Partition between supercooled liquid droplets and ice crystals in mixed-phase clouds based on airborne in situ observations

• Published in: Atmospheric Measurement Techniques
• Main Authors: F. V. Maciel, M. Diao, C. A. Yang
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2024
• Subjects: Environmental engineering; TA170-171; Earthwork. Foundations; TA715-787; Southern Ocean
• Online Access: https://doi.org/10.5194/amt-17-4843-2024; https://doaj.org/article/8dbf69f837464e8e9553cfe0f0331198

The onset of ice nucleation in mixed-phase clouds determines the lifetime and microphysical properties of ice clouds. In this work, we develop a novel method that differentiates between various phases of mixed-phase clouds, such as clouds dominated by pure liquid or pure ice segments, compared with those having ice crystals surrounded by supercooled liquid water droplets or vice versa. Using this method, we examine the relationship between the macrophysical and microphysical properties of Southern Ocean mixed-phase clouds at −40 to 0 °C (e.g. stratiform and cumuliform clouds) based on the in situ aircraft-based observations during the US National Science Foundation Southern Ocean Clouds, Radiation, Aerosol Transport Experimental Study (SOCRATES) flight campaign. The results show that the exchange between supercooled liquid water and ice crystals from a macrophysical perspective, represented by the increasing spatial ratio of regions containing ice crystals relative to the total in-cloud region (defined as ice spatial ratio), is positively correlated with the phase exchange from a microphysical perspective, represented by the increasing ice water content (IWC), decreasing liquid water content (LWC), increasing ice mass fraction, and increasing ice particle number fraction (IPNF). The mass exchange between liquid and ice becomes more significant during phase 3 when pure ice cloud regions (ICRs) start to appear. Occurrence frequencies of cloud thermodynamic phases show a significant phase change from liquid to ice at a similar temperature (i.e. −17.5 °C) among three types of definitions of mixed-phase clouds based on ice spatial ratio, ice mass fraction, or IPNF. Aerosol indirect effects are quantified for different phases using number concentrations of aerosols greater than 100 or 500 nm ( N >100 and N >500 , respectively). N >500 shows stronger positive correlations with ice spatial ratios compared with N >100 . This result indicates that larger aerosols potentially contain ice-nucleating particles ...