Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange
In this study, we have investigated the oxygen isotope compositions (δ 17 O and δ 18 O) of modern rain and ice cores using published isotopic data. We find that, contrary to existing interpretations, precipitation δ 17 O is influenced by two factors: mass-dependent fractionation (MDF), which occurs...
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Online Access: | https://doi.org/10.3390/atmos14081268 https://doaj.org/article/ded090c651c3494ea6fc84da3c812995 |
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ftdoajarticles:oai:doaj.org/article:ded090c651c3494ea6fc84da3c812995 2023-09-26T15:10:41+02:00 Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange Pradeep K. Aggarwal Frederick J. Longstaffe Franklin W. Schwartz 2023-08-01T00:00:00Z https://doi.org/10.3390/atmos14081268 https://doaj.org/article/ded090c651c3494ea6fc84da3c812995 EN eng MDPI AG https://www.mdpi.com/2073-4433/14/8/1268 https://doaj.org/toc/2073-4433 doi:10.3390/atmos14081268 2073-4433 https://doaj.org/article/ded090c651c3494ea6fc84da3c812995 Atmosphere, Vol 14, Iss 1268, p 1268 (2023) isotope oxygen-17 ice core climate change paleothermometry stratosphere Meteorology. Climatology QC851-999 article 2023 ftdoajarticles https://doi.org/10.3390/atmos14081268 2023-08-27T00:36:09Z In this study, we have investigated the oxygen isotope compositions (δ 17 O and δ 18 O) of modern rain and ice cores using published isotopic data. We find that, contrary to existing interpretations, precipitation δ 17 O is influenced by two factors: mass-dependent fractionation (MDF), which occurs during ocean evaporation, and mass-independent fractionation (MIF), which happens in the stratosphere. The MDF contribution remains constant and can be understood by studying tropical rain, as the overall movement of mass in the tropics is upward toward the stratosphere. On the other hand, the MIF effect comes from the mixing of stratospheric air in the troposphere, which is a result of the Brewer–Dobson circulation. This MIF effect on precipitation 17 O increases from the tropics toward the poles and is observed consistently in modern precipitation and ice cores. The relative δ 17 O and δ 18 O composition, denoted as ∆‘ 17 O, in modern precipitation can be calibrated with surface air temperature, creating a new and independent tool for estimating past temperatures. We used this calibration along with the ∆‘ 17 O of Antarctic and Greenland ice cores, and our reconstructed past temperatures are in excellent agreement with those derived from borehole thermometry or gas phase analysis of air trapped in the ice. The ∆‘ 17 O method overcomes the problems associated with using δ 18 O alone for paleothermometry. Our findings align with climate models that suggest a weakening of the Brewer–Dobson circulation during the Last Glacial Maximum. Furthermore, our approach could be used to monitor future changes in stratosphere–troposphere mass exchange in response to a warming climate caused by increasing greenhouse gases. Article in Journal/Newspaper Antarc* Antarctic Greenland Greenland ice cores ice core Directory of Open Access Journals: DOAJ Articles Antarctic Greenland Atmosphere 14 8 1268 |
institution |
Open Polar |
collection |
Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
isotope oxygen-17 ice core climate change paleothermometry stratosphere Meteorology. Climatology QC851-999 |
spellingShingle |
isotope oxygen-17 ice core climate change paleothermometry stratosphere Meteorology. Climatology QC851-999 Pradeep K. Aggarwal Frederick J. Longstaffe Franklin W. Schwartz Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
topic_facet |
isotope oxygen-17 ice core climate change paleothermometry stratosphere Meteorology. Climatology QC851-999 |
description |
In this study, we have investigated the oxygen isotope compositions (δ 17 O and δ 18 O) of modern rain and ice cores using published isotopic data. We find that, contrary to existing interpretations, precipitation δ 17 O is influenced by two factors: mass-dependent fractionation (MDF), which occurs during ocean evaporation, and mass-independent fractionation (MIF), which happens in the stratosphere. The MDF contribution remains constant and can be understood by studying tropical rain, as the overall movement of mass in the tropics is upward toward the stratosphere. On the other hand, the MIF effect comes from the mixing of stratospheric air in the troposphere, which is a result of the Brewer–Dobson circulation. This MIF effect on precipitation 17 O increases from the tropics toward the poles and is observed consistently in modern precipitation and ice cores. The relative δ 17 O and δ 18 O composition, denoted as ∆‘ 17 O, in modern precipitation can be calibrated with surface air temperature, creating a new and independent tool for estimating past temperatures. We used this calibration along with the ∆‘ 17 O of Antarctic and Greenland ice cores, and our reconstructed past temperatures are in excellent agreement with those derived from borehole thermometry or gas phase analysis of air trapped in the ice. The ∆‘ 17 O method overcomes the problems associated with using δ 18 O alone for paleothermometry. Our findings align with climate models that suggest a weakening of the Brewer–Dobson circulation during the Last Glacial Maximum. Furthermore, our approach could be used to monitor future changes in stratosphere–troposphere mass exchange in response to a warming climate caused by increasing greenhouse gases. |
format |
Article in Journal/Newspaper |
author |
Pradeep K. Aggarwal Frederick J. Longstaffe Franklin W. Schwartz |
author_facet |
Pradeep K. Aggarwal Frederick J. Longstaffe Franklin W. Schwartz |
author_sort |
Pradeep K. Aggarwal |
title |
Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
title_short |
Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
title_full |
Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
title_fullStr |
Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
title_full_unstemmed |
Ice Core 17 O Reveals Past Changes in Surface Air Temperatures and Stratosphere to Troposphere Mass Exchange |
title_sort |
ice core 17 o reveals past changes in surface air temperatures and stratosphere to troposphere mass exchange |
publisher |
MDPI AG |
publishDate |
2023 |
url |
https://doi.org/10.3390/atmos14081268 https://doaj.org/article/ded090c651c3494ea6fc84da3c812995 |
geographic |
Antarctic Greenland |
geographic_facet |
Antarctic Greenland |
genre |
Antarc* Antarctic Greenland Greenland ice cores ice core |
genre_facet |
Antarc* Antarctic Greenland Greenland ice cores ice core |
op_source |
Atmosphere, Vol 14, Iss 1268, p 1268 (2023) |
op_relation |
https://www.mdpi.com/2073-4433/14/8/1268 https://doaj.org/toc/2073-4433 doi:10.3390/atmos14081268 2073-4433 https://doaj.org/article/ded090c651c3494ea6fc84da3c812995 |
op_doi |
https://doi.org/10.3390/atmos14081268 |
container_title |
Atmosphere |
container_volume |
14 |
container_issue |
8 |
container_start_page |
1268 |
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1778147013233213440 |