Sea salt aerosols as a reactive surface for inorganic and organic acidic gases in the Arctic troposphere

• Published in: Atmospheric Chemistry and Physics
• Main Authors: J. W. Chi, W. J. Li, D. Z. Zhang, J. C. Zhang, Y. T. Lin, X. J. Shen, J. Y. Sun, J. M. Chen, X. Y. Zhang, Y. M. Zhang, W. X. Wang
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2015
• Subjects: Physics; QC1-999; Chemistry; QD1-999; Arctic; Ny-Ålesund; Svalbard; Ny Ålesund
• Online Access: https://doi.org/10.5194/acp-15-11341-2015; https://doaj.org/article/bb1b338f3587445e99ff2d84101b7cff

Sea salt aerosols (SSA) are dominant particles in the Arctic atmosphere and determine the polar radiative balance. SSA react with acidic pollutants that lead to changes in physical and chemical properties of their surface, which in turn alter their hygroscopic and optical properties. Transmission electron microscopy with energy-dispersive X-ray spectrometry was used to analyze morphology, composition, size, and mixing state of individual SSA at Ny-Ålesund, Svalbard, in summertime. Individual fresh SSA contained cubic NaCl coated by certain amounts of MgCl 2 and CaSO 4 . Individual partially aged SSA contained irregular NaCl coated by a mixture of NaNO 3 , Na 2 SO 4 , Mg(NO 3 ) 2 , and MgSO 4 . The comparison suggests the hydrophilic MgCl 2 coating in fresh SSA likely intrigued the heterogeneous reactions at the beginning of SSA and acidic gases. Individual fully aged SSA normally had Na 2 SO 4 cores and an amorphous coating of NaNO 3 . Elemental mappings of individual SSA particles revealed that as the particles ageing Cl gradually decreased, the C, N, O, and S content increased. 12 C - mapping from nanoscale secondary ion mass spectrometry indicates that organic matter increased in the aged SSA compared with the fresh SSA. 12 C - line scan further shows that organic matter was mainly concentrated on the aged SSA surface. These new findings indicate that this mixture of organic matter and NaNO 3 on particle surfaces likely determines their hygroscopic and optical properties. These abundant SSA as reactive surfaces adsorbing inorganic and organic acidic gases can shorten acidic gas lifetime and influence the possible gaseous reactions in the Arctic atmosphere, which need to be incorporated into atmospheric chemical models in the Arctic troposphere.