Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach
Here we present results of digital modelling of a specific setting of hypogenic carbonic acid speleogenesis (CAS). We study an unconfined aquifer where meteoric water seeps through the vadose zone and becomes saturated with respect to calcite when it arrives at the water table. From below, deep-seat...
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Copernicus Publications
2021
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Online Access: | https://doi.org/10.5194/hess-25-2895-2021 https://doaj.org/article/c6ebbc2311404c35832e5514760e9f78 |
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ftdoajarticles:oai:doaj.org/article:c6ebbc2311404c35832e5514760e9f78 2023-05-15T15:52:37+02:00 Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach F. Gabrovšek W. Dreybrodt 2021-05-01T00:00:00Z https://doi.org/10.5194/hess-25-2895-2021 https://doaj.org/article/c6ebbc2311404c35832e5514760e9f78 EN eng Copernicus Publications https://hess.copernicus.org/articles/25/2895/2021/hess-25-2895-2021.pdf https://doaj.org/toc/1027-5606 https://doaj.org/toc/1607-7938 doi:10.5194/hess-25-2895-2021 1027-5606 1607-7938 https://doaj.org/article/c6ebbc2311404c35832e5514760e9f78 Hydrology and Earth System Sciences, Vol 25, Pp 2895-2913 (2021) Technology T Environmental technology. Sanitary engineering TD1-1066 Geography. Anthropology. Recreation G Environmental sciences GE1-350 article 2021 ftdoajarticles https://doi.org/10.5194/hess-25-2895-2021 2022-12-31T16:36:57Z Here we present results of digital modelling of a specific setting of hypogenic carbonic acid speleogenesis (CAS). We study an unconfined aquifer where meteoric water seeps through the vadose zone and becomes saturated with respect to calcite when it arrives at the water table. From below, deep-seated water with high <math xmlns="http://www.w3.org/1998/Math/MathML" id="M2" display="inline" overflow="scroll" dspmath="mathml"><mrow><msub><mi>p</mi><mrow class="chem"><msub><mi mathvariant="normal">CO</mi><mn mathvariant="normal">2</mn></msub></mrow></msub></mrow></math> <svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="24pt" height="12pt" class="svg-formula" dspmath="mathimg" md5hash="f970a075afd747993d97d753129f4038"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="hess-25-2895-2021-ie00001.svg" width="24pt" height="12pt" src="hess-25-2895-2021-ie00001.png"/></svg:svg> and saturated with respect to calcite invades the limestone formation by forced flow. Two flow domains arise that host exclusively water from the meteoric or deep-seated source. They are separated by a water divide. There by dispersion of flow, a fringe of mixing arises and widening of the fractures is caused by mixing corrosion (MC). The evolution of the cave system is determined by its early state. At sites with high rates of fracture widening, regions of higher hydraulic conductivity are created. They attract flow and support one-by-one mixing with maximal dissolution rates. Therefore, the early evolution is determined by karstification originating close to the input of the upwelling water and at the output at a seepage face. In between these regions, a wide fringe of moderate dissolution is present. In the later stage of evolution, this region is divided by constrictions that originate from statistical variations of fracture aperture widths that favour high dissolution rates and focus flow into this region. This ... Article in Journal/Newspaper Carbonic acid Directory of Open Access Journals: DOAJ Articles Hess ENVELOPE(-65.133,-65.133,-67.200,-67.200) Hydrology and Earth System Sciences 25 5 2895 2913 |
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Open Polar |
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Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
Technology T Environmental technology. Sanitary engineering TD1-1066 Geography. Anthropology. Recreation G Environmental sciences GE1-350 |
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Technology T Environmental technology. Sanitary engineering TD1-1066 Geography. Anthropology. Recreation G Environmental sciences GE1-350 F. Gabrovšek W. Dreybrodt Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
topic_facet |
Technology T Environmental technology. Sanitary engineering TD1-1066 Geography. Anthropology. Recreation G Environmental sciences GE1-350 |
description |
Here we present results of digital modelling of a specific setting of hypogenic carbonic acid speleogenesis (CAS). We study an unconfined aquifer where meteoric water seeps through the vadose zone and becomes saturated with respect to calcite when it arrives at the water table. From below, deep-seated water with high <math xmlns="http://www.w3.org/1998/Math/MathML" id="M2" display="inline" overflow="scroll" dspmath="mathml"><mrow><msub><mi>p</mi><mrow class="chem"><msub><mi mathvariant="normal">CO</mi><mn mathvariant="normal">2</mn></msub></mrow></msub></mrow></math> <svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="24pt" height="12pt" class="svg-formula" dspmath="mathimg" md5hash="f970a075afd747993d97d753129f4038"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="hess-25-2895-2021-ie00001.svg" width="24pt" height="12pt" src="hess-25-2895-2021-ie00001.png"/></svg:svg> and saturated with respect to calcite invades the limestone formation by forced flow. Two flow domains arise that host exclusively water from the meteoric or deep-seated source. They are separated by a water divide. There by dispersion of flow, a fringe of mixing arises and widening of the fractures is caused by mixing corrosion (MC). The evolution of the cave system is determined by its early state. At sites with high rates of fracture widening, regions of higher hydraulic conductivity are created. They attract flow and support one-by-one mixing with maximal dissolution rates. Therefore, the early evolution is determined by karstification originating close to the input of the upwelling water and at the output at a seepage face. In between these regions, a wide fringe of moderate dissolution is present. In the later stage of evolution, this region is divided by constrictions that originate from statistical variations of fracture aperture widths that favour high dissolution rates and focus flow into this region. This ... |
format |
Article in Journal/Newspaper |
author |
F. Gabrovšek W. Dreybrodt |
author_facet |
F. Gabrovšek W. Dreybrodt |
author_sort |
F. Gabrovšek |
title |
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
title_short |
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
title_full |
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
title_fullStr |
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
title_full_unstemmed |
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO 2 concentration: a modelling approach |
title_sort |
early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high co 2 concentration: a modelling approach |
publisher |
Copernicus Publications |
publishDate |
2021 |
url |
https://doi.org/10.5194/hess-25-2895-2021 https://doaj.org/article/c6ebbc2311404c35832e5514760e9f78 |
long_lat |
ENVELOPE(-65.133,-65.133,-67.200,-67.200) |
geographic |
Hess |
geographic_facet |
Hess |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Hydrology and Earth System Sciences, Vol 25, Pp 2895-2913 (2021) |
op_relation |
https://hess.copernicus.org/articles/25/2895/2021/hess-25-2895-2021.pdf https://doaj.org/toc/1027-5606 https://doaj.org/toc/1607-7938 doi:10.5194/hess-25-2895-2021 1027-5606 1607-7938 https://doaj.org/article/c6ebbc2311404c35832e5514760e9f78 |
op_doi |
https://doi.org/10.5194/hess-25-2895-2021 |
container_title |
Hydrology and Earth System Sciences |
container_volume |
25 |
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5 |
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2895 |
op_container_end_page |
2913 |
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