390/min10121091 2022-12-31T09:22:48Z The aim of this study was to increase feedstock availability for mineral carbonation. Acid dissolution and carbonic acid dissolution approaches were used to achieve higher Mg extractions from peridotites. Acid dissolution studies of raw dunite, heat-activated dunite, heat-transformed dunite, and twin sister dunite have not been reported in the literature. Heat-activated dunite is more reactive as compared to heat-transformed dunite, raw dunite, and twin sister dunite. The fraction of magnesium extracted from heat-activated dunite was 57% as compared to 18% from heat-transformed dunite, 14% from raw dunite, and 11% from twin sister dunite. Similarly, silicon and iron extractions were higher for heat-activated dunite compared to that of heat-transformed dunite, raw dunite, and twin sister dunite. Materials rich in forsterite (twin sister dunite and heat-transformed dunite) showed preferential Mg release and exhibited incongruent dissolution similar to that of forsterite. Heat-activated dunite (amorphous magnesium silicate rich) on the other hand behaved differently and showed congruent dissolution. Olivine did not dissolve under carbonic acid dissolution (with concurrent grinding) and acidic conditions. Under carbonic acid dissolution with concurrent grinding conditions, olivine was partially converted into nanometer sized particles (d 10 = 0.08 µm) but still provided 16% Mg extraction during 4 h of dissolution. Article in Journal/Newspaper Carbonic acid Directory of Open Access Journals: DOAJ Articles Minerals 10 12 1091 |
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Open Polar |
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Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
acid dissolution dunite rock olivine carbonic acid dissolution peridotites Mineralogy QE351-399.2 |
spellingShingle |
acid dissolution dunite rock olivine carbonic acid dissolution peridotites Mineralogy QE351-399.2 Muhammad Imran Rashid Emad Benhelal Faezeh Farhang Michael Stockenhuber Eric M. Kennedy Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
topic_facet |
acid dissolution dunite rock olivine carbonic acid dissolution peridotites Mineralogy QE351-399.2 |
description |
The aim of this study was to increase feedstock availability for mineral carbonation. Acid dissolution and carbonic acid dissolution approaches were used to achieve higher Mg extractions from peridotites. Acid dissolution studies of raw dunite, heat-activated dunite, heat-transformed dunite, and twin sister dunite have not been reported in the literature. Heat-activated dunite is more reactive as compared to heat-transformed dunite, raw dunite, and twin sister dunite. The fraction of magnesium extracted from heat-activated dunite was 57% as compared to 18% from heat-transformed dunite, 14% from raw dunite, and 11% from twin sister dunite. Similarly, silicon and iron extractions were higher for heat-activated dunite compared to that of heat-transformed dunite, raw dunite, and twin sister dunite. Materials rich in forsterite (twin sister dunite and heat-transformed dunite) showed preferential Mg release and exhibited incongruent dissolution similar to that of forsterite. Heat-activated dunite (amorphous magnesium silicate rich) on the other hand behaved differently and showed congruent dissolution. Olivine did not dissolve under carbonic acid dissolution (with concurrent grinding) and acidic conditions. Under carbonic acid dissolution with concurrent grinding conditions, olivine was partially converted into nanometer sized particles (d 10 = 0.08 µm) but still provided 16% Mg extraction during 4 h of dissolution. |
format |
Article in Journal/Newspaper |
author |
Muhammad Imran Rashid Emad Benhelal Faezeh Farhang Michael Stockenhuber Eric M. Kennedy |
author_facet |
Muhammad Imran Rashid Emad Benhelal Faezeh Farhang Michael Stockenhuber Eric M. Kennedy |
author_sort |
Muhammad Imran Rashid |
title |
Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
title_short |
Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
title_full |
Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
title_fullStr |
Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
title_full_unstemmed |
Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process |
title_sort |
magnesium leachability of mg-silicate peridotites: the effect on magnesite yield of a mineral carbonation process |
publisher |
MDPI AG |
publishDate |
2020 |
url |
https://doi.org/10.3390/min10121091 https://doaj.org/article/f1735b87102a4886b87ff0b470bb14de |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Minerals, Vol 10, Iss 1091, p 1091 (2020) |
op_relation |
https://www.mdpi.com/2075-163X/10/12/1091 https://doaj.org/toc/2075-163X doi:10.3390/min10121091 2075-163X https://doaj.org/article/f1735b87102a4886b87ff0b470bb14de |
op_doi |
https://doi.org/10.3390/min10121091 |
container_title |
Minerals |
container_volume |
10 |
container_issue |
12 |
container_start_page |
1091 |
_version_ |
1766387590869549056 |